Method for producing pulp

1. A method for pulping a fibrous lignocellulose material, the method comprising the steps of:

(a) reducing the material to a size appropriate for pulping;

(b) cooking the reduced material with oxalic acid at an amount between 0.05% and about 6% of the dry weight of the reduced material, wherein the material is cooked at a temperature between greater than 100° C. and about 140° C. for a time between greater than 10 minutes and about 180 minutes, these conditions being sufficient for cooking the reduced material in such a manner so as to enable step (c);

(c) mechanically defiberizing the cooked material; and

(d) mechanically refining the defiberized material to produce a pulp that exhibits improved paper strength and energy savings relative to uncooked pulp, wherein the material is wood or a recovered paper capable of being processed into pulp for making paper products.

2. The method of claim 1 wherein the oxalic acid is at an amount between about 0.5% and about 5% of the dry weight of the reduced material.

3. The method of claim 1 wherein the oxalic acid is at an amount between about 1% and about 3% of the dry weight of the reduced material.

4. The method of claim 1 wherein the cooked material is refined using either a mechanical pulping method or a thermo-mechanical pulping method.

5. The method of claim 1 wherein the material is cooked at a temperature of between greater than 100° C. and about 130° C.

6. A method for pulping a fibrous lignocellulose material, the method comprising the steps of:

(a) reducing the material to a size appropriate for pulping;

(b) cooking the reduced material with oxalic acid at an amount between 0.05% and about 6% of the dry weight of the reduced material, wherein the material is cooked at a temperature between greater than 100° C. and about 140° C. for a time between greater than 10 minutes and about 180 minutes. these conditions being sufficient for cooking the reduced material in such a manner so as to enable step (d):

(c) further cooking the reduced material with sodium bisulfite at an amount between greater than about 1% and about 8% of the dry weight of the reduced material; and

(d) mechanically refining the cooked material into a pulp, such that the pulp product exhibits improved paper strength and energy savings relative to uncooked pulp, wherein the material is wood.

7. The method of claim 6 wherein the sodium bisulfite is at an amount between about 4% and about 8% of the dry weight of the reduced material.

8. The method of claim 6 wherein the sodium bisulfite is at an amount between about 5% and about 7% of the dry weight of the reduced material.

9. The method of claim 6 wherein the sodium bisulfite is at an amount of about 6% of the dry weight of the reduced material.

10. A method for producing pulp from a fibrous lignocellulose material, the method comprising the steps of:

(a) reducing the material to a size appropriate for pulping;

(b) mixing the reduced material with oxalic acid dihydrate at an amount between 0.05% and about 6% of the dry weight of the reduced material;

(c) cooking the mixture in the presence of pressurized steam, wherein the pressure is less than about 30 p.s.i.g, the conditions of steps (b) and (c) being sufficient to enable defiberization of the cooked material;

(d) defiberizing the cooked material using a thermo-mechanical fiberizer; and

(e) mechanically refining the defiberized material to produce a pulp that exhibits improved paper strength and energy savings relative to uncooked pulp, wherein the material is wood or a recovered paper capable of being processed into pulp for making paper products.

11. The method of claim 10 wherein the oxalic acid dihydrate is at an amount between about 0.5% and about 5% of the dry weight of the reduced material.

12. The method of claim 10 wherein the oxalic acid dihydrate is at an amount between about 1% and about 3% of the dry weight of the reduced material.

13. The method of claim 10 wherein the reduced material is further mixed with sodium bisulfite at an amount between greater than about 1% and about 8% of the dry weight of the reduced material.

14. The method of claim 13 wherein the sodium bisulfite is at an amount between about 4% and about 8% of the dry weight of the reduced material.

15. The method of claim 13 wherein the sodium bisulfite is at an amount between about 5% and about 7% of the dry weight of the reduced material.

16. The method of claim 13 wherein the sodium bisulfite is at an amount of about 6% of the dry weight of the reduced material.

