Nanocomposite fibers and film containing polyolefin and surface-modified carbon nanotubes
View Patent ↗Methods for modifying carbon nanotubes with organic compounds are disclosed. The modified carbon nanotubes have enhanced compatibility with polyolefins. Nanocomposites of the organo-modified carbon nanotubes and polyolefins can be used to produce both fibers and films having enhanced mechanical and electrical properties, especially the elongation-to-break ratio and the toughness of the fibers and/or films.
1. A nanocomposite comprising:
about 70 wt % to about 99.99 wt % of at least one polyolefin; and
about 0.01 wt % to about 30 wt % of at least one modified carbon nanotube, wherein the modified carbon nanotube has been functionalized with at least one modifier comprising an alkene.
2. A nanocomposite as in claim 1 wherein the carbon nanotube comprises a single-wall nanotube.
3. A nanocomposite as in claim 1 wherein the carbon nanotube comprises a multi-wall nanotube.
4. A nanocomposite as in claim 1 wherein the carbon nanotube comprises a carbon nanofiber.
5. A nanocomposite as in claim 1 wherein the at least one modifier is an alkene selected from the group consisting of isoprene, butadiene, isobutadiene, and mixtures thereof.
6. A nanocomposite as in claim 1 wherein the modifier comprises isoprene.
7. A nanocomposite as in claim 1 wherein the polyolefin is selected from the group consisting of polyethylenes, polypropylenes, ethylene-propylene copolymers, ultra-high molecular weight polyethylenes, high pressure low density polyethylenes, linear low density polyethylenes, linear medium density polyethylenes, high density polyethylenes, and modified polyethylenes.
8. A nanocomposite as in claim 1 wherein the polyolefin comprises an ultra-high molecular weight polyethylene.
9. A fiber comprising the nanocomposite of claim 1 .
10. A film comprising the nanocomposite of claim 1 .
11. A nanocomposite comprising:
about 70 wt % to about 99.99 wt % of at least one polyolefin; and
about 0.01 wt % to about 30 wt % of at least one modified carbon nanotube, wherein the modified carbon nanotube has been functionalized with at least one modifier comprising an alkene selected from the group consisting of isoprene, butadiene, isobutadiene, and mixtures thereof.
12. A nanocomposite as in claim 11 wherein the carbon nanotube comprises a single-wall nanotube.
13. A nanocomposite as in claim 11 wherein the carbon nanotube comprises a multi-wall nanotube.
14. A nanocomposite as in claim 11 wherein the carbon nanotube comprises a carbon nanofiber.
15. A nanocomposite as in claim 11 wherein the modifier comprises isoprene.
16. A nanocomposite as in claim 11 wherein the polyolefin is selected from the group consisting of polyethylenes, polypropylenes, ethylene-propylene copolymers, ultra-high molecular weight polyethylenes, high pressure low density polyethylenes, linear low density polyethylenes, linear medium density polyethylenes, high density polyethylenes, and modified polyethylenes.
17. A nanocomposite as in claim 11 wherein the polyolefin comprises an ultra-high molecular weight polyethylene.
18. A fiber comprising the nanocomposite of claim 11 .
19. A film comprising the nanocomposite of claim 11 .