IP Library Granted Patent US 7,678,721
Granted Patent B2
US 7,678,721 · App. 11/586,789 · Granted Mar 16, 2010

Low dielectric glass fiber

Assignee: AGY Holding Corp.
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Quick Facts
Patent No.
US 7,678,721
App. No.
11/586,789
Granted
Mar 16, 2010
Kind
B2
Abstract

A glass fiber having a low dielectric constant and low dielectric loss tangent consists essentially of by weight, as a glass composition, 52 to 60% of SiO 2 , 11 to 16% of Al 2 O 3 , 20 to 30% of B 2 O 3 , and 4 to 8% of CaO, and substantially no MgO, substantially no Li 2 O, substantially no Na 2 O, substantially no K 2 O, and substantially no Ti 2 O. The glass fiber also may contain up to 2% F 2 by weight. The glass fiber is ideal for use as reinforcement for printed wiring boards, and has excellent dielectric properties at frequencies of about 18 GHz or higher.

Claims (36)

1. A low-dielectric-constant glass fiber consisting essentially of 52 to 60% of SiO 2 , 11 to 16% of Al 2 O 3 , 20 to 30% of B 2 O 3 , and 4 to 8% of CaO, by weight, as a glass composition.

2. The low-dielectric-constant glass fiber of claim 1 , wherein the glass fiber consists essentially of 53 to 58% of SiO 2 , 11 to 15% of Al 2 O 3 , 22 to 27% of B 2 O 3 , and 5 to 8% of CaO by weight, as a glass composition.

3. The low-dielectric-constant glass fiber of claim 1 , wherein the glass fiber consists essentially of 54 to 58% of SiO 2 , 11 to 14% of Al 2 O 3 , 24 to 27% of B 2 O 3 , and 5 to 6% of CaO by weight, as a glass composition.

4. The low-dielectric-constant glass fiber of claim 1 , wherein the glass fiber further contains up to about 2% F 2 by weight.

5. The low-dielectric-constant glass fiber of claim 2 , wherein the glass fiber further contains up to about 2% F 2 by weight.

6. The low-dielectric-constant glass fiber of claim 3 , wherein the glass fiber further contains up to about 2% F 2 by weight.

7. The low-dielectric-constant glass fiber of claim 1 , wherein the glass fiber has a dielectric constant less than or equal to about 5, and a dielectric loss tangent less than or equal to about 5×10 −4 at a frequency of 1 MHz at room temperature.

8. The low-dielectric-constant glass fiber of claim 2 , wherein the glass fiber has a dielectric constant less than or equal to about 5, and a dielectric loss tangent less than or equal to about 5×10 −4 at a frequency of 1 MHz at room temperature.

9. The low-dielectric-constant glass fiber of claim 3 , wherein the glass fiber has a dielectric constant less than or equal to about 5, and a dielectric loss tangent less than or equal to about 5×10 −4 at a frequency of 1 MHz at room temperature.

10. The low-dielectric-constant glass fiber of claim 1 , wherein the glass fiber has a dielectric constant less than or equal to about 5, and a dielectric loss tangent less than or equal to about 32×10 −4 at a frequency of 10 GHz at room temperature.

11. The low-dielectric-constant glass fiber of claim 2 , wherein the glass fiber has a dielectric constant less than or equal to about 5, and a dielectric loss tangent less than or equal to about 32×10 −4 at a frequency of 10 GHz at room temperature.

12. The low-dielectric-constant glass fiber of claim 3 wherein the glass fiber has a dielectric constant less than or equal to about 5, and a dielectric loss tangent less than or equal to about 32×10 −4 at a frequency of 10 GHz at room temperature.

13. The low-dielectric-constant glass fiber of claim 1 , wherein the glass fiber has a dielectric constant less than or equal to about 5, and a dielectric loss tangent less than or equal to about 30×10 −4 at a frequency of 18 GHz at room temperature.

14. The low-dielectric-constant glass fiber of claim 2 , wherein the glass fiber has a dielectric constant less than or equal to about 5, and a dielectric loss tangent less than or equal to about 30×10 −4 at a frequency of 18 GHz at room temperature.

15. The low-dielectric-constant glass fiber of claim 3 wherein the glass fiber has a dielectric constant less than or equal to about 5, and a dielectric loss tangent less than or equal to about 30×10 −4 at a frequency of 18 GHz at room temperature.

