IP Library Granted Patent US 7,339,084
Granted Patent B2
US 7,339,084 · App. 11/657,759 · Granted Mar 4, 2008

Method for the production of acetaldehyde from ethylene and oxygen

Assignee: Celanese Chemicals Europe GmbH
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Quick Facts
Patent No.
US 7,339,084
App. No.
11/657,759
Granted
Mar 4, 2008
Kind
B2
Abstract

A single-stage method for the oxidation of ethylene to acetaldehyde in the presence of an aqueous catalyst solution comprising copper chloride and palladium chloride under maintenance of the circulation of the aqueous catalyst solution in a recycle reactor, comprised of a reactor and a mist trap and which includes an externally applied thermal insulation.

Claims (8)

1. A single-stage method for the oxidation of ethylene to acetaldehyde in the presence of an aqueous catalyst solution comprising oxiding ethylene in a solution of copper chloride and palladium chloride under maintenance of circulation of the aqueous catalyst solution in a recycle reactor composed of a reactor and a mist trap, wherein the entire recycle reactor includes an externally applied thermal insulation to form acetaldehyde.

2. The method of claim 1 , wherein the externally applied thermal insulation to the reactor has a thickness of up of 100 mm.

3. The method of claim 1 , wherein the externally applied thermal insulation is comprised of a material, which at the reaction temperature of the acetaldehyde formation, has adequate temperature stability.

4. The method of claim 3 , wherein the externally applied thermal insulation is mineral fibers or glass gall.

5. The method of claim 1 , wherein a pressure-bearing part of the recycle reactor is made of a material which is corrosion resistant against the aqueous catalyst solution.

6. The method of claim 5 , wherein the corrosion-resistant material is selected from the group consisting of titanium, tantalum and niobium-zirconium alloys.

7. The method of claim 1 , wherein the pressure-bearing part of the recycle reactor is made of carbon steel or special steels and the inner reactor wall is coated with a corrosion-stable material which simultaneously has adequate temperature stability at the reaction temperature.

8. The method of claim 7 , wherein the corrosion-stable and simultaneously temperature-resistant coating is enamel or polyhalogenated hydrocarbons.

Assignments (3)
MERGER Recorded Apr 12, 2016
From: CELANESE CHEMICALS EUROPE GMBH
To: NUTRINOVA NUTRITION SPECIALTIES & FOOD INGREDIENTS GMBH
Reel/Frame 038363/0483 →
CHANGE OF NAME Recorded Feb 24, 2016
From: NUTRINOVA NUTRITION SPECIALTIES & FOOD INGREDIENTS GMBH
To: CELANESE SALES GERMANY GMBH
Reel/Frame 037900/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 25, 2007
From: FRANKEN-STELLAMANS, DR. ERHARD; FAHTZ, MARIO; HETT, KLAUS
To: CELANESE CHEMICALS EUROPE GMBH
Reel/Frame 018843/0082 →
Priority Claims (1)
DE 10 2006 004 074 · Jan 28, 2006 · national
Continuity (1)
Related Publication 20070208203A1 · Sep 6, 2007