Method for producing a nonostructured functional coating and a coating that can be produced according to said method
View Patent ↗A method for producing a nanostructured, in particular a ceramic-like functional coating on a substrate is described. To that end, using at least one plasma source, a pulsed plasma is produced with which a matrix phase and at least one nano-scale interstitial phase embedded in it are deposited on the substrate via a material input. Preferably a plurality of pulsed plasma sources that are time-correlated or synchronized with each other are used. Also proposed is a nanostructured functional coating, in particular one producible by this method, which is free of chlorine and/or sulfur, and which contains at least one metal and/or at least one element selected from the group oxygen, hydrogen, nitrogen, carbon, helium, argon or neon.
1. A tool, comprising:
a nanostructure including:
a substrate; and
a functional coating deposited on the substrate, the functional coating including a matrix phase and at least one nano-scale interstitial phase embedded in the matrix phase;
wherein the functional coating is free of at least one of chlorine and sulfur and contains at least one of a metal and at least one element corresponding to one of oxygen, hydrogen, nitrogen, carbon, helium, argon, and neon,
wherein the matrix phase is one of amorphous, metallic, microcrystalline, and crystalline, and the at least one nano-scale interstitial phase includes a nanocrystalline interstitial phase with a mean grain size of 1 nm to 100 nm,
wherein the nanostructure is produced by causing at least one plasma source to produce a pulsed plasma, with which a matrix phase and at least one nano-scale interstitial phase embedded therein are deposited on a substrate via a material input, and
wherein the matrix phase is made of one of a metal, an alloy, a silicon nitride, MoSi 2 , amorphous carbon, and DLC (diamond-like carbon), and wherein a metal oxide is embedded as the nano-scale interstitial phase.
2. The tool according to claim 1 , wherein the pulsing of the at least one plasma source occurs at a frequency of 500 Hz to 100 kHz using at least one of pulses having a shape that is one of at least approximately rectangular, at least approximately trapezoidal, at least approximately saw-tooth, and at least approximately sine-wave pulse-shaped, and pulses having shapes with differing rising and falling functions.
3. The tool according to claim 2 , wherein the at least one plasma source is a sputtering source.
4. The tool according to claim 2 , wherein the pulsing of the at least one plasma source is operated at a frequency of 10 kHz and 90 kHz.
5. The tool according to claim 2 , wherein the pulsing of the at least one plasma source is operated with a pulse-to-pause ratio of 1:10 to 2:1.
6. The tool according to claim 2 , wherein the pulsing of the at least one plasma source is operated with a pulse-to-pause ratio of 1:4 to 1:1.
7. The tool according to claim 2 , wherein the at least one plasma source is operated with a peak pulse power of 5 kW to 40 kW.
8. The tool according to claim 1 , wherein the metal oxide includes one of titanium oxide, chromium oxide, zirconium oxide and tantalum oxide.
9. The tool according to claim 1 , wherein the nanocrystalline interstitial phase has a mean grain size of 3 nm to 30 nm.
10. The tool according to claim 1 , wherein the pulsing of the at least one plasma source occurs at a frequency of 500 Hz to 100 kHz using at least one of pulses having a shape that is one of at least approximately rectangular, at least approximately trapezoidal, at least approximately saw-tooth, and at least approximately sine-wave pulse-shaped, and pulses having shapes with differing rising and falling functions, and wherein the metal oxide includes one of titanium oxide, chromium oxide, zirconium oxide and tantalum oxide.
11. The tool according to claim 10 , wherein the at least one plasma source is a sputtering source, wherein the pulsing of the at least one plasma source is operated at a frequency of 10 kHz and 90 kHz.
12. The tool according to claim 11 , wherein the pulsing of the at least one plasma source is operated with a pulse-to-pause ratio of 1:10 to 2:1.
13. The tool according to claim 12 , wherein the at least one plasma source is operated with a peak pulse power of 5 kW to 40 kW, and wherein the nanocrystalline interstitial phase has a mean grain size of 3 nm to 30 nm.
14. The tool according to claim 11 , wherein the pulsing of the at least one plasma source is operated with a pulse-to-pause ratio of 1:4 to 1:1.
15. The tool according to claim 14 , wherein the at least one plasma source is operated with a peak pulse power of 5 kW to 40 kW, and wherein the nanocrystalline interstitial phase has a mean grain size of 3 nm to 30 nm.
16. The tool according to claim 11 , wherein the at least one plasma source is operated with a peak pulse power of 5 kW to 40 kW, and wherein the nanocrystalline interstitial phase has a mean grain size of 3 nm to 30 nm.