Phosphonium containing charge transport layer photoconductors

1. A photoconductor comprising a supporting substrate, a photogenerating layer, and at least one charge transport layer comprised of at least one charge transport component, and wherein said at least one charge transport layer contains at least one phosphonium salt, and wherein said salt is present in an amount of from about 0.0001 to about 2.5 weight percent.

2. A photoconductor in accordance with claim 1 wherein said salt is an alkyl phosphonium salt.

3. A photoconductor in accordance with claim 2 wherein said alkyl contains from 1 to about 18 carbon atoms.

4. A photoconductor in accordance with claim 1 wherein said salt is triisobutyl(methyl)phosphonium tosylate.

5. A photoconductor in accordance with claim 1 wherein said salt is at least one of tetradecyl(trihexyl)phosphonium chloride, tetradecyl(trihexyl)phosphonium decanoate, trihexyl(tetradecyl)phosphonium bis 2,4,4-trimethylpentyl phosphinate, tetradecyl(trihexyl)phosphonium dicyanamide, tetradecyl(trihexyl)phosphonium bistriflamide, tetradecyl(trihexyl)phosphonium hexafluorophosphate, tetradecyl(trihexyl)phosphonium tetrafluoroborate, ethyl tri(butyl)phosphonium diethylphosphate, (N-methyl-N-phenylamino)triphenylphosphonium iodide, 2-dimethylaminoethyltriphenylphosphonium bromide, 4-(carboxybutyl)triphenyl phosphonium bromide, amyltriphenylphosphonium bromide, tetrabutylphosphonium benzotriazolate, tetrabutylphosphonium tetraphenylborate, tetrakis(hydroxymethyl)phosphonium chloride, and tributylmethylphosphonium iodide.

6. A photoconductor in accordance with claim 1 wherein said salt is present in an amount of from about 20 parts per million to about 500 parts per million.

7. A photoconductor in accordance with claim 1 wherein said salt is present in an amount of from about 40 parts per million to about 300 parts per million.

8. A photoconductor in accordance with claim 1 wherein said salt is triisobutyl(ethyl)phosphonium tosylate, tetradecyl(trihexyl)phosphonium dicyanamide, or tetradecyl(trihexyl)phosphonium bistriflamide present in an amount of from about 10 parts per million to about 200 parts per million.

9. A photoconductor in accordance with claim 1 wherein said charge transport component is comprised of at least one of aryl amine molecules

wherein X is selected from the group consisting of at least one of alkyl, alkoxy, aryl, and halogen; and wherein X, Y and Z are independently selected from the group consisting of at least one of alkyl, alkoxy, aryl, and halogen.

10. A photoconductor in accordance with claim 1 wherein said charge transport component is an aryl amine selected from the group consisting of N,N′-bis(4-butylphenyl)-N,N′-di-p-tolyl-[p-terphenyl]-4,4″-diamine, N,N′-bis(4-butylphenyl)-N,N′-di-m-tolyl-[p-terphenyl]-4,4″-diamine, N,N′-bis(4-butylphenyl)-N,N′-di-o-tolyl-[p-terphenyl]-4,4″-diamine, N,N-bis(4-butylphenyl)-N,N′-bis-(4-isopropylphenyl)-[p-terphenyl]-4,4″-diamine, N,N′-bis(4-butylphenyl)-N,N′-bis-(2-ethyl-6-methylphenyl)-[p-terphenyl]-4,4″-diamine, N,N′-bis(4-butylphenyl)-N,N′-bis-(2,5-dimethylphenyl)-[p-terphenyl]-4,4″-diamine, N,N′-diphenyl-N,N′-bis(3-chlorophenyl)-[p-terphenyl]-4,4″-diamine, and mixtures thereof, and wherein said at least one charge transport layer is from 1 to about 4, and wherein said salt is tetradecyl(trihexyl)phosphonium chloride, tetradecyl(trihexyl)phosphonium decanoate, trihexyl(tetradecyl)phosphonium bis 2,4,4-trimethylpentylphosphinate, tetradecyl(trihexyl)phosphonium dicyanamide, triisobutyl(methyl)phosphonium tosylate, tetradecyl(trihexyl)phosphonium bistriflamide, tetradecyl(trihexyl) phosphonium hexafluorophosphate, tetradecyl(trihexyl)phosphonium tetrafluoroborate, ethyl tri(butyl)phosphonium diethylphosphate, (N-methyl-N-phenylamino)triphenylphosphonium iodide, 2-dimethylaminoethyltriphenyl phosphonium bromide, 4-(carboxybutyl)triphenylphosphonium bromide, amyltriphenylphosphonium bromide, tetrabutylphosphonium benzotriazolate, tetrabutylphosphonium tetraphenylborate, tetrakis(hydroxymethyl)phosphonium chloride, and tributylmethylphosphonium iodide.

11. A photoconductor in accordance with claim 1 further including in at least one of said charge transport layers an antioxidant comprised of at least one of a hindered phenolic and a hindered amine, and wherein said at least one charge transport layer is from 1 to about 4.

12. A photoconductor in accordance with claim 1 wherein said photogenerating layer is comprised of at least one photogenerating pigment.

13. A photoconductor in accordance with claim 12 wherein said photogenerating pigment is comprised of at least one of a metal phthalocyanine, a perylene, and a metal free phthalocyanine.

