IP Library › Granted Patent US 7,501,001

Granted Patent B2

US 7,501,001 · App. 10/211,630 · Granted Mar 10, 2009

Abrasive particles, and methods of making and using the same

Assignee: 3M Innovative Properties Company

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Quick Facts

Patent No.: US 7,501,001
App. No.: 10/211,630
Granted: Mar 10, 2009
Kind: B2

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Abstract

Abrasive particles and methods of making the same. Embodiments of the invention can be used to make abrasive particles. The abrasive particles can be incorporated into a variety of abrasive articles, including bonded abrasives, coated abrasives, nonwoven abrasives, and abrasive brushes.

Claims (132)

1. A plurality of abrasive particles having a specified nominal grade, wherein at least a portion of the abrasive particles is a plurality of abrasive particles comprising a glass-ceramic, the glass-ceramic comprising Al 2 O 3 and a metal oxide other than Al 2 O 3 , wherein at least a portion of the Al 2 O 3 is present as alpha Al 2 O 3 .

2. The plurality of abrasive particles of claim 1 wherein the glass-ceramic contains not more than 10 percent by weight collectively As 2 O 3 , B 2 O 3 , GeO 2 , P 2 O 5 , SiO 2 , TeO 2 , and V 2 O 5 , based on the total weight of the glass-ceramic.

3. A plurality of abrasive particles having a specified nominal grade, wherein at least a portion of the abrasive particles is a plurality of abrasive particles comprising a glass-ceramic, the glass-ceramic comprising at least 30 percent by weight Al 2 O 3 , based on the total weight of the glass-ceramic.

4. A plurality of abrasive particles having a specified nominal grade, wherein at least a portion of the abrasive particles is a plurality of abrasive particles comprising a glass-ceramic, the glass-ceramic comprising a metal oxide other than Al 2 O 3 and crystals of alpha Al 2 O 3 , wherein at least 80 percent by weight of the glass-ceramic of each particle of the portion collectively comprises Al 2 O 3 and the metal oxide other than Al 2 O 3 , based on the total weight of the glass-ceramic.

5. A plurality of abrasive particles having a specified nominal grade, wherein at least a portion of the abrasive particles is a plurality of abrasive particles comprising a glass-ceramic, the glass-ceramic comprising a metal oxide other than Al 2 O 3 and crystals of alpha Al 2 O 3 , wherein at least 60 percent by weight of the glass-ceramic of each particle of the portion collectively comprises Al 2 O 3 and the metal oxide other than Al 2 O 3 , and not more than 20 percent by weight collectively As 2 O 3 , B 2 O 3 , GeO 2 , P 2 O 5 , SiO 2 , TeO 2 , and V 2 O 5 , based on the total weight of the glass-ceramic.

6. A plurality of abrasive particles having a specified nominal grade, wherein at least a portion of the abrasive particles is a plurality of abrasive particles comprising a glass-ceramic, the glass-ceramic comprising a metal oxide other than Al 2 O 3 and crystals of alpha Al 2 O 3 , and wherein crystals present in the glass-ceramic have an average crystal size of not greater than 1 micrometer.

7. A method for making abrasive particles, the method comprising:

8. A method for making abrasive particles, the method comprising:

heat-treating particles comprising an amorphous material such that at least a portion of the amorphous material is converted to a glass-ceramic, the amorphous material comprising Al 2 O 3 and a metal oxide other than Al 2 O 3 , wherein the glass-ceramic comprises the Al 2 O 3 and the metal oxide other than Al 2 O 3 , wherein at least a portion of the Al 2 O 3 is present as alpha Al 2 O 3 ; and

grading the abrasive particles comprising the glass-ceramic to provide a plurality of abrasive particles having a specified nominal grade, wherein at least a portion of the plurality of abrasive particles is a plurality of the abrasive particles comprising the glass-ceramic.

9. A method for making abrasive particles, the method comprising:

heat-treating ceramic comprising an amorphous material such that at least a portion of the amorphous material is converted to a glass-ceramic, the amorphous material comprising Al 2 O 3 and a metal oxide other than Al 2 O 3 , wherein the glass-ceramic comprises the Al 2 O 3 and the metal oxide other than Al 2 O 3 , wherein at least a portion of the Al 2 O 3 is present as alpha Al 2 O 3 ;

crushing the glass-ceramic to provide abrasive particles comprising the glass-ceramic; and

grading the abrasive particles comprising the glass-ceramic to provide a plurality of abrasive particles having a specifiednominal grade, wherein at least a portion of the plurality of abrasive particles is a plurality of the abrasive particles comprising the glass-ceramic.

