Mouth guard and sheet for mouth guard
A mouth guard which is excellent in impact absorbability and durability, is thin and has good fittability, and is able to easily chew thereupon, and does not give vomiting feel; and a sheet for mouth guard which is suitable for producing the mouth guard. The mouth guard or the sheet for mouth guard comprises at least one block copolymer selected from the group consisting of a block copolymer (a-1) comprising polymer blocks A made of a vinyl aromatic compound, and polyisoprene blocks B having a content of 1,2-bonds and 3,4-bonds of 40% by mol or more; a block copolymer (a-2) comprising polymer blocks A, and polymer blocks C which contain an isoprene unit and a butadiene unit in a ratio of from 5/95 to 95/5 (% by weight) and have a content of 1,2-bonds and 3,4-bonds of 40% by mol or more; and a block copolymer (a-3) comprising polymer blocks A, and polybutadiene blocks D having a content of 1,2-bonds of 60% by mol or more, wherein a content of vinyl aromatic compound units in each of the copolymers is from 10 to 40% by weight, and a hydrogenated product thereof (b-1) to (b-3).
1. A mouth guard comprising 85% by weight or more of at least one block copolymer selected from the group consisting of:
a block copolymer (a-1) comprising one or more polymer blocks A made of a vinyl aromatic compound, and one or more polyisoprene blocks B having a content of 1,2-bonds and 3,4-bonds of 40% by mol or more, wherein a content of vinyl aromatic compound units is from 10 to 40% by weight, and a hydrogenated product thereof (b-i);
a block copolymer (a-2) comprising one or more polymer blocks A made of a vinyl aromatic compound, and one or more polymer blocks C which contain an isoprene unit and a butadiene unit in a ratio of from 5/95 to 95/5 (% by weight) and have a content of 1,2-bonds and 3,4-bonds of 40% by mol or more, wherein a content of vinyl aromatic compound units is from 10 to 40% by weight, and a hydrogenated product thereof (b-2); and
a block copolymer (a-3) comprising one or more polymer blocks A made of a vinyl aromatic compound, and one or more polybutadiene blocks D having a content of 1,2-bonds of 60% by mol or more, wherein a content of vinyl aromatic compound units is from 10 to 40% by weight, and a hydrogenated product thereof (b-3).
2. A sheet for mouth guard comprising 85% by weight or more of at least one block copolymer selected from the group consisting of:
a block copolymer (a-1) comprising one or more polymer blocks A made of a vinyl aromatic compound, and one or more polyisoprene blocks B having a content of 1,2-bonds and 3,4-bonds of 40% by mol or more, wherein a content of vinyl aromatic compound units is from 10 to 40% by weight, and a hydrogenated product thereof (b-1);
a block copolymer (a-2) comprising one or more polymer blocks A made of a vinyl aromatic compound, and one or more polymer blocks C which contain an isoprene unit and a butadiene unit in a ratio of from 5/95 to 95/5 (% by weight) and have a content of 1,2-bonds and 3,4-bonds of 40% by mol or more, wherein a content of vinyl aromatic compound units is from 10 to 40% by weight, and a hydrogenated product thereof (b-2); and
a block copolymer (a-3) comprising one or more polymer blocks A made of a vinyl aromatic compound, and one or more polybutadiene blocks D having a content of 1,2-bonds of 60% by mol or more, wherein a content of vinyl aromatic compound units is from 10 to 40% by weight, and a hydrogenated product thereof (b-3).
3. The mouth guard as claimed in claim 1 , comprising 90% by weight or more of said at least one block copolymer.
4. The mouth guard as claimed in claim 1 , wherein the polymer blocks A in block copolymers (a-1), (a-2) and (a-3) comprise at least one vinyl aromatic compound selected from the group consisting of styrene, α-methylstyrene, 1-vinylnaphthalene, 3-methylstyrene, 4-propylstyrene, 4-cyclohexylstyrene, 4-dodecyistyrene, 2-ethyl-4-benzylstyrene, and 4-(phenylbutyl)styrene.
5. The mouth guard as claimed in claim 1 , wherein the polymer blocks A in block copolymers (a-1), (a-2) and (a-3) comprise styrene.
6. The mouth guard as claimed in claim 1 , wherein the number-average molecular weight of polymer block A in block copolymers (a-1), (a-2) and (a-3) is within a range of from 2500 to 50000.
7. The mouth guard as claimed in claim 1 , wherein the number-average molecular weight of polymer block A in block copolymers (a-1), (a-2) and (a-3) is within a range of from 2500 to 20000.
8. The mouth guard as claimed in claim 1 , wherein said block copolymer comprises at least one polyisoprene block B, and wherein said polyisoprene blocks B have a content of 1,2-bonds and 3,4-bonds of 45 to 90% by mol.
9. The mouth guard as claimed in claim 1 , wherein said block copolymer comprises at least one polyisoprene block B, and wherein said polyisoprene blocks B have a content of 1,2-bonds and 3,4-bonds of from 50 to 80% by mol.
10. The mouth guard as claimed in claim 8 , wherein the number-average molecular weight of polymer block B is within a range of from 10000 to 300000.
11. The mouth guard as claimed in claim 9 , wherein the number-average molecular weight of polymer block B is within a range of from 100000 to 200000.
12. The mouth guard as claimed in claim 1 , wherein said block copolymer comprises at least one block C, said blocks C have content of 1,2-bonds and 3,4-bonds of 45% by mol or more, and wherein said isoprene units and butadiene units are contained in a ratio of from 10/90 to 90/10 (% by weight).
13. The mouth guard as claimed in claim 12 , wherein the number-average molecular weight of polymer block C is within a range of from 10000 to 300000.
14. The mouth guard as claimed in claim 12 , wherein the number-average molecular weight of polymer block C is within a range of from 10000 to 200000.
15. The mouth guard as claimed in claim 1 , wherein said block copolymer comprises at least one block D, said blocks D have a content of 1,2-bonds of 80% by mol or more.
16. The mouth guard as claimed in claim 1 , wherein said block copolymer comprises at least one block D, said blocks D have a content of 1,2-bonds of 85% by mol or more.
17. The mouth guard as claimed in claim 15 , wherein the number-average molecular weight of polymer block D is within a range of from 10000 to 300000.
18. The mouth guard as claimed in claim 16 , wherein the number-average molecular weight of polymer block D is within a range of from 10000 to 200000.
19. The mouth guard as claimed in claim 1 , comprising 90% by weight or more of said at least one block copolymer, wherein:
the polymer blocks A in block copolymers (a-1), (a-2) and (a-3) comprise at least one vinyl aromatic compound selected from the group consisting of styrene, a-methylstyrene, 1-vinylnaphthalene, 3-methyistyrene, 4-propyistyrene, 4-cyclohexyistyrene, 4-dodecyistyrene, 2-ethyl-4-benzylstyrene, and 4-(phenylbutyl)styrene;
the number-average molecular weight of polymer block A in block copolymers (a-1), (a-2) and (a-3) is within a range of from 2500 to 50000;
said polyisoprene blocks B have a content of 1,2-bonds and 3,4-bonds of 45 to 90% by mol;
the number-average molecular weight of polymer block B is within a range of from 10000 to 300000;
said blocks C have content of 1,2-bonds and 3,4-bonds of 45% by mol or more, and said isoprene units and butadiene units are contained in a ratio of from 10/90 to 90/10 (% by weight);
the number-average molecular weight of polymer block C is within a range of from 10000 to 300000;
said blocks D have a content of 1,2-bonds of 80% by mol or more; and
the number-average molecular weight of polymer block D is within a range of from 10000 to 300000.