14. A photoconductor in accordance with claim 12 wherein said photogenerating pigment is comprised of chlorogallium phthalocyanine, or a titanyl phthalocyanine.

15. A photoconductor in accordance with claim 12 wherein said photogenerating pigment is comprised of hydroxygallium phthalocyanine.

16. A photoconductor in accordance with claim 1 further including a hole blocking layer, and an adhesive layer.

17. A photoconductor in accordance with claim 1 wherein said at least one charge transport layer is comprised of a first and a second charge transport layer, and wherein said salt is included in said first charge transport layer in an amount of from about 20 to about 175 parts per million based on the first charge transport layer components.

18. A photoconductor in accordance with claim 1 wherein said at least one charge transport layer is comprised of a top charge transport layer and a bottom charge transport layer, and wherein said top layer is in contact with said bottom layer and said bottom layer is in contact with said photogenerating layer, and wherein said bottom layer includes a salt of tetradecyl(trihexyl)phosphonium chloride, tetradecyl(trihexyl)phosphonium decanoate, trihexyl(tetradecyl)phosphonium bis 2,4,4-trimethylpentylphosphinate, tetradecyl(trihexyl)phosphonium dicyanamide, triisobutyl(methyl)phosphonium tosylate, tetradecyl(trihexyl)phosphonium bistriflamide, tetradecyl(trihexyl)phosphonium hexafluorophosphate, tetradecyl(trihexyl)phosphonium tetrafluoroborate, ethyl tri(butyl)phosphonium diethylphosphate, (N-methyl-N-phenylamino)triphenylphosphonium iodide, 2-dimethylaminoethyltriphenylphosphonium bromide, 4-(carboxybutyl)triphenyl phosphonium bromide, amyltriphenylphosphonium bromide, tetrabutylphosphonium benzotriazolate, tetrabutylphosphonium tetraphenylborate, tetrakis(hydroxymethyl)phosphonium chloride, or tributylmethylphosphonium iodide.

19. A photoconductor comprised in sequence of a supporting substrate, a photogenerating layer, and a charge transport layer; and wherein said charge transport layer contains a phosphonium salt.

20. A photoconductor in accordance with claim 19 wherein said charge transport layer is comprised of a first charge transport layer and a second charge transport layer, and wherein said salt is included in said first charge transport layer in contact with said photogenerating layer, and said salt is present in an amount of from about 10 parts per million to about 500 parts per million.

21. A photoconductor in accordance with claim 20 wherein said salt is at least one of tetradecyl(trihexyl)phosphonium chloride, tetradecyl(trihexyl) phosphonium decanoate, trihexyl(tetradecyl)phosphonium bis 2,4,4-trimethylpentylphosphinate, tetradecyl(trihexyl)phosphonium dicyanamide, triisobutyl(methyl)phosphonium tosylate, tetradecyl(trihexyl)phosphonium bistriflamide, tetradecyl(trihexyl)phosphonium hexafluorophosphate, tetradecyl(trihexyl)phosphonium tetrafluoroborate, ethyl tri(butyl)phosphonium diethylphosphate, (N-methyl-N-phenylamino)triphenylphosphonium iodide, 2-dimethylaminoethyltriphenylphosphonium bromide, 4-(carboxybutyl)triphenyl phosphonium bromide, amyltriphenylphosphonium bromide, tetrabutylphosphonium benzotriazolate, tetrabutylphosphonium tetraphenylborate, tetrakis(hydroxymethyl)phosphonium chloride, and tributylmethylphosphonium iodide, and which salt is present in an amount of from about 0.003 to about 3 weight percent.

22. A photoconductor in accordance with claim 1 wherein the substrate is comprised of aluminum, wherein said salt primarily functions to control the photosensitivity of said photoconductor, and wherein said salt is present in an amount of from about 0.001 to about 1 weight percent.

23. A photoconductor comprising a supporting substrate, a photogenerating layer, a first hole transport layer and a second hole transport layer, and wherein said first hole transport layer has incorporated therein a phosphonium salt selected from the group consisting of tetradecyl(trihexyl)phosphonium chloride, tetradecyl(trihexyl)phosphonium decanoate, trihexyl(tetradecyl)phosphonium bis 2,4,4-trimethylpentylphosphinate, tetradecyl(trihexyl)phosphonium dicyanamide, triisobutyl(methyl)phosphonium tosylate, tetradecyl(trihexyl)phosphonium bistriflamide, tetradecyl(trihexyl)phosphonium hexafluorophosphate, tetradecyl(trihexyl)phosphonium tetrafluoroborate, ethyl tri(butyl)phosphonium diethylphosphate, (N-methyl-N-phenylamino)triphenylphosphonium iodide, 2-dimethylaminoethyltriphenylphosphonium bromide, 4-(carboxybutyl)triphenyl phosphonium bromide, amyltriphenylphosphonium bromide, tetrabutylphosphonium benzotriazolate, tetrabutylphosphonium tetraphenylborate, tetrakis(hydroxymethyl) phosphonium chloride, tributylmethylphosphonium iodide, and mixtures thereof, and which salt is present in an amount of from about 2 to about 300 parts per million.

24. A photoconductor in accordance with claim 23 wherein said salt is triisobutyl(methyl)phosphonium tosylate.