Method of treating digested sludge
A method of treating, in wastewater purification, sludge containing organic matter, divalent iron and phosphorus, in which the sludge that is treated is made to contain dissolved iron and phosphorus at a molar ratio Fe:P of above 1:1, the sludge is treated at 0–100° C. with an acid at a pH of 1–5 for dissolution of divalent iron and phosphorus from the sludge, the sludge is supplied with an oxidizer selected from hydrogen peroxide and percompounds, wherein divalent iron is oxidized by Fenton's reaction to trivalent iron, and (i) trivalent iron is precipitated as trivalent iron phosphate (ii) free radicals with a deodorization and sanitation effect are formed by Fenton's reaction, the sludge is then dewatered at a pH of at most 7, and the aqueous solution obtained in dewatering is recirculated to the wastewater purification.
1. A method of treating, in wastewater purification, sludge containing organic matter, divalent iron and phosphorus, comprising:
treating the sludge so that it contains dissolved iron and phosphorus at a molar ratio Fe:P of above 1:1;
treating the sludge at 0–100° C. with an acid, wherein a pH of 1–5 is achieved for dissolution of divalent iron and phosphorus from the sludge;
supplying the sludge with an oxidizer or mixture of oxidizers selected from hydrogen peroxide and percompounds, whereby divalent iron is oxidized by Fenton's reaction to trivalent iron; and
(i) trivalent iron is precipitated as trivalent iron phosphate particles to promote improved dewatering of the sludge;
(ii) free radicals with a deodorisation and sanitation effect are formed by Fenton's reaction;
dewatering the sludge at a pH of at most 7; and
recirculating the aqueous solution obtained in dewatering to the wastewater purification.
2. A method as claimed in claim 1 , wherein the sludge is acid treated with sulphuric acid, formic acid or oxalic acid.
3. A method as claimed in claim 1 or 2 , wherein the sludge is acid treated for 10 min to 2 h.
4. A method as claimed in claim 1 , wherein the sludge that is treated is made to contain iron and phosphorus at a molar ratio Fe:P from above 1:1 to 1.5:1.
5. A method as claimed in claim 1 , wherein the sludge is supplied with additional divalent iron before the adding of an oxidizer.
6. A method as claimed in claim 1 , wherein the oxidizer or mixture of oxidizers is selected from at least one of hydrogen peroxide, sodium percarbonate and peracetic acid.
7. A method as claimed in claim 1 , wherein the oxidizer is hydrogen peroxide.
8. A method as claimed in claim 1 , wherein the sludge is supplied with hydrogen peroxide as an oxidizer in an amount of 10–100 kg, 100% hydrogen peroxide per tonne of dry solids.
9. The method according to claim 8 , wherein the amount of hydrogen peroxide is 30–60 kg, 100% hydrogen peroxide per tonne of dry solids.
10. A method as claimed in claim 1 , wherein the sludge is supplied with a dewatering aid before dewatering.
11. A method as claimed in claim 1 , wherein the sludge is predewatered with a centrifuge or a rotary screen.
12. A method as claimed in claim 1 , wherein the sludge is finally dewatered with a centrifuge, screw press, chamber filter press or band filter press.
13. A method as claimed in claim 1 , wherein the sludge is dewatered to a solids content of at least 30% by weight.
14. A method as claimed in claim 1 , wherein the sludge is dewatered to a solids content of 35–60% by weight.