UV-curable ink-jet ink, electronic circuit board, electronic component and display device
A UV-curable ink-jet ink is provided, which has a high sensitivity and allows soft and highly fine patterns to be formed. The UV-curable ink-jet ink includes a mono-functional polymerizable monomer (A) having a hydroxyl group, a di(meth)acrylate ester (B) and a photo-polymerization initiator (C).
1. A UV-curable ink-jet ink, comprising a mono-functional polymerizable monomer (A) having a hydroxyl group, a di(meth)acrylate ester (B) and a photo-polymerization initiator (C), wherein the mono-functional polymerizable monomer (A) having a hydroxyl group is a compound of formula (1):
wherein R 1 is a C 4 -C 12 alkylene group which is a straight chain or has a ring structure, R 2 is a C 1 -C 3 alkyl group or hydrogen, and n is an integer of 1-30.
2. The UV-curable ink-jet ink of claim 1 , wherein the di(meth)acrylate ester (B) is one or more selected from the group consisting of diacrylate modified by bisphenol-F ethylene oxide, diacrylate modified by bisphenol-A ethylene oxide, diacrylate modified by ethylene oxide isocyanurate, polyethyleneglycol diacrylate, polypropyleneglycol diacrylate, pentaerythritol diacrylate, pentaerythritol diacrylate monostearate, 1,4-butanediol diacrylate, 1,6-hexanediol diacrylate, 1,9-nonanediol diacrylate, 1,4-cyclohexanedimethanol diacrylate, 2-n-butyl-2-ethyl-1,3-propanediol diacrylate, trimethyloipropane diacrylate and dipentaerythritol diacrylate.
3. The UV-curable ink-jet ink of claim 1 , wherein the di(meth)acrylate ester (B) is one or more selected from the group consisting of diacrylate modified by bisphenol-F ethylene oxide, diacrylate modified by bisphenol-A ethylene oxide and diacrylate modified by ethylene oxide isocyanurate.
4. The UV-curable ink-jet ink of claim 1 , wherein the mono-functional polymerizable monomer (A) having a hydroxyl group is 4-hydroxybutyl (meth)acrylate or 1,4-cyclohexanedimethanol mono(meth)acrylate, the di(meth)acrylate ester (B) is one or more selected from the group consisting of diacrylate modified by bisphenol-F ethylene oxide, diacrylate modified by bisphenol-A ethylene oxide and diacrylate modified by ethylene oxide isocyanurate, and the photo-polymerization initiator (C) is 2-benzyl-2-dimethylamino-1-(4-morpholinophenyl)- 1-butanone.
5. The UV-curable ink-jet ink of claim 1 , further comprising a compound (D) having two or more oxirane groups or oxetane groups.
6. The UV-curable ink-jet ink of claim 5 , wherein the compound (D) having two or more oxirane groups or oxetane groups is one or more selected from compounds of formulae (7), (8), (9) and (10):
wherein in formula (7), m is an integer of 0-10.