Method for preparing functional nanomaterials utilizing endothermic reaction
A method is disclosed whereby a functional nanomaterial such as a monolayer carbon nanotube, a monolayer boron nitride nanotube, a monolayer silicon carbide nanotube, a multilayer carbon nanotube with the number of layers controlled, a multilayer boron nitride nanotube with the number of layers controlled, a multilayer silicon carbide nanotube with the number of layers controlled, a metal containing fullerene, and a metal containing fullerene with the number of layers controlled is produced at a high yield. According to the method, when a multilayer carbon nanotube ( 3 ) is formed by a chemical vapor deposition or a liquid phase growth process, an endothermic reaction aid (H 2 S) is introduced in addition to a primary reactant (CH 4 , H 2 ) in the process to form a monolayer carbon nanotube ( 4 ).
1. A method of making a functional nanomaterial comprising converting a multilayer nanotube into a monolayer nanotube by heat-treating the multilayer nanotube in a gas phase comprising at least one reactant selected from the group consisting of hydrogen sulfide (H 2 S), carbon monoxide (CO), nitrous oxide (N 2 O), and sulfur (S), whereby multilayer walls are stripped from the multilayer nanotube to thereby form a monolayer nanotube.
2. A method of making a functional nanomaterial as set forth in claim 1 , wherein said multilayer nanotube is a multilayer carbon nanotube, a multilayer boron nitride nanotube or a multilayer silicon carbide nanotube.
3. The method of making a functional nanomaterial as set forth in claim 1 , wherein said multilayer nanotube is a multilayer carbon nanotube, said reactant is hydrogen sulfide (H 2 S), and said heat-treatment temperature is 230° C. or higher.