Low temperature air separation process for producing pressurized gaseous product
View Patent ↗An apparatus and process for producing pressurized gaseous product by air separation. A compressed air stream is cooled in an exchanger to form a compressed cooled air stream. The stream is then cryogenically compressed in a first compressor to form a first pressurized gas stream. The first pressurized gas stream is further cooled in the exchanger, cryogenically compressed in a second compressor, and then it is cooled and partially liquefied. The cooled and partially liquefied product is then fed to a system of distillation columns. A liquid product is removed from the system of distillation columns. This product is then pressurized, vaporized and warmed in the exchanger to yield pressurized gaseous product.
1. A method of low temperature air separation which may be used for producing pressurized gaseous product comprising:
a) cooling a compressed air stream in an exchanger to form a compressed cooled air stream;
b) forming a first pressurized gas stream by cryogenically compressing at least a portion of said compressed cooled air stream in a first compressor, wherein said first compressor comprises a first inlet temperature;
c) cooling at least a portion of said first pressurized gas stream in said exchanger to form a first cooled pressurized gas stream;
d) forming a second pressurized gas stream by cryogenically compressing at least a portion of said first cooled pressurized gas stream in a second compressor, said second compressor comprising a second inlet temperature;
e) cooling and at least partially liquefying said second pressurized gas stream;
f) feeding said cooled, partially liquefied second pressurized gas stream to a system of at least one distillation column;
g) feeding said distillation column system with a liquid feed stream;
h) extracting a liquid product from said distillation column system;
i) pressurizing at least part of said liquid product;
j) vaporizing at least part of said liquid product; and
k) warming at least part of said liquid product in said exchanger to yield a pressurized gaseous product.
2. The method of claim 1 , wherein said liquid feed stream comprises liquid air.
3. The method of claim 1 , wherein said liquid feed stream further comprises at least one component of air.
4. The method of claim 2 , wherein said liquid product comprises at least one member selected from the group consisting of:
a) nitrogen;
b) oxygen; and
b) argon.
5. The method of claim 1 , wherein said liquid product comprises at least one member selected from the group consisting of:
a) oxygen; and
b) nitrogen.
6. The method of claim 1 , wherein said first inlet temperature is about the boiling temperature of said liquid product.
7. The method of claim 1 wherein said second inlet temperature is about the boiling temperature of said vaporized liquid product.
8. The method of claim 1 wherein all said cooling is performed in the absence of turboexpansion.
9. The method of claim 1 wherein at least part of said liquid feed stream originates from a storage means.
10. A method of low temperature air separation which may be used for producing pressurized gaseous product comprising:
a) performing the following actions during a first period when the cost of electricity is above a predetermined threshold, said first period actions comprising:
1) cooling a compressed air stream in an exchanger to form a compressed cooled air stream;
2) forming a first pressurized gas stream by cryogenically compressing at least a portion of said compressed cooled air stream in a first compressor, wherein said first compressor comprises a first inlet temperature;
3) cooling at least a portion of said first pressurized gas stream in said exchanger to form a first cooled pressurized gas stream;
4) forming a second pressurized gas stream by cryogenically compressing at least a portion of said first cooled pressurized gas stream in a second compressor, said second compressor comprising a second inlet temperature;
5) cooling and at least partially liquefying said second pressurized gas stream;
6) feeding said cooled, partially liquefied second pressurized gas stream to a system of at least one distillation column;
7) feeding said distillation column system with a liquid feed stream;
8) extracting a liquid product from said distillation column system;
9) pressurizing at least part of said liquid product;
10) vaporizing at least part of said liquid product; and
11) warming at least part of said liquid product in said exchanger to yield a pressurized gaseous product; and
b) producing at least part of said liquid feed stream during a second period when the cost of electricity is below said predetermined level.
11. An apparatus which may be used for producing pressurized gaseous product comprising:
a) a system of at least one distillation column;
b) a conduit for feeding a liquid stream to said distillation column system, wherein said liquid stream is derived from air;
c) a heat exchanger comprising a warm end and a cold end;
d) a first compressor comprising a first inlet temperature;
e) a second compressor comprising a second inlet temperature;
f) a conduit for feeding a compressed air stream to said exchanger;
g) a conduit for removing a compressed cooled air from at least one member selected from the group consisting of:
i) an intermediate part of said exchanger; and
ii) the cold end of said exchanger;
h) a conduit for sending said compressed cooled air to said first compressor to create a first pressurized gas stream;
i) a conduit for sending at least a portion of said first pressurized gas stream to said exchanger to form a first cooled pressurized gas stream;
j) a conduit for sending at least a portion of said first cooled pressurized gas from said exchanger to said second compressor to form a second pressurized gas stream;
k) a conduit for sending at least part of said second pressurized gas stream to said exchanger;
l) a conduit for removing at least part of said second pressurized gas stream and feeding said second pressurized gas stream to said distillation column system;
m) a conduit for sending a liquid feed stream to said distillation column system;
n) a conduit for removing a liquid stream from said distillation column system;
o) a means for pressurizing at least part of said removed liquid stream to form a pressurized liquid stream; and
p) a conduit for sending at least part of said pressurized liquid stream to said exchanger.
12. The apparatus of claim 11 , further comprising a means for sending gaseous cooled compressed air from said exchanger to said distillation column system.
13. The apparatus of claim 11 , further comprising:
a) at least one turboexpander; and
b) a conduit for feeding a fluid from said distillation column system to said turboexpander.
14. The apparatus of claim 11 , further comprising:
a) a storage tank for said liquid feed stream produced by said distillation column system; and
b) a conduit to connect said storage tank to at least one member selected from the group consisting of:
1) said exchanger; and
2) said distillation column system.
15. The apparatus of claim 11 , further comprising:
a) a storage tank for storing said liquid feed stream;
b) a conduit said storage tank to an external source of liquid; and
c) a conduit connecting said storage tank to said distillation column system.