Preparation of iron(II) acetate powder from a low grade magnetite
View Patent ↗The present invention relates to a preparation of iron(II) acetate powder from low grade magnetite and comprises the following steps: (a) adding organic acid to low grade magnetite powder to obtain iron solution; (b) adding hydroxide to the iron solution to obtain iron hydroxide; and (c) adding acetic acid to the iron hydroxide, thereby obtaining iron(II) acetate. According to the present invention, it is possible to obtain high purity iron(II) acetate using low grade magnetite and there are advantages of mass producible environmentally-friendly simple process and prevention of corrosion of facilities.
1. A process for the preparation of iron(II) acetate, comprising the following steps:
(a) adding organic acid to low grade magnetite powder to obtain iron solution;
(b) adding hydroxide to the iron solution to obtain iron hydroxide; and
(c) adding acetic acid to the iron hydroxide, thereby obtaining iron(II) acetate.
2. The process for the preparation of iron(II) acetate as set forth in claim 1 , wherein the low grade magnetite in the step (a) has an iron content of 30-70% by weight.
3. The process for the preparation of iron(II) acetate as set forth in claim 1 , wherein the organic acid in the step (a) is oxalic acid.
4. The process for the preparation of iron(II) acetate as set forth in claim 3 , wherein in the step (a), 0.2M to 0.8M oxalic acid is added and the reaction is performed at a temperature of 80-100° C.
5. The process for the preparation of iron(II) acetate as set forth in claim 4 , wherein the step (a) is performed in pH 0.5-2.5.
6. The process for the preparation of iron(II) acetate as set forth in claim 1 , wherein the hydroxide in the step (b) is sodium hydroxide, ammonium hydroxide or a mixture thereof.
7. The process for the preparation of iron(II) acetate as set forth in claim 6 , wherein the step (b) is performed in pH 3.5-4.5.
8. The process for the preparation of iron(II) acetate as set forth in claim 1 , wherein in the step (c), 10-100 parts by weight of acetic acid based on 1 part by weight of the iron hydroxide is added.
9. The process for the preparation of iron(II) acetate as set forth in claim 8 , wherein the step (c) is performed at a temperature of 25-100° C.
10. The process for the preparation of iron(II) acetate as set forth in claim 1 , further comprising, before the step (a), the step of crushing low magnetite ore and then separating ferromagnetic particles.