Membrane electrode assembly for a fuel cell
A membrane electrode assembly (MEA) for a fuel cell, which has a planar polymer membrane. This membrane, in a tangentially inner area, is coated on both sides with electrode structure, and, in a tangentially outer area projecting at least on one side beyond the electrode structure coating, is connected to a sealing member. A marginal zone of the polymer membrane is embedded in the elastomer sealing member. The sealing member extends tangentially inward to a transition area that lies tangentially between the outer area and the inner area, where it overlaps the electrode structures on outer faces of the electrode structures, on both of the sides of the polymer membrane.
1. A membrane electrode assembly for a fuel cell, comprising:
a planar polymer membrane which, in a tangentially inner area, is coated with respective electrode structures on either side and, in a tangentially outer area that projects on at least one side beyond the electrode structures, is connected to a sealing member formed of elastomer material, wherein:
a marginal zone of the polymer membrane is embedded into the sealing member,
the sealing member extends tangentially inwardly into a transition area that lies tangentially between the outer area and the inner area, and overlaps the electrode structures on outer faces of the electrode structures, on both of the sides of the polymer membrane, and
the inner area of the polymer membrane and the transition area are doped with a doping agent, such that the concentration of the doping agent decreases tangentially outwardly in the transition area.
2. The membrane electrode assembly as claimed in claim 1 , wherein the sealing member frames the entire inner area of the polymer membrane tangentially outwardly.
3. The membrane electrode assembly as claimed in claim 1 , wherein the elastomer material is cast onto the polymer membrane.
4. The membrane electrode assembly as claimed in claim 1 , wherein the doping agent contains phosphoric acid (H 3 PO 4 ).
5. The membrane electrode assembly as claimed in claim 1 , wherein the polymer membrane is formed of polybenzimidazole.
6. The membrane electrode assembly as claimed in claim 1 , wherein spacer structures, which are non-elastic compared to the elastomer material of the sealing member, are embedded into the sealing member.
7. The membrane electrode assembly as claimed in claim 1 , wherein the polymer membrane and the sealing member have openings in the outer area for reaction gases or cooling medium to pass through.
8. The membrane electrode assembly as claimed in claim 1 , wherein the sealing member has sealing structures disposed on the exterior of the sealing member, and is configured to interact with adjacent elements in a fuel cell stack, to form a seal.
9. A fuel cell stack, comprising a plurality of membrane electrode units which are each disposed between separator plates,
wherein each membrane electrode unit comprises a planar polymer membrane which, in a tangentially inner area, is coated with respective electrode structures on either side and which has a tangentially outer area projecting beyond the electrode structure coating,
wherein a marginal zone of each polymer membrane is embedded into and forms a bond with a sealing member formed of an elastomer material, and the sealing member extends tangentially inwardly into a transition area that lies tangentially between the outer area and the inner area, where the sealing member overlaps the electrode structures on outer faces of the electrode structures, on both of the sides of the polymer membrane, and
wherein the inner areas of the plurality of polymer membranes and the respective transition areas are doped with a doping agent, such that the concentration of the doping agent decreases tangentially outwardly in the transition areas.
10. The fuel cell stack as claimed in claim 9 , wherein the sealing member frames the entire inner area of the polymer membrane tangentially outwardly.
11. The fuel cell stack as claimed in claim 9 , wherein the elastomer material is cast onto the polymer membrane.
12. The fuel cell stack as claimed in claim 9 , wherein the doping agent contains phosphoric acid (H 3 PO 4 ).
13. The fuel cell stack as claimed in claim 9 , wherein the polymer membranes are formed of polybenzimidazole.
14. The fuel cell stack as claimed in claim 9 , wherein spacer structures, which are non-elastic compared to the elastomer material of the sealing member, are embedded into each sealing member.
15. The fuel cell stack as claimed in claim 9 , further comprising:
channels for conducting at least one of reaction gases and a cooling medium, wherein the channels axially extend through the fuel cell stack in an area corresponding to the outer area of the polymer membranes, such that each sealing member has sealing structures that enclose each channel that penetrates the sealing member and that interact with an adjacent one of the separator plates, to form a seal.