10. A method for making abrasive particles, the method comprising:

providing a plurality of particles having a specified nominal grade, wherein at least a portion of the particles is a plurality of particles comprising an amorphous material, the amorphous material comprising at least 30 percent by weight Al 2 O 3 , based on the total weight of the amorphous material of each particle of the portion; and

11. A method for making abrasive particles, the method comprising:

heat-treating particles comprising an amorphous material such that at least a portion of the amorphous glass is converted to a glass-ceramic, the amorphous material comprising at least 30 percent by weight Al 2 O 3 , based on the total weight of the amorphous material, and wherein the glass-ceramic comprises at least 30 percent by weight Al 2 O 3 , based on the total weight of the glass-ceramic; and

12. A method for making abrasive particles, the method comprising:

heat-treating ceramic comprising an amorphous material such that at least a portion of the amorphous material is convened to a glass-ceramic, the amorphous material comprising at least 30 percent by weight Al 2 O 3 , based on the total weight of the amorphous material, and wherein the glass-ceramic comprises at least 30 percent by weight Al 2 O 3 , based on the total weight of the glass-ceramic;

crushing the glass-ceramic to provide abrasive particles comprising the glass-ceramic; and

13. A method for making abrasive particles, the method comprising:

providing a plurality of particles having a specified nominal grade, wherein at least a portion of the particles is a plurality of particles comprising an amorphous material, the amorphous material comprising Al 2 O 3 and a metal oxide other than Al 2 O 3 , wherein at least 80 percent by weight of the amorphous material of each particle of the portion collectively comprises the Al 2 O 3 and the metal oxide other than Al 2 O 3 , based on the total weight of the amorphous material; and

heat-treating the particles comprising amorphous material such that at least a portion of the amorphous material is converted to a glass-ceramic and such that a plurality of abrasive particles having a specified nominal grade is provided, wherein at least a portion of the abrasive particles is a plurality of abrasive particles comprising the glass-ceramic, wherein the glass-ceramic comprises the metal oxide other than Al 2 O 3 and crystals of alpha Al 2 O 3 , and wherein at least 80 percent by weight of the glass-ceramic of each particle of the portion collectively comprises the Al 2 O 3 and the metal oxide other than Al 2 O 3 , based on the total weight of the glass-ceramic.

14. A method for making abrasive particles, the method comprising:

heat-treating particles comprising an amorphous material such that at least a portion of the amorphous material is converted to a glass-ceramic, the amorphous material comprising Al 2 O 3 and a metal oxide other than Al 2 O 3 , wherein at least 80 percent by weight of the amorphous material of each particle of the portion collectively comprises the Al 2 O 3 and the metal oxide other than Al 2 O 3 , based on the total weight of the amorphous material, and wherein the glass-ceramic comprises the metal oxide other than Al 2 O 3 and crystals of alpha Al 2 O 3 , wherein at least 80 percent by weight of the of the glass-ceramic of each particle of the portion collectively comprises the Al 2 O 3 and the metal oxide other than Al 2 O 3 , based on the total weight of the glass-ceramic; and

15. A method for making abrasive particles, the method comprising:

heat-treating ceramic comprising an amorphous material such that at least a portion of the amorphous material is converted to a glass-ceramic, the amorphous material comprising Al 2 O 3 and a metal oxide other than Al 2 O 3 , wherein at least 80 percent by weight of the amorphous material of each particle of the portion collectively comprises the Al 2 O 3 and the metal oxide other than Al 2 O 3 , based on the total weight of the amorphous material, wherein the glass-ceramic comprises the metal oxide other than Al 2 O 3 and crystals of alpha Al 2 O 3 , and wherein at least 80 percent by weight of the glass-ceramic collectively comprises the Al 2 O 3 and the metal oxide other than Al 2 O 3 , based on the total weight of the glass-ceramic;

crushing the glass-ceramic to provide abrasive particles comprising the glass-ceramic; and

