Thermoplastic cellulose derivative composition and fiber comprising the same
A thermoplastic cellulose derivative composition of the present invention contains, as a main component, a cellulose ester having an aliphatic polyester side chain having a repeat unit having 2 to 5 carbon atoms, wherein a rate of heating loss at 200° C. is 5 wt % or less, a melt viscosity at 200° C. and 1000 sec −1 is 50 to 300 Pa·sec, and a melt tension at the time of take-up at 200° C. and 100 m/min is 0.1 to 40 mN. The present invention can provide excellent fiber products by melt spinning of the composition.
1. A method of producing a fiber comprising a thermoplastic cellulose composition, wherein the method comprises:
spinning out a thermoplastic cellulose mixed ester composition, having a melt viscosity determined at 200° C. and at a shear rate of 1000 sec −1 of 50 to 300 Pa·sec, and a melt tension of 0.1 to 40 mN at the time of take-up at 200° C. and 100 m/min, at a melting temperature of 180 to 240° C.;
converging the fiber with an oiling agent or water applied at a distance of 0.5 to 5 m from the bottom of a nozzle;
taking up a resultant yarn by a godet roller under a spinning tension of 0.1 to 3.0 mN/dtex; and then
winding the yarn on a package.
2. A method of producing a fiber comprising a thermoplastic cellulose mixed ester composition according to claim 1 , wherein a spinning draft is 30 to 300.
3. A method of producing a fiber comprising a thermoplastic cellulose mixed ester composition according to claim 1 , wherein thermoplastic cellulose mixed ester composition comprises 70 to 98% by weight of a cellulose mixed ester, and 1 to 30% by weight of a plasticizer having a molecular weight of 350 to 20,000.
4. A method of producing a fiber comprising a thermoplastic cellulose mixed ester composition according to claim 1 , wherein the fiber has a multifilament form.
5. A melt spun fiber comprising a thermoplastic cellulose mixed ester composition comprising a mixture of 70 to 98% by weight of a cellulose mixed ester, and 1 to 30% by weight of a plasticizer having a molecular weight of 350 to 20,000, and wherein the cellulose mixed ester is at least one selected from the group consisting of cellulose acetate propionate, cellulose acetate butyrate, and cellulose acetate phthalate.
6. A melt spun fiber comprising a thermoplastic cellulose mixed ester composition according to claim 5 , wherein the plasticizer is polylactic acid having a weight average molecular weight of 1,000 to 20,000.
7. A melt spun fiber comprising a thermoplastic cellulose mixed ester composition according to claim 5 , wherein the plasticizer is polyethylene glycol having a weight average molecular weight of 350 to 20,000.
8. A melt spun fiber comprising a thermoplastic cellulose mixed ester composition according to claim 5 , wherein the plasticizer is a glycerin ester having a molecular weight of 350 to 1,000.
9. A melt spun fiber comprising a thermoplastic cellulose mixed ester composition according to claim 5 , wherein the content of the plasticizer is 1 to 15% by weight based on the total amount of the composition, and the composition exhibits a rate of heating loss at 200° C. of 5 wt % or less.
10. A melt spun fiber comprising a thermoplastic cellulose mixed ester composition according to claim 5 , wherein the fiber has a strength of 0.5 to 4.0 cN/dtex, and an elongation of 2 to 50%.
11. The melt spun fiber comprising a thermoplastic cellulose mixed ester composition according to claim 5 , wherein the fiber has a strength of 1.2 to 4.0 cN/dtex.
12. A melt spun fiber comprising a thermoplastic cellulose mixed ester composition comprising a mixture of 70 to 98% by weight of a cellulose mixed ester, and 1 to 30% by weight of a plasticizer having a molecular weight of 350 to 20,000, and wherein the cellulose mixed ester is at least one selected from the group consisting of cellulose acetate propionate, cellulose acetate butyrate, and cellulose acetate phthalate, wherein the fiber has a multifilament form and wherein the filament has a constant size in the axial direction of the fiber, and the fiber has a U % of 0.1 to 2.5%.