Antimicrobial solid surface materials containing chitosan-metal complexes
A solid surface material with an antimicrobial agent in a thermoset and/or thermoplastic resin matrix where the antimicrobial agent comprises a chitosan-metal complex.
1. A method for producing a chitosan-silver complex, the method comprising the sequential steps of: (a) dissolving 0.25 to 8.0% by weight chitosan in an acid solution; (b) adding a solution of a silver salt to the product of step (a); (c) adding water to the product of step (b), with stirring; (d) raising the pH of the product of step (c) to pH 7 to 8 by adding a basic solution; (e) filtering the product of step (d); (f) washing the filtered solids obtained in step (e) with water, (g) washing the solids of step (f) with acetonitrile; (h) drying the washed solids under vacuum to obtain the chitosan-silver complex; and (i) optionally, grinding the dried product of step (h) to a fine powder.
2. The method of claim 1 , wherein the acid solution is a 0.25 to 5% aqueous solution of acetic acid; the silver salt solution is 0.5 to 20 wt % silver nitrate in water; and the pH is raised in step (d) by addition of aqueous ammonium hydroxide or substituted ammonium hydroxide.
3. A chitosan-silver complex produced by the method of claim 1 .
4. A finish solution for textile applications comprising the chitosan-silver complex of claim 3 .