16. A method for making abrasive particles, the method comprising:

providing a plurality of particles having a specified nominal grade, wherein at least a portion of the particles is a plurality of particles comprising an amorphous material, the amorphous material comprising Al 2 O 3 and a metal oxide other than Al 2 O 3 , wherein at least 60 percent by weight of the amorphous material of each particle of the portion collectively comprises the Al 2 O 3 and the metal oxide other than Al 2 O 3 , and not more than 20 percent by weight collectively As 2 O 3 , B 2 O 3 , GeO 2 , P 2 O 5 , SiO 2 , TeO 2 , and V 2 O 5 , based on the total weight of the amorphous material; and

heat-treating the particles comprising amorphous material such that at least a portion of the amorphous material is converted to a glass-ceramic and such that a plurality of abrasive particles having a specified nominal grade is provided, wherein at least a portion of the abrasive particles is a plurality of abrasive particles comprising the glass-ceramic, wherein the glass-ceramic comprises the metal oxide other than Al 2 O 3 and crystals of alpha Al 2 O 3 , wherein at least 60 percent by weight of the glass-ceramic of each particle of the portion collectively comprises the Al 2 O 3 and the metal oxide other than Al 2 O 3 , and not more than 20 percent by weight collectively As 2 O 3 , B 2 O 3 , GeO 2 , P 2 O 5 , SiO 2 , TeO 2 , and V 2 O 5 , based on the total weight of the glass-ceramic.

17. A method for making abrasive particles, the method comprising:

heat-treating particles comprising an amorphous material such that at least a portion of the amorphous material is converted to a glass-ceramic, the amorphous material comprising Al 2 O 3 and a metal oxide other than Al 2 O 3 , wherein at least 60 percent by weight of the amorphous material of each particle of the portion collectively comprises the Al 2 O 3 and the metal oxide other than Al 2 O 3 , and not more than 20 percent by weight collectively As 2 O 3 , B 2 O 3 , GeO 2 , P 2 O 5 , SiO 2 , TeO 2 , and V 2 O 5 , based on the total weight of the amorphous material, wherein the glass-ceramic comprises the metal oxide other than Al 2 O 3 and crystals of alpha Al 2 O 3 , wherein at least 60 percent by weight of the glass-ceramic of each particle of the portion collectively comprises the Al 2 O 3 and the metal oxide other than Al 2 O 3 , and not more than 20 percent by weight collectively As 2 O 3 , B 2 O 3 , GeO 2 , P 2 O 5 , SiO 2 , TeO 2 , and V 2 O 5 , based on the total weight of the glass-ceramic; and

18. A method for making abrasive particles, the method comprising:

heat-treating ceramic comprising amorphous material such that at least a portion of the amorphous material is converted to a glass-ceramic, the amorphous material comprising Al 2 O 3 and a metal oxide other than Al 2 O 3 , wherein at least 60 percent by weight of the amorphous material collectively comprises the Al 2 O 3 and the metal oxide other than Al 2 O 3 , and As 2 O 3 , B 2 O 3 , GeO 2 , P 2 O 5 , SiO 2 , TeO 2 , and V 2 O 5 , based on the total weight of the amorphous material, wherein the glass-ceramic comprises the metal oxide other than Al 2 O 3 and crystals of alpha Al 2 O 3 , and wherein at least 60 percent by weight of the glass-ceramic collectively comprises the Al 2 O 3 and the metal oxide other than Al 2 O 3 , and As 2 O 3 , B 2 O 3 , GeO 2 , P 2 O 5 , SiO 2 , TeO 2 , and V 2 O 5 , based on the total weight of the glass-ceramic;

crushing the glass-ceramic to provide abrasive particles comprising the glass-ceramic; and

19. A method for making abrasive particles, the method comprising:

heat-treating the particles comprising an amorphous material such that at least a portion of the amorphous material is converted to a glass-ceramic and such that a plurality of abrasive particles having a specified nominal grade is provided, wherein at least a portion of the abrasive particles is a plurality of abrasive particles comprising the glass-ceramic, wherein the glass-ceramic comprises the metal oxide other than Al 2 O 3 and crystals of alpha Al 2 O 3 , and wherein crystals present in the glass-ceramic have an average crystal size of not greater than 1 micrometer.

