Method of reducing porosity in thermal spray coated and sintered articles

1. A method for sealing porosity of at least a portion of an outer porous surface of an article, said method comprising (i) applying a first solution on the outer porous surface of said article, (ii) infiltrating at least a portion of the outer porous surface with said first solution, (iii) applying a second solution on the outer porous surface of said article, (iv) infiltrating at least a portion of the outer porous surface with said second solution, (v) allowing the infiltrated first solution and the infiltrated second solution to react, thereby forming an infiltrated solid precipitate, said infiltrated solid precipitate sealing the porosity of at least a portion of the outer porous surface of said article, and (vi) heating the article at a temperature of greater than about 750° C. in order to convert the infiltrated solid precipitate to an oxide.

2. The method of claim 1 wherein (i) the first solution comprises a basic solution and the second solution comprises a metal salt solution, or (ii) the first solution comprises a metal salt solution and the second solution comprises a basic solution.

3. The method of claim 1 wherein (i) the first solution comprises a metal salt selected from yttrium nitrate, cerium nitrate or lanthanum nitrate and the second solution comprises a base selected from ammonium hydroxide, potassium hydroxide or sodium hydroxide, or (ii) the first solution comprises a base selected from ammonium hydroxide, potassium hydroxide or sodium hydroxide and the second solution comprises a metal salt selected from yttrium nitrate, cerium nitrate or lanthanum nitrate.

4. The method of claim 1 wherein the infiltrated solid precipitate comprises yttrium hydroxy nitrate, cerium hydroxy nitrate or lanthanum hydroxyl nitrate.

5. The method of claim 1 wherein the article comprises a metallic article with a thermally sprayed coating or a sintered porous metallic or ceramic article.

6. The method of claim 1 wherein the article comprises a chamber or a component of said chamber used in the production of an integrated circuit component.

7. A method for sealing porosity of at least a portion of an outer porous surface of an article, said method comprising (i) applying a sealant solution comprising a metal salt solution and a basic solution on the outer porous surface of said article, wherein said metal salt solution comprises a metal salt selected from yttrium nitrate, cerium nitrate or lanthanum nitrate, and said basic solution comprises a base selected from ammonium hydroxide, potassium hydroxide or sodium hydroxide, (ii) infiltrating at least a portion of the outer porous surface with said sealant solution, (iii) allowing the metal salt solution and the basic solution of the sealant solution to react, thereby forming an infiltrated solid precipitate wherein the infiltrated solid precipitate comprises yttrium hydroxy nitrate, cerium hydroxy nitrate or lanthanum hydroxyl nitrate, said infiltrated solid precipitate sealing the porosity of at least a portion of the outer porous surface of said article, and (iv) heating the article at a temperature of greater than about 750° C. in order to convert the infiltrated solid precipitate to an oxide.

8. The method of claim 7 wherein the article comprises a metallic article with a thermally sprayed coating or a sintered porous metallic or ceramic article.

9. The method of claim 7 wherein the article comprises a chamber or a component of said chamber used in the production of an integrated circuit component.

10. A method for sealing porosity of at least a portion of an outer surface of an article, said method comprising:

(a) preparing a first reactive solution;

(b) applying the first reactive solution on the outer porous surface of the article;

(c) allowing the first reactive solution to infiltrate the outer porous surface of the article;

(d) applying a second reactive solution on the outer porous surface of the article;

(e) allowing the second reactive solution to infiltrate the outer porous surface of the article;

(f) allowing the first and second reactive solutions to react, thereby forming an infiltrated solid precipitate, said infiltrated solid precipitate sealing the porosity of at least a portion of the outer porous surface of said article; and

(g) heating the article at a temperature of greater than about 750° C. to substantially remove water from the article and to convert the infiltrated solid precipitate to an oxide.

11. The method of claim 10 wherein (i) the first reactive solution comprises a basic solution and the second reactive solution comprises a metal salt solution, or (ii) the first reactive solution comprises a metal salt solution and the second reactive solution comprises a basic solution.

12. The method of claim 10 wherein (i) the first reactive solution comprises a metal salt selected from yttrium nitrate, cerium nitrate or lanthanum nitrate and the second reactive solution comprises a base selected from ammonium hydroxide, potassium hydroxide or sodium hydroxide, or (ii) the first reactive solution comprises a base selected from ammonium hydroxide, potassium hydroxide or sodium hydroxide and the second reactive solution comprises a metal salt selected from yttrium nitrate, cerium nitrate or lanthanum nitrate.

13. The method of claim 10 wherein the infiltrated solid precipitate comprises yttrium hydroxy nitrate, cerium hydroxy nitrate or lanthanum hydroxyl nitrate.

14. The method of claim 10 wherein the article comprises a metallic article with a thermally sprayed coating, or a sintered porous metallic or ceramic article.

15. The method of claim 10 wherein the article comprises a chamber or a component of said chamber used in the production of an integrated circuit component.