16. A product comprising a glass fiber according to claim 1 , the product being selected from the group consisting of a printed circuit board, a woven fabric, a non-woven fabric, a unidirectional fabric, a chopped strand, a chopped strand mat, a composite material, and a communication signal transport medium.

17. A product comprising a glass fiber according to claim 2 , the product being selected from the group consisting of a printed circuit board, a woven fabric, a non-woven fabric, a unidirectional fabric, a chopped strand, a chopped strand mat, a composite material, and a communication signal transport medium.

18. A product comprising a glass fiber according to claim 3 , the product being selected from the group consisting of a printed circuit board, a woven fabric, a non-woven fabric, a unidirectional fabric, a chopped strand, a chopped strand mat, a composite material, and a communication signal transport medium.

19. A low-dielectric-constant glass fiber comprising 52 to 60% of SiO 2 , 11 to 16% of Al 2 O 3 , 20 to 30% of B 2 O 3 , and 4 to 8% of CaO, by weight, as a glass composition, and comprising substantially no MgO, substantially no Li 2 O, substantially no Na 2 O, substantially no K 2 O, and substantially no TiO 2 .

20. The low-dielectric-constant glass fiber of claim 19 , wherein the glass fiber comprises 53 to 58% of SiO 2 , 11 to 15% of Al 2 O 3 , 22 to 27% of B 2 O 3 , and 5 to 8% of CaO by weight, as a glass composition, and comprises substantially no MgO, substantially no Li 2 O, substantially no Na 2 O, substantially no K 2 O, and substantially no TiO 2 .

21. The low-dielectric-constant glass fiber of claim 19 , wherein the glass fiber comprises 54 to 58% of SiO 2 , 11 to 14% of Al 2 O 3 , 24 to 27% of B 2 O 3 , and 5 to 6% of CaO by weight, as a glass composition, and comprises substantially no MgO, substantially no Li 2 O, substantially no Na 2 O, substantially no K 2 O, and substantially no TiO 2 .

22. The low-dielectric-constant glass fiber of claim 19 , wherein the glass fiber further contains up to about 2% F 2 by weight.

23. The low-dielectric-constant glass fiber of claim 20 , wherein the glass fiber further contains up to about 2% F 2 by weight.

24. The low-dielectric-constant glass fiber of claim 21 , wherein the glass fiber further contains up to about 2% F 2 by weight.

25. The low-dielectric-constant glass fiber of claim 19 , wherein the glass fiber has a dielectric constant less than or equal to about 5, and a dielectric loss tangent less than or equal to about 5×10 −4 at a frequency of 1 MHz at room temperature.

26. The low-dielectric-constant glass fiber of claim 20 , wherein the glass fiber has a dielectric constant less than or equal to about 5, and a dielectric loss tangent less than or equal to about 5×10 −4 at a frequency of 1 MHz at room temperature.

27. The low-dielectric-constant glass fiber of claim 21 , wherein the glass fiber has a dielectric constant less than or equal to about 5, and a dielectric loss tangent less than or equal to about 5×10 −4 at a frequency of 1 MHz at room temperature.

28. The low-dielectric-constant glass fiber of claim 19 , wherein the glass fiber has a dielectric constant less than or equal to about 5, and a dielectric loss tangent less than or equal to about 32×10 −4 at a frequency of 10 GHz at room temperature.

29. The low-dielectric-constant glass fiber of claim 20 , wherein the glass fiber has a dielectric constant less than or equal to about 5, and a dielectric loss tangent less than or equal to about 32×10 −4 at a frequency of 10 GHz at room temperature.

30. The low-dielectric-constant glass fiber of claim 21 wherein the glass fiber has a dielectric constant less than or equal to about 5, and a dielectric loss tangent less than or equal to about 32×10 −4 at a frequency of 10 GHz at room temperature.

31. The low-dielectric-constant glass fiber of claim 19 , wherein the glass fiber has a dielectric constant less than or equal to about 5, and a dielectric loss tangent less than or equal to about 30×10 −4 at a frequency of 18 GHz at room temperature.

32. The low-dielectric-constant glass fiber of claim 20 , wherein the glass fiber has a dielectric constant less than or equal to about 5, and a dielectric loss tangent less than or equal to about 30×10 −4 at a frequency of 18 GHz at room temperature.