20. A method for making abrasive particles, the method comprising:

heat-treating particles comprising an amorphous material such that at least a portion of the amorphous material is converted to a glass-ceramic, the amorphous material comprising Al 2 O 3 and a metal oxide other than Al 2 O 3 , wherein the glass-ceramic comprises the metal oxide other than Al 2 O 3 and crystals of alpha Al 2 O 3 , and wherein crystals present in the glass-ceramic have an average crystal size of not greater than 1 micrometer; and

21. A method for making abrasive particles, the method comprising:

heat-treating ceramic comprising an amorphous material such that at least a portion of the amorphous material is converted to crystalline ceramic, the amorphous material comprising Al 2 O 3 and a metal oxide other than Al 2 O 3 , wherein the glass-ceramic comprises the metal oxide other than Al 2 O 3 and crystals of alpha Al 2 O 3 , and wherein crystals present in the glass-ceramic have an average crystal size of not greater than 1 micrometer;

crushing the glass-ceramic to provide abrasive particles comprising the glass-ceramic; and

22. A plurality of abrasive particles having a specified nominal grade, wherein at least a portion of the abrasive particles is a plurality of abrasive particles comprising a glass-ceramic, the glass-ceramic comprising a metal oxide other than Al 2 O 3 and crystals of alpha Al 2 O 3 , wherein crystals present in the glass-ceramic have an average crystal size of not greater than 200 nanometers, and wherein the glass-ceramic has a density of at least 90% of theoretical density.

23. A plurality of abrasive particles having a specified nominal grade, wherein at least a portion of the abrasive particles is a plurality of abrasive particles comprising a glass-ceramic, the glass-ceramic comprising a metal oxide other than Al 2 O 3 and crystals of alpha Al 2 O 3 , wherein no more than 10% by number of crystals present in the glass-ceramic are greater than 200 nanometers, and wherein the glass-ceramic has a density of at least 90% of theoretical density.

24. A plurality of abrasive particles having a specified nominal grade, wherein at least a portion of the abrasive particles is a plurality of abrasive particles comprising a glass-ceramic, the glass-ceramic comprising a metal oxide other than Al 2 O 3 and crystals of alpha Al 2 O 3 , wherein at least 20% by number of crystals present in the glass-ceramic are not greater than 200 nanometers, and wherein the glass-ceramic has a density of at least 90% of theoretical density.

25. A plurality of abrasive particles having a specified nominal grade, wherein at least a portion of the abrasive particles is a plurality of abrasive particles comprising a glass-ceramic, the glass-ceramic comprising a metal oxide other than Al 2 O 3 and crystals of alpha Al 2 O 3 , wherein at least a portion of crystals present in the glass-ceramic are not greater than 150 nanometers, and wherein the glass-ceramic has a density of at least 90% of theoretical density.

26. An abrasive article comprising a binder and a plurality of abrasive particles, wherein at least a portion of the abrasive particles are abrasive particles comprising a glass-ceramic, the glass-ceramic comprising a metal oxide other than Al 2 O 3 and crystals of alpha Al 2 O 3 , wherein at least 80 percent by weight of the glass-ceramic of each particle of the portion collectively comprises Al 2 O 3 and the metal oxide other than Al 2 O 3 , based on the total weight of the glass-ceramic.

27. An abrasive article comprising a binder and a plurality of abrasive particles, wherein at least a portion of the abrasive particles are abrasive particles comprising a glass-ceramic, the glass-ceramic comprising a metal oxide other than Al 2 O 3 and crystals of alpha Al 2 O 3 , wherein the glass-ceramic of each particle of the portion contains not more than 10 percent by weight collectively As 2 O 3 , B 2 O 3 , GeO 2 , P 2 O 5 , SiO 2 , TeO 2 , and V 2 O 5 , based on the total weight of the glass-ceramic.

28. A method of abrading a surface, the method comprising:

providing an abrasive article comprising a binder and a plurality of abrasive particles, wherein at least a portion of the abrasive particles are abrasive particles comprising a glass-ceramic, the glass-ceramic comprising a metal oxide other than Al 2 O 3 and crystals of alpha Al 2 O 3 , wherein at least 80 percent by weight of the glass-ceramic of each particle of the portion collectively comprises Al 2 O 3 and the metal oxide other than Al 2 O 3 , based on the total weight of the glass-ceramic;

contacting at least one of the abrasive particles comprising the glass-ceramic with a surface of a workpiece; and

moving at least one of the contacted abrasive particles comprising the glass-ceramic or the contacted surface to abrade at least a portion of the surface with the contacted abrasive particles comprising the glass-ceramic.

