Ionic organosilicon compounds and compositions thereof
Ionic organosilicon compounds are provided comprising ethylene glycol functionality and aqueous compositions comprising such ionic organosilicon compounds; wherein the aqueous compositions are suitable for imparting water repellency to a wide variety of surfaces. The compositions of the present invention are prepared by dissolving ionic organosilicon compounds in water. Surprisingly, it has been found that the water soluble ionic organosilicon compounds, which have an ionic group, a hydrophobic group and at least one alkoxy group on silicon, of the present invention provide treated surfaces with excellent hydrophobicity.
1. An ionic organosilicon compound selected from the formula:
where in each formula:
Y is RO where R is (CH 2 CH 2 O) n H where n has a value of one through ten;
a has a value of zero, one and two;
R′ is a methyl or ethyl radical;
R″ is an alkylene group with four carbon atoms;
R′″, R″″ and R v are alkyl groups containing one to twenty two carbon atoms wherein at least one such group is larger than eight carbon atoms, —CH 2 C 6 H 5 , —CH 2 CH 2 OH, —CH 2 OH, and —(CH 2 ) x NHC(O)R vi wherein x has a value of from two to ten and R vi is a perfluoroalkyl radical having one to twelve carbon atoms; and
X is chloride, bromide, fluoride, iodide, acetate or tosylate.
2. An ionic organosilicon compound according to claim 1 , wherein said compound is selected from the formula:
wherein:
Y is RO where R is an alkyl group with one to four carbons, (CH 2 CH 2 O) n H where n has a value of one through ten;
a has a value of zero, one and two;
R′ is a methyl or ethyl radical;
R′″, R″″ and R v are alkyl groups containing one to twenty two carbon atoms wherein at least one such group is larger than eight carbon atoms, —CH 2 C 6 H 5 , —CH 2 CH 2 OH, —CH 2 OH, and —(CH 2 ) x NHC(O)R vi wherein x has a value of from two to ten and R vi is a perfluoroalkyl radical having one to twelve carbon atoms; and
X is chloride, bromide, fluoride, iodide, acetate or tosylate.
3. An ionic organosilicon compound according to claim 1 , wherein said compound is 3-[tri-(2-hydroxyethoxy)silyl]-2-methylpropyldimethyloctadecyl ammonium chloride.
4. An aqueous composition consisting essentially of at least one water soluble ionic organosilicon compounds of claim 1 .
5. The aqueous composition of claim 4 ; wherein said composition consists essentially of only one ionic organosilicon compound.
6. The aqueous composition of claim 4 ; wherein said water soluble ionic organosilicon compound consists essentially of between 0.1 to 10 weight percent of said aqueous composition.
7. The aqueous composition of claim 4 ; wherein said water soluble ionic organosilicon compound is 3-[tri-(2-hydroxyethoxy)silyl]-2- methylpropyldimethyloctadecyl ammonium chloride.
8. An aqueous composition comprising at least one water soluble ionic organosilicon compound of claim 1 .
9. The aqueous composition of claim 8 ; wherein said composition comprises of only one ionic organosilicon compound.
10. The aqueous composition of claim 8 ; wherein said water soluble ionic organosilicon compound comprises between about 0.1 to 10 weight percent of said aqueous composition.
11. The aqueous composition of claim 8 ; wherein said water soluble ionic organosilicon compound is 3-[tri-(2-hydroxyethoxy)silyl]-2-methylpropyldimethyloctadecyl ammonium chloride.