Recyclable carpet comprising hot melt adhesive composition
A hot melt adhesive is provided that is useful in the production of textiles, such as a tuft carpet, contains a blend of constituents that allows synthetic carpet members to be fully recycled without first separating the adhesive from the carpet members. The adhesive includes (a) from about 5 to about 30 weight % of a copolymer of an alkyl acrylate having from 2 to 18 carbon atoms; (b) from about 5 to about 50 weight % of a wax and desirably a C10 wax; (c) up to about 75 weight % of a filler; and (d) from about 0.1 to about 10 weight % of an aliphatic carboxylic acid having from 8 to 24 carbon atoms.
1. A multi-layer laminated article comprising:
a first layer selected from the group consisting of polypropylene and polyamides; and
a second layer comprising a hot melt adhesive composition which comprises:
i) from about 5 to about 30 weight % of at least one copolymer of an alkyl acrylate selected from the group consisting of methyl acrylate, ethylene (meth)acrylate, propyl acrylate, butyl (meth)acrylate, hexyl acrylate, 2-ethylhexyl acrylate, dodecyl acrylate, lauryl acrylate, stearyl acrylate and mixtures thereof;
ii) from about 5 to about 50 weight % of a wax having from 6 to 20 carbon atoms;
iii) up to about 75 weight % of a filler; and
iv) from about 0.1 to about 10 weight % of an aliphatic carboxylic acid having from 8 to 32 carbon atoms.
2. The multi-layer laminated article of claim 1 , wherein said wax is selected from the group consisting of paraffin waxes, microcrystalline waxes, high density low molecular weight polyethylene waxes, by-product polyethylene waxes, Fischer-Tropsch waxes, oxidized Fischer Tropsch waxes, hydroxy waxes, stearamide waxes, and mixtures thereof.
3. The multi-layer laminated article of claim 1 , wherein said filler is from about 25 to 65 weight % of the composition and is selected from the group consisting of calcium carbonate, clay, magnesium carbonate, calcium sulfate, alumina, talc, barium sulfate, silica, carbon black, aluminum hydroxide, magnesium hydroxide, and mixtures thereof.
4. The multi-layer laminated article of claim 1 , wherein said carboxylic acid has from 12 to 18 carbon atoms.
5. A recyclable carpet comprising:
a first layer selected from the group consisting of polypropylene and polyamides; and
a second layer comprising a hot melt adhesive composition which comprises:
i) from about 5 to about 30 weight % of at least one copolymer of an alkyl acrylate selected from the group consisting of methyl acrylate, ethylene (meth)acrylate, propyl acrylate, butyl (meth)acrylate, hexyl acrylate, 2-ethylhexyl acrylate, dodecyl acrylate, lauryl acrylate, stearyl acrylate and mixtures thereof;
ii) from about 5 to about 50 weight % of a wax having from 6 to 20 carbon atoms;
iii) up to about 75 weight % of a filler; and
iv) from about 0.1 to about 10 weight % of an aliphatic carboxylic acid having from 8 to 32 carbon atoms.
6. The recyclable carpet of claim 5 , wherein said wax is selected from the group consisting of high density low molecular weight polyethylene waxes, and by-product polyethylene waxes having from 6 to 15 carbon atoms, from about 25 to 65 weight % filler, and said aliphatic carboxylic acid is from about 1 to about 5 weight % stearic acid.
7. The recyclable carpet of claim 5 , further comprising tufts of yarn secured into the first layer.
8. A carpet comprising:
a first layer selected from the group consisting of polypropylene and polyamides; and
a second layer laminated to the first layer and comprising a hot melt adhesive composition which comprises:
i) between 5 and 30 weight % of at least one copolymer of an alkyl acrylate selected from the group consisting of methyl acrylate, ethylene (meth)acrylate, propyl acrylate, butyl (meth)acrylate, hexyl acrylate, 2-ethylhexyl acrylate, dodecyl acrylate, lauryl acrylate, stearyl acrylate and mixtures thereof;
ii) between 5 and 50 weight % of a wax having from 6 to 20 carbon atoms;
iii) less than 75 weight % of a filler; and
iv) between 0.1 and 10 weight % of an aliphatic carboxylic acid having from 8 to 32 carbon atoms.
9. The carpet of claim 8 , further comprising tufts of yarn secured into the first layer.
10. The multi-layer laminated article of claim 1 , wherein said carboxylic acid comprises stearic acid.
11. The carpet of claim 8 , wherein said carboxylic acid comprises stearic acid.
12. The multi-layer laminated article of claim 1 , wherein the hot melt adhesive composition further comprises a plasticizer.