29. A method of abrading a surface, the method comprising:

providing an abrasive article comprising a binder and a plurality of abrasive particles, wherein at least a portion of the abrasive particles are abrasive particles comprising a glass-ceramic, the glass-ceramic comprising a metal oxide other than Al 2 O 3 and crystals of alpha Al 2 O 3 , wherein the glass-ceramic of each particle of the portion contains not more than 10 percent by weight collectively As 2 O 3 , B 2 O 3 , GeO 2 , P 2 O 5 , SiO 2 , TeO 2 , and V 2 O 5 , based on the total weight of the glass-ceramic;

contacting at least one of the abrasive particles comprising the glass-ceramic with a surface of a workpiece; and

30. An abrasive article comprising a binder and a plurality of abrasive particles, wherein at least a portion of the abrasive particles are abrasive particles comprising a glass-ceramic, the glass-ceramic comprising a metal oxide other than Al 2 O 3 and crystals of alpha Al 2 O 3 , wherein at least 60 percent by weight of the glass-ceramic of each particle of the portion collectively comprises Al 2 O 3 and the metal oxide other than Al 2 O 3 , and not more than 20 percent by weight collectively and As 2 O 3 , B 2 O 3 , GeO 2 , P 2 O 5 , SiO 2 , TeO 2 , and V 2 O 5 , based on the total weight of the glass-ceramic.

31. A method of abrading a surface, the method comprising:

providing an abrasive article comprising a binder and a plurality of abrasive particles, wherein at least a portion of the abrasive particles are abrasive particles comprising a glass-ceramic, the glass-ceramic comprising a metal oxide other than Al 2 O 3 and crystals of alpha Al 2 O 3 , wherein at least 60 percent by weight of the glass-ceramic of each particle of the portion collectively comprises Al 2 O 3 and the metal oxide other than Al 2 O 3 , and not more than 20 percent by weight collectively As 2 O 3 , B 2 O 3 , GeO 2 , P 2 O 5 , SiO 2 , TeO 2 , and V 2 O 5 , based on the total weight of the glass-ceramic;

contacting at least one of the abrasive particles comprising the glass-ceramic with a surface of a workpiece; and

32. An abrasive article comprising a binder and a plurality of abrasive particles, wherein at least a portion of the abrasive particles are abrasive particles comprising a glass-ceramic, the glass-ceramic comprising a metal oxide other than Al 2 O 3 and crystals of alpha Al 2 O 3 , and wherein crystals present in the glass-ceramic have an average crystal size of not greater than 1 micrometer.

33. A method of abrading a surface, the method comprising:

providing an abrasive article comprising a binder and a plurality of abrasive particles, wherein at least a portion of the abrasive particles are abrasive particles comprising a glass-ceramic, the glass-ceramic comprising a metal oxide other than Al 2 O 3 and crystals of alpha Al 2 O 3 , and wherein crystals present in the glass-ceramic have an average crystal size of not greater than 1 micrometer;

contacting at least one of the abrasive particles comprising the glass-ceramic with a surface of a workpiece; and

34. A plurality of abrasive particles having a specified nominal grade, wherein at least a portion of the abrasive particles is a plurality of abrasive particles comprising a glass-ceramic, the glass-ceramic comprising a complex metal oxide and a metal oxide other than the complex metal oxide, wherein at least a portion of the complex metal oxide is crystalline, and wherein at least 80 percent by weight of the glass-ceramic of each particle of the portion collectively comprises the complex metal oxide and the metal oxide other than the complex metal oxide, based on the total weight of the glass-ceramic.

35. A plurality of abrasive particles having a specified nominal grade, wherein at least a portion of the abrasive particles is a plurality of abrasive particles comprising a glass-ceramic, the glass-ceramic comprising a complex metal oxide and a metal oxide other than the complex metal oxide, wherein at least a portion of the complex metal oxide is crystalline, and wherein at least 60 percent by weight of the glass-ceramic of each particle of the portion collectively comprises the complex metal oxide and the metal oxide other than the complex metal oxide, and not more than 20 percent by weight collectively As 2 O 3 , B 2 O 3 , GeO 2 , P 2 O 5 , SiO 2 , TeO 2 , and V 2 O 5 , based on the total weight of the glass-ceramic.

