High OTR films made from homopolymer polypropylene and 1-butene/ethylene copolymer blends
A polyolefin blend having in a range of 40 to less than 90% by weight of a high modulus, isotactic polypropylene; and in a range of 10 to 60% by weight of a 1-butene/ethylene copolymer; the 1-butene/ethylene copolymer having about 0.5 to about 10 wt % of an ethylene. A polyolefin blend can be in a form of a transparent, oriented film having a biaxially oriented layer with an oxygen transmission rate of at least about 200 cc/100 sq. in./day/atmosphere (3077 cc/sq. m./24h/atmosphere), a tensile modulus of at least about 160,000 psi (1.103 GPa) and a haze value of no greater than about 3% measured at a thickness of about 1 mil (25 μm).
1. A biaxially oriented, transparent, multilayer packaging film, said film including a core layer and opposed, functional skin layers, said core layer including a blend comprising:
a) a high modulus polypropylene having an isotactic index of at least about 92% and being present in a range greater than 40% to less 90% by weight of the blend and
b) a 1-butene/ethylene copolymer in a range greater than 10% to less than 60% by weight of the blend, wherein the 1-butene/ethylene copolymer comprises about 0.5% to about 10 wt % of an ethylene; said core layer being biaxially oriented at a temperature resulting in said core layer having an oxygen transmission rate of at least about 200 cc/100 sq. in./day/atmosphere (3077 cc/sq. m./24 hr./atmosphere), a tensile modulus in at least one direction of at least about 160,000 psi (1.103 GPa) and a haze value of no greater than about 3% and wherein the oxygen transmission rate, the tensile modulus and the haze value are measured at a thickness of about 1 mil (25 μm); and
c) said functional skin layers being substantially thinner than said core layer.
2. The packaging film according to claim 1 , wherein the tensile modulus of the cover layer is at least about 180,000 psi (1.241 GPa).
3. The packaging film according to claim 1 , further including from 0 to about 20% by weight of a polyethylene in the polyolefin blend in the core.
4. The packaging film according to claim 3 , wherein the polyethylene is a metallocene linear low-density polyethylene having a density from about 0.9 to about 0.92 g/cc.
5. The packaging film according to claim 3 , wherein the polyolefin blend of the core layer comprises:
a) about 65% by weight of the high modulus, isotactic polypropylene;
b) about 25% by weight of the 1-butene/ethylene copolymer, wherein the melt index of the 1-butene/ethylene copolymer is about 45 dg/min, and wherein the 1-butene/ethylene copolymer comprises about 3.5% by weight of ethylene; and
c) about 10% by weight of the polyethylene, wherein the polyethylene is a metallocene linear low-density polyethylene having a density of about 0.917 g/cc.
6. The packaging film according to claim 1 , wherein the isotactic index is about 93% to about 98%.
7. The packaging film according to claim 1 , wherein the polypropylene has a melt flow rate of about 1 to about 10 dg/min.
8. The packaging film according to claim 1 , wherein the polypropylene has a melt flow rate of about 2 to about 3.5 dg/min.
9. The packaging film according to claim 1 , wherein the polypropylene is in a range greater than 40% to 75% by weight of the blend.
10. The packaging film according to claim 1 , wherein the polypropylene is about 60 to less than 75% by weight of the blend.
11. The packaging film according to claim 1 , wherein the melt index of the 1-butene/ethylene copolymer is about 2 to about 45 dg/min.
12. The packaging film according to claim 1 , wherein at least one of said functional skin layers is selected from the group consisting of a sealant layer, a print layer, and a slip layer.
13. The packaging film according to claim 1 , wherein the polyolefin blend in the core layer comprises:
a) about 75% by weight of the high modulus, isotactic polypropylene; and
b) about 25% by weight of the 1-butene/ethylene copolymer, wherein the melt index of the 1-butene/ethylene copolymer is about 45 dg/min, and wherein the 1-butene/ethylene copolymer comprises about 3.5% by weight of ethylene.
14. The packaging film according to claim 1 , wherein the polyolefin blend of the core layer comprises:
a) about 60% by weight of the high modulus, isotactic polypropylene; and
b) about 40% by weight of the 1-butene/ethylene copolymer, wherein the melt index of the 1-butene/ethylene copolymer is about 45 dg/min, and wherein the 1-butene/ethylene copolymer comprises about 3.5% by weight of ethylene.
15. The packaging film according to claim 1 , wherein the polyolefin blend of the core layer comprises:
a) about 60% by weight of the high modulus, isotactic polypropylene; and
b) about 40% by weight of the 1-butene/ethylene copolymer, wherein the 1-butene/ethylene copolymer comprises about 0.5% by weight of ethylene.
16. The packaging film according to claim 1 , wherein the film is oriented at an orientation temperature of at least 130° C.