Nano-powder-based coating and ink compositions
View Patent ↗Nano-powder-based coating and ink compositions, methods for producing and using these compositions, and articles prepared from these compositions are described.
1. A method of producing an article comprising:
(a) providing a composition comprising nano-particles dispersed in a liquid carrier
comprising (a) water, a water-miscible organic solvent, or combination thereof and (b) an organic solvent that evaporates more quickly than the water, water-miscible organic solvent, or combination thereof,
wherein the combination of (a) the water, water-miscible organic solvent, or combination thereof and (b) the organic solvent that evaporates more quickly than the water, water-miscible solvent, or combination thereof, together form an emulsion;
(b) applying the composition to a surface of a substrate; and
(c) drying the composition to remove the liquid carrier, whereupon the nano-particles self-assemble to form a transparent and electrically conductive coating in the form of a network-like pattern that includes interconnected traces defining randomly shaped cells on the surface of the substrate,
wherein the coating is transparent to light at wavelengths in the range of 400 to 700 nm.
2. A method according to claim 1 comprising sintering the nano-particles at a temperature no greater than 300° C. following application to the surface of the substrate.
3. A method according to claim 1 comprising sintering the nano-particles at a temperature no greater than 150° C. following application to the surface of the substrate.
4. A method according to claim 1 comprising sintering the nano-particles at a temperature no greater than 50° C. following application to the surface of the substrate.
5. A method according to claim 1 comprising sintering the nano-particles at a temperature between 50 and 300° C. following application to the surface of the substrate.
6. A method according to claim 1 comprising sintering the nano-particles at a temperature between 50 and 150° C. following application to the surface of the substrate.
7. A method according to claim 1 comprising exposing the nano-particles to a chemical reagent following application to the surface of the substrate to reduce the electrical resistance of the network.
8. A method according to claim 7 wherein the chemical reagent is in the form of a vapor.
9. A method according to claim 7 wherein the chemical reagent is in the form of a liquid.
10. A method according to claim 7 wherein the chemical reagent comprises an organic acid.
11. A method according to claim 10 wherein the organic acid comprises formic acid.
12. A method according to claim 10 wherein the organic acid comprises acetic acid.
13. A method according to claim 7 wherein the chemical reagent comprises an organic aldehyde.
14. A method according to claim 13 wherein the organic aldehyde comprises formaldehyde.
15. A method according to claim 7 comprising exposing the nano-particles to the chemical reagent at ambient temperature.
16. A method according to claim 1 comprising sintering the nano-particles at a temperature no greater than 300° C. in the presence of an organic acid selected from the group consisting of formic acid, acetic acid, and combinations thereof following application to the substrate.
17. A method according to claim 1 comprising sintering the nano-particles at a temperature no greater than 150° C. in the presence of an organic acid selected from the group consisting of formic acid, acetic acid, and combinations thereof following application to the substrate.
18. A method according to claim 1 comprising sintering the nano-particles at a temperature no greater than 50° C. in the presence of an organic acid selected from the group consisting of formic acid, acetic acid, and combinations thereof following application to the substrate.
19. A method according to claim 1 comprising sintering the nano-particles at a temperature between 50 and 300° C. in the presence of formic acid following application to the substrate.
20. A method according to claim 1 wherein the substrate is selected from the group consisting of glass substrates, rigid polymer substrates, flexible polymer substrates, and combinations thereof.
21. A method according to claim 1 wherein the substrate is selected from the group consisting of metal substrates, ceramic substrates, and combinations thereof.
22. A method according to claim 1 wherein the substrate is a paper substrate.
23. A method according to claim 1 wherein the substrate comprises a polymer substrate having a glass transition temperature no greater than 150° C.
24. A method according to claim 1 comprising applying the composition to the surface of the substrate according to a predetermined pattern.
25. A method according to claim 1 wherein the nano-particles comprise a metal element.
26. A method according to claim 1 wherein the nano-particles comprise a metal oxide.
27. A method according to claim 1 wherein the nano-particles include a metal element selected from the group consisting of silver, gold, platinum, palladium, nickel, cobalt, copper, and combinations thereof.
28. A method according to claim 1 wherein the nano-particles are prepared according to a process comprising:
(a) forming an alloy comprising an auxiliary metal and a metal; and
(b) treating the alloy with a leaching agent to remove the auxiliary metal.
29. A method according to claim 28 wherein the auxiliary metal comprises aluminum.
30. A method according to claim 1 wherein the nano-particles have a D90 value of less than 0.1 μm.
31. A method according to claim 1 wherein the water-miscible organic solvent is selected from the group consisting of methanol, ethanol, ethylene glycol, glycerol, dimethylformamide, dimethylacetamide, acetonitrile, dimethylsulfoxide, N-methylpyrrolidone, and combinations thereof.
32. A method according to claim 1 wherein the organic solvent that evaporates more quickly than water, the water-miscible solvent, or combination thereof is selected from the group consisting of petroleum ether, hexane, heptane, toluene, benzene, dichloroethane, trichloroethylene, chloroform, dichloromethane, nitromethane, dibromomethane, cyclopentanone, cyclohexanone, and combinations thereof.
33. A method according to claim 1 wherein the composition further comprises an agent selected from the group consisting of polymers, binders, surfactants, dispersants, coupling agents, and combinations thereof.
34. A method according to claim 1 wherein the network has a percent light transmission of 10% to 90% at a wavelength of 400 nm to 700 nm.
35. A method according to claim 1 wherein the network has a percent light transmission of 30% to 90% at a wavelength of 400 nm to 700 nm.
36. A method according to claim 1 wherein the network has a haze value of 0.1% to 10%.
37. A method according to claim 1 wherein the network has a haze value of 0.50% to 50%.
38. A method according to claim 1 wherein the network has an electrical resistance of 0.1 Ω/square to 1,000 Ω/square.
39. A method according to claim 1 wherein the network has an electrical resistance of 0.1 Ω/square to 10,000 Ω/square.
40. A method according to claim 1 wherein the network has an electrical resistance of 0.1 Ω/square to 10,000 Ω/square and has a percent transmission of 10% to 90% at a wavelength of 400 nm to 700 nm.
41. A method according to claim 1 further comprising transferring the network to a second substrate.
42. A method according to claim 1 comprising applying the composition to the surface of the substrate by ink jet printing.
43. A method of producing an article comprising:
(A) providing an emulsion comprising nano-particles dispersed in a liquid carrier that includes (a) water, a water-miscible organic solvent, or combination thereof and (b) an organic solvent that evaporates more quickly than the water, water-miscible solvent, or combination thereof,
wherein the combination of (a) the water, water-miscible organic solvent, or combination thereof and (b) the organic solvent that evaporates more quickly than the water, water-miscible solvent, or combination thereof, together form the emulsion,
wherein the nano-particles have a D90 value of less than 0.1 μm and are prepared according to a process comprising:
(i) forming an alloy comprising aluminum and a metal; and
(ii) treating the alloy with a leaching agent to remove the aluminum;
(B) applying the composition to a surface of a substrate;
(C) drying the composition to remove the liquid carrier, whereupon the nano-particles self-assemble to form an article comprising the nano-particles in the form of an electrically conductive network on the surface of the substrate; and
(D) sintering the nano-particles at a temperature no greater than 50° C. in the presence of an organic acid following application to the surface of the substrate,
wherein the network is transparent to light at wavelengths in the range of 400 to 700 nm and has an electrical resistance of 0.1 Ω/square to 1,000 Ω/square.