36. A plurality of abrasive particles having a specified nominal grade, wherein at least a portion of the abrasive particles is a plurality of abrasive particles comprising a glass-ceramic, the glass-ceramic comprising a complex metal oxide and a metal oxide other than the complex metal oxide, wherein at least a portion of the complex metal oxide is crystalline, and wherein crystals present in the glass-ceramic have an average crystal size of not greater than 1 micrometer.

37. A method for making abrasive particles, the method comprising:

providing a plurality of particles having a specified nominal grade, wherein at least a portion of the particles is a plurality of particles comprising an amorphous material, the amorphous material comprising a complex metal oxide and a metal oxide other than the complex metal oxide, and wherein at least 80 percent by weight of the amorphous material of each particle of the portion collectively comprises the complex metal oxide and the metal oxide other than the complex metal oxide, based on the total weight of the amorphous material; and

heat-treating the particles comprising amorphous material such that at least a portion of the amorphous material is converted to a glass-ceramic and such that a plurality of abrasive particles having a specified nominal grade is provided, wherein at least a portion of the abrasive particles is a plurality of the abrasive particles comprising the glass-ceramic, wherein the glass-ceramic comprises the metal oxide other than the complex metal oxide and crystals of the complex metal oxide, and wherein at least 80 percent by weight of the glass-ceramic of each particle of the portion collectively comprises the complex metal oxide and the metal oxide other than the complex metal oxide, based on the total weight of the glass-ceramic.

38. A method for making abrasive particles, the method comprising:

heat-treating particles comprising an amorphous material such that at least a portion of the amorphous material is converted to a glass-ceramic, the amorphous material comprising a complex metal oxide and a metal oxide other than the complex metal oxide, wherein at least 80 percent by weight of the amorphous material of each particle of the portion collectively comprises the complex metal oxide and the metal oxide other than the complex metal oxide, based on the total weight of the amorphous material, wherein the glass-ceramic comprises the metal oxide other than the complex metal oxide and crystals of the complex metal oxide, and wherein at least 80 percent by weight of the glass-ceramic of each particle collectively of the portion comprises the complex metal oxide and the metal oxide other than the complex metal oxide, based on the total weight of the glass-ceramic; and

39. A method for making abrasive particles, the method comprising:

heat-treating ceramic comprising an amorphous material such that at least a portion of the amorphous material is converted to a glass-ceramic, the amorphous material comprising a complex metal oxide and a metal oxide other than the complex metal oxide, wherein at least 80 percent by weight of the amorphous material of each particle of the portion collectively comprises the and the metal oxide other than the complex metal oxide, based on the total weight of the amorphous material, wherein the glass-ceramic comprises the metal oxide other than the complex metal oxide and crystals of the complex metal oxide, and wherein at least 80 percent by weight of the glass-ceramic collectively comprises the metal oxide other than the complex metal oxide and the complex metal oxide, based on the total weight of the glass-ceramic;

crushing the glass-ceramic to provide abrasive particles comprising the glass-ceramic; and

40. A method for making abrasive particles, the method comprising:

providing a plurality of particles having a specified nominal grade, wherein at least a portion of the particles is a plurality of particles comprising an amorphous material, the amorphous material comprising a complex metal oxide and a metal oxide other than the complex metal oxide, wherein at least 60 percent by weight of the amorphous material of each particle of the portion collectively comprises the complex metal oxide and the metal oxide other than the complex metal oxide, and not more than 20 percent by weight collectively As 2 O 3 , B 2 O 3 , GeO 2 , P 2 O 5 , SiO 2 , TeO 2 , and V 2 O 5 , based on the total weight of the amorphous material; and

heat-treating the particles comprising amorphous material such that at least a portion of the amorphous material is converted to a glass-ceramic and such that a plurality of abrasive particles having a specified nominal grade is provided, wherein at least a portion of the abrasive particles is a plurality of abrasive particles comprising the glass-ceramic, wherein the glass-ceramic comprises the metal oxide other than the complex metal oxide and crystals of the complex metal oxide, and wherein at least 60 percent by weight of the glass-ceramic of each particle collectively of the portion comprises the complex metal oxide and the metal oxide other than the complex metal oxide, and not more than 20 percent by weight collectively As 2 O 3 , B 2 O 3 , GeO 2 , P 2 O 5 , SiO 2 , TeO 2 , and V 2 O 5 , based on the total weight of the glass-ceramic.

