Nanostructures, systems, and methods including nanolasers for enhanced Raman spectroscopy
View Patent ↗Nanostructures configured to enhance the intensity of Raman scattered radiation scattered by an analyte include a substantially planar substrate, a plurality of nanoparticles disposed on a surface of the substrate, and a Raman-enhancing material disposed on at least a portion of at least one nanoparticle. Each nanoparticle is configured to emit lased radiation upon stimulation of the nanoparticle and may comprise a nanowire laser. Raman spectroscopy systems include a radiation source, a radiation detector configured to detect Raman scattered radiation scattered by an analyte, a nanostructure including at least one nanoparticle configured to emit lased radiation upon stimulation, and means for stimulating the nanoparticle. Methods for performing Raman spectroscopy include providing a nanostructure including at least one nanoparticle configured to emit lased radiation upon stimulation of the nanoparticle, providing an analyte proximate to the nanoparticle, stimulating the nanoparticle, and detecting Raman scattered radiation.
1. A nanostructure configured to enhance the intensity of Raman scattered radiation scattered by an analyte, the nanostructure comprising:
a substantially planar substrate;
a plurality of nanoparticles extending in a substantially perpendicular direction from a surface of the substantially planar substrate, each nanoparticle of the plurality of nanoparticles being configured to emit lased radiation from a top surface thereof upon stimulation of the nanoparticle; and
a Raman-enhancing material disposed on at least a portion of at least one nanoparticle.
2. A nanostructure as recited in claim 1 , wherein the plurality of nanoparticles comprises a plurality of nanowire lasers extending from the surface of the substantially planar substrate.
3. A nanostructure as recited in claim 2 , wherein each nanowire laser of the plurality of nanowire lasers extends in a direction substantially parallel to the other nanowire lasers.
4. A nanostructure as recited in claim 2 , wherein each nanowire laser of the plurality of nanowire lasers comprises one of ZnO, ZnS, CdS, GaN, and InP.
5. A nanostructure as recited in claim 4 , wherein each nanowire laser of the plurality of nanowire lasers further comprises a dopant.
6. A nanostructure as recited in claim 5 , wherein the dopant comprises an ion of one of Mn, Cu, Ag, and Cr.
7. A nanostructure as recited in claim 2 , wherein each nanowire laser of the plurality of nanowire lasers is at least partially coated with the Raman-enhancing material.
8. A nanostructure as recited in claim 1 , further comprising a substance configured to attract an analyte disposed on at least a portion of the surface of at least one nanoparticle.
9. A nanostructure as recited in claim 1 , wherein the substrate comprises one of Si, SiO, Ge, ZnO, and sapphire.
10. A nanostructure as recited in claim 1 , wherein the Raman-enhancing material comprises one of Au, Ag, and Cu.
11. A nanostructure as recited in claim 1 , further comprising an analyte disposed proximate to at least one nanoparticle and the Raman-enhancing material.
12. A Raman spectroscopy system comprising:
a nanostructure configured to enhance the intensity of Raman scattered radiation scattered by an analyte, the nanostructure comprising at least one nanoparticle configured to emit lased radiation upon stimulation of the at least one nanoparticle;
means for stimulating the at least one nanoparticle; and
a radiation detector configured to detect Raman scattered radiation scattered by the analyte.
13. A Raman spectroscopy system as recited in claim 12 , wherein the nanoparticle comprises a nanowire laser.
14. A Raman spectroscopy system as recited in claim 13 , wherein the nanowire laser comprises one of ZnO, ZnS, CdS, GaN, and InP.
15. A Raman spectroscopy system as recited in claim 13 , wherein the nanowire laser is configured to provide an evanescent field upon stimulation of the nanowire laser.
16. A Raman spectroscopy system as recited in claim 12 , wherein the means for stimulating the at least one nanoparticle comprise a radiation source configured to provide pump radiation.
17. A Raman spectroscopy system as recited in claim 12 , further comprising a Raman-enhancing material disposed on at least a portion of the nanostructure configured to enhance the Raman signal of an analyte.
18. A method for performing Raman spectroscopy comprising:
providing a nanostructure configured to enhance the Raman scattered radiation scattered by an analyte, the nanostructure comprising at least one nanoparticle configured to emit lased radiation upon stimulation of the at least one nanoparticle;
providing an analyte at a position proximate to the at least one nanoparticle;
stimulating the at least one nanoparticle; and
detecting Raman scattered radiation scattered by the analyte.
19. A method for performing Raman spectroscopy as recited in claim 18 , wherein stimulating the at least one nanoparticle comprises irradiating the at least one nanoparticle with pump radiation.
20. A method for performing Raman spectroscopy as recited in claim 18 , further comprising providing an evanescent field in a region comprising the position of the analyte.
21. A method for performing Raman spectroscopy as recited in claim 18 , further comprising providing a Raman-enhancing material on at least a portion of the at least one nanoparticle.