IP Library › Granted Patent US 7,112,380
Granted Patent B2
US 7,112,380 · App. 10/156,030 · Granted Sep 26, 2006

Method and apparatus for the storage and redistribution of electrical energy

Assignee: Casale Chemicals S.A.
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Quick Facts
Patent No.
US 7,112,380
App. No.
10/156,030
Granted
Sep 26, 2006
Kind
B2
Abstract

A method of storage and redistribution of electrical energy comprising the steps of: producing hydrogen and oxygen through water electrolysis in an electrolyzer ( 1 ) operating under pressure; collecting the hydrogen and oxygen so obtained in respective pressurized tanks ( 3, 5 ); reconverting into water and electrical energy hydrogen and oxygen, through an electrochemical reaction of the latter in a fuel cell ( 9 ) fed from the tanks ( 3, 5 ), distinguishes itself by the fact that in the electrolyzer ( 1 ) and in the fuel cell ( 9 ) a same liquid phase is used and by the fact that the water produced in the fuel cell ( 9 ) by the hydrogen and oxygen reconversion step, is collected in the respective liquid phase and transferred together with the liquid phase to the electrolyzer ( 1 ) in order to undergo electrolysis.

Claims (10)

1. Method of storage and redistribution of electrical energy comprising the steps of: producing hydrogen and oxygen through water electrolysis in an electrolyzer ( 1 ) operating under pressure; collecting the hydrogen and oxygen so obtained in respective pressurized tanks ( 3 , 5 ) said hydrogen and oxygen pressurized tanks ( 3 , 5 ) and said electrolyzer ( 1 ) all operating at substantially the same operating pressure; reconverting into water and electrical energy said hydrogen and said oxygen produced in said electrolyzer, through an electrochemical reaction of the latter in a fuel cell ( 9 ) fed from said tanks ( 3 , 5 ), and wherein said electrolyzer ( 1 ) and said fuel cell ( 9 ) use a single continuous liquid phase which is continuously circulated between the electrolyzer and the fuel cell and wherein the water produced in said fuel cell ( 9 ) by the hydrogen and oxygen reconversion step, is collected in the respective liquid phase and transferred together with the liquid phase to said electrolyzer ( 1 ) in order to undergo electrolysis.

2. Method according to claim 1 , characterized in that said reconversion of hydrogen and oxygen in said fuel cell ( 9 ) is carried out under pressure.

3. Method according to claim 2 , characterized in that the operating pressure of said fuel cell ( 9 ) is slightly lower than that of said electrolyzer ( 1 ).

4. Method according to claim 1 , characterized in that said electrolyzer ( 1 ) is in direct communication with said tanks ( 3 , 5 ), to which the hydrogen and oxygen obtained through water electrolysis are directly sent, and said tanks ( 3 , 5 ) are in direct communication with said fuel cell ( 9 ), the hydrogen being directly fed to the anodic compartments thereof and the oxygen to the cathodic compartments thereof, respectively.

5. Method according to claim 4 , characterized in that portions of the liquid phase of said electrolyzer ( 1 ) entrained into said tanks ( 3 , 5 ) by the hydrogen and oxygen, respectively, are separated and collected in the tanks themselves and recycled to said electrolyzer ( 1 ), after having been cooled in an appropriate heat exchanger ( 7 ).

6. Method according to claim 4 , characterized in that the hydrogen and oxygen in excess fed to said fuel cell ( 9 ) are discharged from the cell itself, whereby portions of liquid phase entrained in hydrogen and oxygen are separated, said portions being recycled in part to said cell ( 9 ) and in part to said electrolyzer ( 1 ), after having been cooled or warmed in respective heat exchangers ( 19 , 7 ).

7. Method according to claim 1 , characterized in that said liquid phase consists of an alkaline aqueous solution.

8. Method according to claim 7 , characterized in that said liquid phase consists of water or aqueous solutions of electrolytes, among which there are preferably strong alkalis.

9. Apparatus for the storage and redistribution of electrical energy, wherein it comprises a water electrolyzer ( 1 ) provided with a respective liquid phase and operating under a predetermined pressure, pressurized tanks ( 3 , 5 ) said hydrogen and oxygen pressurized tanks ( 3 , 5 ) and said elctrolyzer ( 1 ) all operating at substantially the same operating pressure in direct fluid communication with said electrolyzer ( 1 ) in order to directly receive from it hydrogen and oxygen flows, respectively, a fuel cell ( 9 ), provided with a respective liquid phase and operating under a predetermined pressure, said cell ( 9 ) having anodic and cathodic compartments in direct fluid communication with said hydrogen and oxygen tanks ( 3 , 5 ) in order to exclusively receive said hydrogen and said oxygen produced in said electrolyzer ( 1 ), respectively, and in direct fluid communication with said electrolyzer ( 1 ), said electrolyzer ( 1 ) and said cell ( 9 ) using a single continuous liquid phase which is continuously circulated between the electrolyzer and the fuel cell.

10. Apparatus according to claim 9 , characterized in that said mutually directly interconnected electrolyzer ( 1 ), fuel cell ( 9 ) and tanks ( 3 , 5 ) are grouped in a single unit.

Assignments (2)
RE-RECORD TO CORRECT THE CONVEYING AND RECEIVING PARTY'S, PREVIOUSLY RECORDED AT REEL 013257, FRAME 0633. Recorded Apr 9, 2003
From: SIOLI, GIANCARLO
To: CASALE CHEMICALS S.A.
Reel/Frame 013942/0296 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 3, 2002
From: GIANCARLO, SIOLI
To: CASALE CHEMICALS SA
Reel/Frame 013257/0633 →
Priority Claims (1)
EP 01113229 · May 30, 2001 · regional
Continuity (1)
Related Publication 20020195349A1 · Dec 26, 2002