Iron-based sintered alloy material for valve seat
View Patent ↗An iron-based sintered alloy material for a valve seat having improved wear resistance and reduced opposite aggressibility to a mating valve. The iron-based sintered alloy material contains 10% to 20% by area of first hard particles and 15% to 35% by area of second hard particles dispersed in a base matrix phase, the first and the second hard particles accounting for 25% to 55% by area in total. The first hard particles are composed of a cobalt-based intermetallic compound and have a size of 10 to 150 μm and a hardness of at least 500HV0.1 and less than 800HV0.1. The second hard particles are composed of a cobalt-based intermetallic compound and have a size of 10 to 150 μm and a hardness of at least 800HV0.1 and less than 1100HV0.1. Solid lubricant particles may also be dispersed in the base matrix phase.
1. An iron-based sintered alloy material for a valve seat, comprising:
a base matrix phase;
first hard particles; and
second hard particles,
wherein the first hard particles and the second hard particles have different hardness and are dispersed in the base matrix phase, the first hard particles are composed of a cobalt-based intermetallic compound and have a size of 10 to 150 μm and a hardness of 500HV0.1 or more and less than 800HV0.1, the second hard particles are composed of a cobalt-based intermetallic compound and have a size of 10 to 150 μm and a hardness of 800HV0.1 or more and less than 1100HV0.1, the first hard particles occupy 10% to 20% by area, the second hard particles occupy 15% to 35% by area, and the first hard particles and the second hard particles occupy 25% to 55% by area in total.
2. The iron-based sintered alloy material for a valve seat according to claim 1 , wherein the first hard particles contain 0.5% to 4.0% by mass of Si, 5.0% to 20.0% by mass of Cr, and 20.0% to 40.0% by mass of Mo, the balance being Co and unavoidable impurities, and the second hard particles contain 0.5% to 4.0% by mass of Si, 5.0% to 20.0% by mass of Ni, 15.0% to 35.0% by mass of Cr, and 15.0% to 35.0% by mass of Mo, the balance being Co and unavoidable impurities.
3. The iron-based sintered alloy material for a valve seat according to claim 1 or 2 , wherein a base matrix, which is composed of the base matrix phase and the first and the second hard particles, contains 0.5% to 3.0% by mass of C, 0.5% to 2.0% by mass of Si, 2.0% to 8.0% by mass of Ni, 3.0% to 13.0% by mass of Cr, 7.0% to 15.0% by mass of Mo, 0.5% to 4.0% by mass of Cu, and 12.0% to 26.0% by mass of Co, the balance being Fe and unavoidable impurities.
4. The iron-based sintered alloy material for a valve seat according claim 1 or 2 , wherein, in addition to the first hard particles and the second hard particles, 0.2% to 3.0% by area of solid lubricant particles are dispersed in the base matrix phase.
5. A valve seat composed of the iron-based sintered alloy material according to claim 1 or 2 .
6. The iron-based sintered alloy material for a valve seat according to claim 3 , wherein, in addition to the first hard particles and the second hard particles, 0.2% to 3.0% by area of solid lubricant particles are dispersed in the base matrix phase.
7. A valve seat composed of the iron-based sintered alloy material according to claim 3 .
8. A valve seat composed of the iron-based sintered alloy material according to claim 4 .
9. A valve seat composed of the iron-based sintered alloy material according to claim 6 .