Emollient carrier gel
A waxy solid having ultrafine particles homogeneously distributed in a mixture of vegetable oil and waxy solid, the oil being present in a major proportion by weight, forms a homogeneous colloidal solution which is then cooled and subjected to high shear to form ultrafine particles of the waxy solid, in situ, in a size range from about 0.1 μm to 10 μm. The resulting stiff gel retains its shape and high viscosity for at least 30 days when confined in a container in an air atmosphere at 40° C. at substantially sea level. The stability of the gel is visually evidenced by a lack of syneresis. The gel is destabilized at a temperature in the range from 52° C. (125° F.) to 100° C. (212° F.).
1. An essentially anhydrous, hydrophobic, substantially pigment free, homogeneous and stable carrier gel, free of synthetic oils, consisting of a minor proportion by weight of a waxy solid and a major proportion by weight of a naturally occurring vegetable oil, the gel being present as a colloid in which the dispersed phase of waxy solid particles has combined with the continuous phase of vegetable oil to produce a semi-solid material substantially free of any solvent, the gel having physical properties including viscosity, stability, emolliency and occlusivity similar to that of petrolatum so as to be a substitute for petrolatum but having a destabilization point in the range from 520° C. (125° F.) to 100° C. (212° F.).
2. The carrier gel of claim 1 wherein the vegetable oil includes from 0 to 15% by weight of a hydrogenated vegetable oil and the gel has particles of waxy solid in a size range from about 0.1 μm to 10 μm homogeneously distributed as a disperse phase the gel having a viscosity in the range from 10,000 cP at 25° C. measured with a T-A bar at 0.5 rpm. to about 100,000 cp at 25° C. measured with a T-F bar at 0.1 rpm. each measured with a Brookfield Model DV-II+ Viscometer on a Model D Helipath stand, the gel being stable for at least 30 days when confined in a container in an air atmosphere at 40° C. at substantially sea level.
3. The carrier gel of claim 1 wherein the vegetable oil is present in an amount in the range from about 55% to 95%, and the waxy solid is present in an amount in the range from about 5% to 40%.
4. The carrier gel of claim 3 wherein the vegetable oil is present in an amount in the range from about 60% to 90% by weight of the gel, and the waxy solid is present in an amount in the range from about 10% to 25%.
5. A method for preparing a carrier gel, comprising,
heating a mixture consisting of a minor proportion by weight of a waxy solid and a major proportion by weight of a vegetable oil substantially free of any solvent, to a temperature above the melting point of the waxy solid but below a temperature at which either of the components is degraded to form a homogeneous colloidal solution;
cooling the mixture to a temperature below about 38° C. (100° F.) to form a slurry having an initial viscosity in the range from about 2,000 cp to 50,000 cp at 25° C.; continuously mixing the slurry with sufficient energy to raise the temperature at least 5° C. to form a rheopectic mass and simultaneously cooling the mass to a temperature below 49° C. (120° F.);
thereafter cooling the rheopectic mass to ambient temperature; and,
recovering a cool and stable carrier gel having physical properties similar to that of petrolatum so as to be a substitute for petrolatum but having a destabilization point in the range from 52° C. (125° F.) to 100° C. (212° F.).
6. The method of claim 4 wherein the cool gel having no visible slump at 30° C. for a period of 24 hr, and a viscosity in the range from 10.000 cP at 25° C. measured with a T-A bar at 0.5 rpm, to about 100,000 cP at 25° C. measured with a T-F bar at 0.1 rpm, each measured with a Brookfield Model DV-II+ Viscometer on a Model D Helipath stand is held open to the atmosphere for at least 8 hr to enhance the stability of the gel.
7. The method of claim 4 including heating the mixture to a temperature from about 5° C. to 20° C. above the melting point of the waxy solid; and, wherein the vegetable oil is present in an amount in the range from about 55% to 95%, and the waxy solid is present in an amount in the range from about 5% to 45%.
8. An emollient carrier gel produced by heating a mixture consisting of a minor proportion by weight of a waxy solid and a major proportion by weight of a naturally occurring vegetable oil substantially free of any solvent, to a temperature above the melting point of the waxy solid but below a temperature at which either of the components is degraded to form a homogeneous colloidal solution;
cooling the mixture to a temperature below about 38° C. (100° F.) to form a slurry having an initial viscosity in the range from about 2,000 cp to 50,000 cp at 25° C.; continuously mixing the slurry with sufficient energy to raise the temperature at least 5° C. to form a rheopectic mass and simultaneously cooling the mass to a temperature below 49° C. (120° F.);
thereafter cooling the rheopectic mass to ambient temperature; and, recovering a cool and stable carrier gel having physical properties similar to that of petrolatum so as to be a substitute for petrolatum but having a destabilization point in the range from 52° C. (125° F.) to 100° C. (212° F.).
9. The carrier gel of claim 7 wherein the cool and stable gel is held open to the atmosphere for at least 8 hr to enhance the stability of the gel.
10. The carrier gel of claim 7 including heating the mixture to a temperature from about 5° C. to 20° C. above the melting point of the waxy solid; and, wherein the vegetable oil is present in an amount in the range from about 55% to 95%, and the waxy solid is present in an amount in the range from about 5% to 45%.