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Disclosed is a formulation for the absorption of CO 2 , which comprises water, at least one CO 2 absorption compound and a carbonic anhydrase as an activator to enhance the absorption capacity of the CO 2 absorption compound. The invention also concerns the use of carbonic anhydrase, in a CO 2 absorption solution to increase the CO 2 absorption rate of such solution.
1. A formulation for the absorption of CO 2 , comprising:
water and
at least one CO 2 absorption compound selected from the group consisting of N-methyldiethanolamine (MDEA), piperazine (PZ) and 2-(2-aminoethylamino)ethanol (AEE), forming a solution; and
carbonic anhydrase as an activator to enhance the absorption of the solution.
2. A method to activate a CO 2 absorption solution, which comprises:
contacting gaseous CO 2 with an aqueous CO 2 absorption solution comprising at least one CO 2 absorption compound selected from the group consisting of N-methyldiethanolamine (MDEA), piperazine (PZ) and 2-(2-aminoethylamino)ethanol (AEE); and
adding carbonic anhydrase to said CO 2 absorption solution while it is contacted with said gaseous CO 2 .
3. The formulation of claim 1 , wherein the carbonic anhydrase is immobilized on a support.
4. The formulation of claim 1 , wherein the carbonic anhydrase is a component of the solution.
5. The method of claim 2 , wherein the carbonic anhydrase is immobilized on a packing and the CO 2 absorption solution flows through the packing.
6. The method of claim 2 , wherein the carbonic anhydrase is directly present in and flows with the CO 2 absorption solution.
7. The formulation of claim 1 , wherein the CO 2 absorption compound comprises MDEA.
8. The formulation of claim 1 , wherein the CO 2 absorption compound comprises PZ.
9. The formulation of claim 1 , wherein the CO 2 absorption compound comprises AEE.
10. The method of claim 2 , wherein the CO 2 absorption compound comprises MDEA.
11. The method of claim 2 , wherein the CO 2 absorption compound comprises PZ.
12. The method of claim 2 , wherein the CO 2 absorption compound comprises AEE.