33. The low-dielectric-constant glass fiber of claim 21 wherein the glass fiber has a dielectric constant less than or equal to about 5, and a dielectric loss tangent less than or equal to about 30×10 −4 at a frequency of 18 GHz at room temperature.

34. A product comprising a glass fiber according to claim 19 , the product being selected from the group consisting of a printed circuit board, a woven fabric, a non-woven fabric, a unidirectional fabric, a chopped strand, a chopped strand mat, a composite material, and a communication signal transport medium.

35. A product comprising a glass fiber according to claim 20 , the product being selected from the group consisting of a printed circuit board, a woven fabric, a non-woven fabric, a unidirectional fabric, a chopped strand, a chopped strand mat, a composite material, and a communication signal transport medium.

36. A product comprising a glass fiber according to claim 21 , the product being selected from the group consisting of a printed circuit board, a woven fabric, a non-woven fabric, a unidirectional fabric, a chopped strand, a chopped strand mat, a composite material, and a communication signal transport medium.

Assignments (13)
RELEASE OF SECURITY INTEREST Recorded Sep 21, 2020
From: WELLS FARGO BANK, NATIONAL ASSOCIATION
To: AGY HOLDING CORP.
Reel/Frame 053836/0520 →
RELEASE OF SECURITY INTEREST Recorded Sep 21, 2020
From: U.S. BANK NATIONAL ASSOCIATION
To: AGY HOLDING CORP.
Reel/Frame 053836/0470 →
SECURITY INTEREST Recorded Sep 21, 2020
From: AGY HOLDING CORP.
To: TCW ASSET MANAGEMENT COMPANY LLC
Reel/Frame 053836/0429 →
PATENT SECURITY AGREEMENT Recorded Jul 24, 2015
From: AGY HOLDING CORP.
To: WELLS FARGO BANK, NATIONAL ASSOCIATION
Reel/Frame 036180/0047 →
CORRECTIVE ASSIGNMENT TO CORRECT THE ASSIGNEES' AND ASSIGNOR'S NAME PREVIOUSLY RECORDED ON REEL 035904 FRAME 0070. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST IN PATENTS. Recorded Jun 26, 2015
From: UBS AG
To: AGY HOLDING CORP.; AGY AIKEN LLC; AGY PA OPERATIONS LLC F/K/A AGY HUNTINGDON LLC
Reel/Frame 036080/0313 →
RELEASE OF SECURITY INTEREST IN PATENTS Recorded Jun 12, 2015
From: AGY HOLDING CORP.; AGY AIKEN LLC; AGY PA OPERATIONS LLC F/K/A AGY HUNTINGDON LLC
To: UBS AG
Reel/Frame 035904/0070 →
RELEASE OF SECURITY INTEREST Recorded Jun 10, 2015
From: UBS AG, STAMFORD BRANCH, AS AGENT
To: AGY HOLDING CORP.; AGY AIKEN LLC; AGY HUNTINGDON LLC
Reel/Frame 035880/0051 →
PATENT SECURITY AGREEMENT Recorded Jul 1, 2013
From: AGY HOLDING CORP.
To: U.S. BANK NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 030744/0838 →
PATENT SECURITY AGREEMENT Recorded Jul 1, 2013
From: AGY HOLDING CORP.
To: WELLS FARGO BANK, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 030744/0823 →
SECURITY AGREEMENT Recorded May 13, 2013
From: AGY HOLDING CORP.; AGY AIKEN LLC; AGY HUNTINGDON LLC
To: UBS AG, STAMFORD BRANCH, AS AGENT
Reel/Frame 030406/0847 →
RELEASE OF SECURITY INTEREST Recorded May 13, 2013
From: BANK OF AMERICA, N.A., AS AGENT
To: AGY HOLDING CORP.; AGY AIKEN LLC; AGY HUNTINGDON LLC
Reel/Frame 030405/0327 →
SECURITY AGREEMENT Recorded Mar 9, 2011
From: AGY HOLDING CORP.
To: BANK OF AMERICA, N.A.
Reel/Frame 025920/0217 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 13, 2007
From: BOESSNECK, DOUGLAS S.; GONTERMAN, J. RONALD; PROKHORENKO, OLEG A.
To: AGY HOLDING CORP.
Reel/Frame 018885/0836 →
Continuity (1)
Related Publication 20080103036A1 · May 1, 2008