41. A method for making abrasive particles, the method comprising:

heat-treating particles comprising an amorphous material such that at least a portion of the amorphous material is converted to a glass-ceramic, the amorphous material comprising a complex metal oxide and a metal oxide other than the complex metal oxide, wherein at least 60 percent by weight of the amorphous material of each particle of the portion collectively comprises the complex metal oxide and the metal oxide other than the complex metal oxide, and not more than 20 percent by weight collectively and As 2 O 3 , B 2 O 3 , GeO 2 , P 2 O 5 , SiO 2 , TeO 2 , and V 2 O 5 , based on the total weight of the amorphous material, wherein the glass-ceramic comprises the metal oxide other than the complex metal oxide and crystals of the complex metal oxide, wherein at least 60 percent by weight of the glass-ceramic of each particle of the portion collectively comprises the complex metal oxide and the metal oxide other than the complex metal oxide, and not more than 20 percent by weight collectively As 2 O 3 , B 2 O 3 , GeO 2 , P 2 O 5 , SiO 2 , TeO 2 , V 2 O 5 , and based on the total weight of the glass-ceramic; and

42. A method for making abrasive particles, the method comprising:

heat-treating ceramic comprising an amorphous material such that at least a portion of the amorphous material is converted to a glass-ceramic, the amorphous material comprising a complex metal oxide and a metal oxide other than the complex metal oxide, wherein at least 60 percent by weight of the amorphous material of each particle of the portion collectively comprises the complex metal oxide and the metal oxide other than the complex metal oxide, and comprising the glass-ceramic based on the total weight of the amorphous material, wherein the glass-ceramic comprises the metal oxide other than the complex metal oxide and crystals of the complex metal oxide, wherein at least 60 percent by weight of the glass-ceramic collectively comprises the complex metal oxide and the metal oxide other than the complex metal oxide, and not more than 20 percent by weight collectively As 2 O 3 , B 2 O 3 , GeO 2 , P 2 O 5 , SiO 2 , TeO 2 , and V 2 O 5 , based on the total weight of the glass-ceramic;

crushing the glass-ceramic to provide abrasive particles comprising the glass-ceramic; and

43. A method for making abrasive particles, the method comprising:

44. A method for making abrasive particles, the method comprising:

45. A method for making abrasive particles, the method comprising:

crushing the glass-ceramic to provide abrasive particles comprising the glass-ceramic; and

grading the abrasive particles comprising the glass-ceramic to provide, a plurality of abrasive particles having a specified nominal grade, wherein at least a portion of the plurality of abrasive particles is a plurality of the abrasive particles comprising the glass-ceramic.

46. A plurality of abrasive particles having a specified nominal grade, wherein at least a portion of the abrasive particles is a plurality of abrasive particles comprising a glass-ceramic, the glass-ceramic comprising a complex metal oxide and a metal oxide other than the complex metal oxide, wherein at least a portion of the complex metal oxide is crystalline, wherein crystals present in the glass-ceramic have an average crystal size of not greater than 200 nanometers, and wherein the glass-ceramic has a density of at least 90% of theoretical density.

47. A plurality of abrasive particles having a specified nominal grade, wherein at least a portion of the abrasive particles is a plurality of abrasive particles comprising a glass-ceramic, the glass-ceramic comprising a complex metal oxide and a metal oxide other than the complex metal oxide, wherein at least a portion of the complex metal oxide is crystalline, wherein no more than 10% by number of crystals present in the glass-ceramic are greater than 200 nanometers, and wherein the glass-ceramic has a density of at least 90% of theoretical density.

48. A plurality of abrasive particles having a specified nominal grade, wherein at least a portion of the abrasive particles is a plurality of abrasive particles comprising a glass-ceramic, the glass-ceramic comprising a complex metal oxide and a metal oxide other than the complex metal oxide, wherein at least a portion of the complex metal oxide is crystalline, wherein at least 20% by number of crystals present in the glass-ceramic are not greater than 200 nanometers, and wherein the glass-ceramic has a density of at least 90% of theoretical density.