17. The method of claim 10 wherein the mixture is steam heated at a pressure of about 25 p.s.i.g.

18. The method of claim 10 wherein the defiberized material is refined using either a mechanical pulping method or a thermo-mechanical pulping method.

19. A method for pulping wood material, the method comprising the steps of:

(a) reducing the material to a size appropriate for pulping;

(b) cooking the reduced material with oxalie acid at an amount between about 0.05% and about 6% of the dry weight of the reduced material, wherein the material is cooked at a temperature between greater than 100° C. and about 140° C. for a time between greater than 3 minutes and about 180 minutes, these conditions being sufficient for cooking the reduced material in such a manner so as to enable step (c); and

(c) mechanically defiberizing the cooked material; and

(d) mechanically refining the defiberized material to produce a pulp that exhibits improved paper strength and enemy savings relative to uncooked pulp, wherein the material is hardwood or softwood.

20. The method of claim 19 wherein the material originates from either round wood or wood residue.

21. The method of claim 19 wherein the wood is selected from the group consisting of Southern Yellow Pine, Spruce, Western Hemlock and Aspen.

22. A method for pulping recovered paper material, the method comprising the steps of:

(a) reducing the material to a size appropriate for pulping;

(b) cooking the reduced material with oxalic acid at an amount between about 0.05% and about 6% of the dry weight of the reduced material, wherein the material is cooked at a temperature between greater than 100° C. and about 140° C. for a time between greater than 3 minutes and about 180 minutes, these conditions being sufficient for cooking the reduced material in such a manner so as to enable step (c); and

(c) mechanically refining the cooked material into a pulp, such that the pulp product exhibits improved paper strength and energy savings relative to uncooked pulp, wherein the material includes pre-consumer recovered paper selected from the group consisting of trimmings and scraps from printing, carton manufacturing, and other converting processes which are reused to make pulp without reaching the final consumers; or post-consumer paper selected from the group consisting of corrugated boxes, newspapers, magazines, and office paper which has been recycled.

23. A method for producing pulp from wood material, the method comprising the steps of:

(a) reducing the material to a size appropriate for pulping;

(b) mixing the reduced material with oxalic acid dihydrate at an amount between about 0.05% and about 6% of the dry weight of the reduced material;

(c) cooking the mixture with steam at a pressure of less than about 30 p.s.i.g, the conditions of steps (b) and (c) being sufficient to enable defiberization of the cooked material;

(d) defiberizing the cooked material using a thermo-mechanical fiberizer; and

(e) mechanically refining the defiberized material to produce a pulp that exhibits improved paper strength and energy savings relative to uncooked pulp, wherein the material is hardwood or softwood capable of being processed into pulp for making paper products.

24. The method of claim 23 wherein the material is selected from either round wood comprising whole trees or wood residue comprising wood scraps left behind from forest and sawmill operations.

25. The method of claim 23 wherein the wood is selected from the group consisting of Southern Yellow Pine, Spruce, Western Hemlock, and Aspen.

26. A method for producing pulp from recovered paper material, the method comprising the steps of:

(a) reducing the material to a size appropriate for pulping;

(b) mixing the reduced material with oxalic acid dihydrate at an amount between about 0.05% and about 6% of the dry weight of the reduced material;

(c) cooking the mixture with steam at a pressure of less than about 30 p.s.i.g, the conditions of steps (b) and (c) being sufficient to enable defiberization of the cooked material;

(d) defiberizing the cooked material using a thermo-mechanical fiberizer; and

(e) mechanically refining the defiberized material to produce a pulp that exhibits improved paper strength and energy savings relative to uncooked pulp, wherein the material includes pre-consumer recovered paper selected from the group consisting of trimmings and scraps from printing, carton manufacturing, and other converting processes which are reused to make pulp without reaching the final consumer; or post-consumer paper selected from the group consisting of corrugated boxes, newspapers, magazines, and office paper which has been recycled.