High-solids lime slurry
Novel hydrated-lime slurry compositions are disclosed, which include a heat-stable polymeric dispersant. The polymeric dispersant is capable to withstand temperatures in excess of 212° F. experienced by the slurry as a result of the hydrolysis of quicklime to produce hydrated lime, and accordingly can be added to the slurry composition prior to the addition of quicklime. Methods for making such slurry compositions are also disclosed.
1. A slurry for use as an alkaline-neutralization agent, comprising:
30-60 weight percent suspended hydrated lime particles, said hydrated lime particles having a mean particle size not greater than 50 mesh;
0.4-1.2 weight percent heat-stable polymeric dispersant, calculated as a percentage of the hydrated lime present;
0.8-1.5 weight percent gypsum, calculated as a percentage of the hydrated lime present; and
balance water;
said slurry having a viscosity less than 2,000 cps at 70° F., said heat-stable polymeric dispersant being effective to withstand temperatures in excess of 212° F. without losing its ability to maintain said slurry viscosity below 2,000 cps at 70° F.
2. The slurry of claim 1 , said hydrated lime particles having a mean particle size not greater than 40-mesh.
3. The slurry of claim 1 , comprising:
37-41 weight percent of said suspended hydrated lime particles;
0.7-0.8 weight percent of said heat-stable polymeric dispersant, calculated as a percentage of the hydrated lime present; and
1-1.2 weight percent of said gypsum, calculated as a percentage of the hydrated lime present.
4. The slurry of claim 3 , said gypsum being present in the form of particles having a mean particle size not greater than 40-mesh.
5. The slurry of claim 1 , said heat-stable polymeric dispersant being effective to withstand temperatures in excess of 220° F. without losing its ability to maintain said slurry viscosity below 2,000 cps at 70° F.
6. The slurry of claim 1 , said heat-stable polymeric dispersant comprising a straight-chain polyacrylate homopolymer having a molecular weight in the range of 4500-5000 g/mol, which is made using an organic initiator and an isopropyl alcohol chain-transfer agent.
7. The slurry of claim 6 , said straight-chain polyacrylate homopolymer being substantially devoid of iron.
8. The slurry of claim 6 , said straight-chain polyacrylate homopolymer having a nominal molecular weight of 4500 g/mol.
9. The slurry of claim 6 , said straight-chain polyacrylate homopolymer comprising acid solids.
10. The slurry of claim 1 , said slurry excluding alkali-metal hydroxides.
11. The slurry of claim 1 , said slurry having a viscosity in the range of 600-800 cps at 70° F.