Fabric softener compositions containing a mixture of cationic polymers as rheology modifiers
An aqueous fabric softening composition is described having its rheological properties of flow elasticity and viscosity capable of being readily modified as needed independently of each other to satisfy a consumer preference, said composition comprising: a) from about 0.01% to about 25%, by weight, of a cationic fabric softener; b) an effective amount of a mixture of cationic polymers capable of modifying the aforesaid rheological properties, said mixture comprising: (iii) from about 0.01% to about 90%, by weight, of a cationic linear homopolymer that is derivable from the polymerization of acrylic acid and/or methacrylic acid or a linear copolymer that is derivable from the polymerization of acrylic acid and/or methacrylic acid and acrylamide or methacrylamide, said homopolymer or copolyer having a molecular weight of from about 10,000 to about 30 million; and (iv) from about 10% to about 99.99%, by weight, of a cationic cross-linked polymer that is derivable from the polymerization of, from 5 to 100 mole percent of cationic vinyl addition monomer, from 0 to 95 mole percent of acrylamide, and from 70 ppm to 300 ppm of a difunctional vinyl addition monomer cross linking agent, the respective amounts of (i) and (ii) in said mixture being selected to provide the desired rheological properties of viscosity and flow elasticity in said softening composition; and c) balance water.
1. An aqueous fabric softening composition having its rheological properties of flow elasticity and viscosity capable of being readily modified as needed independently of each other to satisfy a consumer preference, said composition comprising:
a) from about 0.01% to about 25%, by weight, of a cationic fabric softener;
b) an effective amount of a mixture of cationic polymers capable of modifying the aforesaid rheological properties, said mixture comprising:
(i) from about 0.01% to about 90%, by weight, of a cationic linear homopolymer that is derivable from the polymerization of quaternary ammonium acrylate or methacrylate, a linear copolymer that is derivable from the polymerization of quaternary ammonium acrylate and/or methacrylate and acrylamide or methacrylamide, said homopolymer or copolymer having a molecular weight of from about 10,000 to about 30 million; and
(ii) from about 10% to about 99.99%, by weight, of a cationic cross-linked polymer that is derivable from the polymerization of, from 5 to 100 mole percent of cationic vinyl addition monomer, from 0 to 95 mole percent of acrylamide, and from 70 ppm to 300 ppm of a difunctional vinyl addition monomer cross linking agent, the respective amounts of (i) and (ii) in said mixture being selected to provide the desired rheological properties of viscosity and flow elasticity in said softening composition;
c) from 0% to about 10% by weight of a sequestering compound selected from the group consisting of amino-carboxylic acid compounds, organo aminophosphonic acid compounds and mixtures thereof;
d) from 0% to about 5% by weight of a perfume;
e) from 0% to about 10% by weight of an emulsifier;
f) from 0 to about 10% by weight of one or more adjuvants selected from the group consisting of dyes, opacifying agent, bluing agents and preservatives; and
g) balance water.
2. A fabric softening composition in accordance with claim 1 , which further contains (a) from 0% to about 1% by weight of an electrolyte; and (b) from 0% to about 10% by weight of a co-softener selected from the group consisting of fatty alcohol, glycerol monostearate and glycerol monooleate.
3. A fabric softener composition in accordance with claim 1 wherein said emulsifier is a fatty alcohol ethoxylate nonionic surfactant.
4. A fabric softening composition of claim 1 where said cationic linear polymer comprises a quaternary salt of acrylate or methacrylate.
5. A fabric softening composition of claim 1 where said cationic cross-linked polymer is a cross-linked vinyl polymer.
6. A fabric softening composition of claim 1 where said cationic cross-linked polymer comprises a quaternary salt of acrylare or methacrylate.
7. A fabric composition of claim 1 wherein said cationic softener is selected from the group consisting of quaternary ammonium compounds, esterquats, imidazolinium quats and difatty diamide ammonium methyl sulfate.
8. A fabric softening composition of claim 7 wherein said cationic softener comprises ditallow diester ammonium methosulfate.
9. A method for softening fabrics comprising forming an aqueous solution containing an effective amount of the fabric softening composition of claim 1 and then contacting the fabrics to be softened with said aqueous solution.