49. A plurality of abrasive particles having a specified nominal grade, wherein at least a portion of the abrasive particles is a plurality of abrasive particles comprising a glass-ceramic, the glass-ceramic comprising a complex metal oxide and a metal oxide other than the complex metal oxide, wherein at least a portion of the complex metal oxide is crystalline, wherein at least a portion of crystals present in the glass-ceramic are not greater than 150 nanometers, and wherein the glass-ceramic has a density of at least 90% of theoretical density.

50. An abrasive article comprising a binder and a plurality of abrasive particles, wherein at least a portion of the abrasive particles are abrasive particles comprising a glass-ceramic, the glass-ceramic comprising a complex metal oxide and a metal oxide other than the complex metal oxide, wherein at least a portion of the complex metal oxide is crystalline, and wherein at least 80 percent by weight of the glass-ceramic of each particle of the portion collectively comprises the complex metal oxide and the metal oxide other than the complex metal oxide, based on the total weight of the glass-ceramic.

51. A method of abrading a surface, the method comprising:

providing an abrasive article comprising a binder and a plurality of abrasive particles, wherein at least a portion of the abrasive particles are abrasive particles comprising a glass-ceramic, the glass-ceramic comprising a complex metal oxide and a metal oxide other than the complex metal oxide, wherein at least a portion of the complex metal oxide is crystalline, and wherein at least 80 percent by weight of the glass-ceramic of each particle of the portion collectively comprises the complex metal oxide and the metal oxide other than the complex metal oxide, based on the total weight of the glass-ceramic;

contacting at least one of the abrasive particles comprising the glass-ceramic with a surface of a workpiece; and

52. An abrasive article comprising a binder and a plurality of abrasive particles, wherein at least a portion of the abrasive particles are abrasive particles comprising a glass-ceramic, the glass-ceramic comprising a complex metal oxide and a metal oxide other than the complex metal oxide, wherein at least a portion of the complex metal oxide is crystalline, and wherein at least 60 percent by weight of the glass-ceramic of each particle of the portion collectively comprises the complex metal oxide and the metal oxide other than the complex metal oxide, and not more than 20 percent by weight collectively As 2 O 3 , B 2 O 3 , GeO 2 , P 2 O 5 , SiO 2 , TeO 2 , and V 2 O 5 , based on the total weight of the glass-ceramic.

53. A method of abrading a surface, the method comprising:

providing an abrasive article comprising a binder and a plurality of abrasive particles, wherein at least a portion of the abrasive particles are abrasive particles comprising a glass-ceramic, the glass-ceramic comprising a complex metal oxide and a metal oxide other than the complex metal oxide, wherein at least a portion of the complex metal oxide is crystalline, and wherein at least 60 percent by weight of the glass-ceramic of each particle of the portion collectively comprises the complex metal oxide and the metal oxide other than the complex metal oxide, and not more than 20 percent by weight collectively As 2 O 3 , B 2 O 3 , GeO 2 , P 2 O 5 , SiO 2 , TeO 2 , and V 2 O 5 , based on the total weight of the glass-ceramic;

contacting at least one of the abrasive particles comprising the glass-ceramic with a surface of a workpiece; and

54. An abrasive article comprising a binder and a plurality of abrasive particles, wherein at least a portion of the abrasive particles are abrasive particles comprising a glass-ceramic, the glass-ceramic comprising a complex metal oxide and a metal oxide other than the complex metal oxide, wherein at least a portion of the complex metal oxide is crystalline, and wherein crystals present in the glass-ceramic have an average crystal size of not greater than 1 micrometer.

55. A method of abrading a surface, the method comprising:

contacting at least one of the abrasive particles comprising the glass-ceramic with a surface of a workpiece; and

Assignments (1)

ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 2, 2002

From: ROSENFLANZ, ANATOLY Z.; CELIKKAYA, AHMET; ANDERSON, THOMAS J.

To: 3M INNOVATIVE PROPERTIES COMPANY

Reel/Frame 013170/0589 →

Continuity (5)

Continuation In Part 0992253000 · Aug 2, 2001

Continuation In Part 0992252800 · Aug 2, 2001

Continuation In Part 0992252700 · Aug 2, 2001

Continuation In Part 0992252600 · Aug 2, 2001

Related Publication 20030110707A1 · Jun 19, 2003