Hydroprocessing process
A process for hydroprocessing a hydrocarbon feedstock includes the steps of providing a hydrocarbon feed having an initial characteristic; providing a first hydrogen-containing gas; feeding the hydrocarbon feed and the first hydrogen-containing gas cocurrently to a first hydroprocessing zone so as to provide a first hydrocarbon product; providing a plurality of additional hydroprocessing zones including a final zone and an upstream zone; feeding the first hydrocarbon product cocurrently with a recycled gas to the upstream zone so as to provide an intermediate hydrocarbon product; and feeding the intermediate hydrocarbon product cocurrently with a second hydrogen-containing gas to the final zone so as to provide a final hydrocarbon product having a final characteristic which is improved as compared to the initial characteristic.
1. A process for hydroprocessing a hydrocarbon feedstock, comprising the steps of:
providing a hydrocarbon feed having an initial sulfur content;
providing a first hydrogen-containing gas;
feeding said hydrocarbon feed and said first hydrogen-containing gas cocurrently to a first hydroprocessing zone so as to provide a first hydrocarbon product;
providing a plurality of additional hydroprocessing zones including a final zone and an upstream zone;
feeding said first hydrocarbon product cocurrently with a recycled gas to said upstream zone so as to provide an intermediate hydrocarbon product; and
feeding said intermediate hydrocarbon product cocurrently with a second hydrogen-containing gas to said final zone so as to provide a final hydrocarbon product having a final sulfur content which is less than said initial sulfur content wherein said final zone also produces a hydrogen-containing gas phase, and further comprising feeding said hydrogen-containing gas phase to said upstream zone as said recycled gas.
2. The process according to claim 1 , wherein said final sulfur content is less than or equal to about 10 wppm based upon weight of said final product.
3. The process according to claim 1 , wherein said first hydroprocessing zone is a first hydrodesulfurization zone.
4. The process according to claim 3 , wherein said additional hydroprocessing zones comprise additional hydrodesulfurization zones.
5. The process according to claim 4 , wherein said first hydrodesulfurization zone and said upstream hydrodesulfurization zone each produce a gas phase containing hydrogen sulfide hydrogen and volatile hydrocarbon fractions and further comprising feeding said gas phase to a low temperature separator for separating a liquid phase containing said volatile hydrocarbon fractions and a gas phase containing said hydrogen sulfide and hydrogen, and combining said volatile hydrocarbon fractions with said hydrocarbon feed.
6. The process according to claim 1 , wherein said first hydrogen-containing gas and said second hydrogen-containing gas are separate quantities of fresh hydrogen-containing gas, and wherein said recycled gas contains contaminant removed from said intermediate hydrocarbon product.
7. The process according to claim 1 , wherein each of said first hydroprocessing zone and said plurality of additional zones contains a hydroprocessing catalyst.
8. The process according to claim 1 , wherein said hydrocarbon feed is a Diesel feed.
9. The process according to claim 1 , wherein said hydrocarbon feed is a gasoil feed.
10. The process according to claim 1 , wherein said hydrocarbon feed is a naphtha feed, and further comprising feeding a product of said first hydroprocessing zone and said plurality of additional hydroprocessing zones to a condenser for providing liquid phase naphtha and gas phase hydrogen and hydrogen sulfide.