Organometallic complex, and light-emitting element and light-emitting device using the organometallic complex
View Patent ↗A material which can emit phosphorescence is disclosed. Further, a light-emitting element having good chromaticity is disclosed. An embodiment of the present invention is an organometallic complex including a structure as represented by the general formula (1): wherein R 1 represents an alkyl group having 1 to 4 carbon atoms; each of R 2 to R 5 represents any one of hydrogen, a halogen element, an acyl group, an alkyl group, an alkoxyl group, an aryl group, a cyano group, and a heterocyclic group; Ar represents an aryl group or a heterocyclic group, preferably, an aryl group having an electron withdrawing group or a heterocyclic group having an electron withdrawing group; and M represents a Group 9 element or a Group 10 element. By virtue that the Ar has an electron withdrawing group, an organometallic complex which emits phosphorescence with higher emission intensity can be obtained.
1. An organometallic complex comprising a structure represented by a formula (1):
wherein R 1 represents an alkyl group having 1 to 4 carbon atoms; each of R 2 to R 5 represents hydrogen; Ar represents an aryl group; and M represents a Group 9 element or a Group 10 element.
2. An organometallic complex comprising a structure represented by a formula (2):
wherein R 11 represents an alkyl group having 1 to 4 carbon atoms; each of R 12 to R 15 represents hydrogen; each of R 16 to R 19 represents one of hydrogen and an electron withdrawing group; and M represents a Group 9 element or a Group 10 element.
3. An organometallic complex comprising a structure represented by a formula (3):
wherein R 21 represents an alkyl group having 1 to 4 carbon atoms; each of R 22 to R 25 represents hydrogen; Ar represents an aryl group; and M represents a Group 9 element or a Group 10 element, in which n=2 when M represents a Group 9 element whereas n=1 when M represents a Group 10 element; and L represents a monoanionic ligand having a beta-diketone structure, or a monoanionic bidentate chelate ligand having a carboxyl group, or a monoanionic bidentate chelate ligand having a phenolic hydroxyl group.
4. An organometallic complex comprising a structure represented by a formula (4):
wherein R 31 represents an alkyl group having 1 to 4 carbon atoms; each of R 32 to R 35 represents hydrogen; each of R 36 to R 39 represents one of hydrogen and an electron withdrawing group; M represents a Group 9 element or a Group 10 element, in which n=2 in the case that M represents a Group 9 element whereas n=1 in the case that M represents a Group 10 element; and L represents a monoanionic ligand having a beta-diketone structure, or a monoanionic bidentate chelate ligand having a carboxyl group, or a monoanionic bidentate chelate ligand having a phenolic hydroxyl group.
5. The red-emissive organometallic complex according to claim 3 or 4 , wherein L represents a monoanionic chelate ligand represented by any one of structural formulae 5 to 11:
6. An organometallic complex represented by any one of structural formulae 12 to 14:
7. The red-emissive organometallic complex according to claim 2 , wherein the electron withdrawing group is a halogen element.
8. The red-emissive organometallic complex according to claim 2 , wherein the electron withdrawing group is a cyano group.
9. The red-emissive organometallic complex according to claim 2 , wherein the electron withdrawing group is a perfluorocarbon.
10. The red-emissive organometallic complex according to claim 2 , wherein the electron withdrawing group is a fluorine.
11. The red-emissive organometallic complex according to claim 2 , wherein the electron withdrawing group is a chlorine.
12. The red-emissive organometallic complex according to claim 4 , wherein the electron withdrawing group is a halogen element.
13. The red-emissive organometallic complex according to claim 4 , wherein the electron withdrawing group is a cyano group.
14. The red-emissive organometallic complex according to claim 4 , wherein the electron withdrawing group is a perfluorocarbon.
15. The red-emissive organometallic complex according to claim 4 , wherein the electron withdrawing group is a fluorine.
16. The red-emissive organometallic complex according to claim 4 , wherein the electron withdrawing group is a chlorine.