Peroxide-cured thermoplastic vulcanizates and medical devices made therewith

1. A method of preparing a thermoplastic vulcanizate comprising:

dynamically vulcanizing poly(ethylene-co-propylene-co-5-ethylidene-2-norbornen) rubber within a blend comprising 100 parts by weight of the rubber, about 15 to about 25 parts by weight polypropylene, from about 10 to about 250 parts by weight clay or carbon black, about 70 to about 200 parts by weight of an extender oil, and a single cure system consisting of an organic peroxide cure agent and from about 1 to about 12 parts by weight triallyl isocyanurate, wherein the single cure system is the only cure system, to thereby form a thermoplastic vulcanizate;

where said step of dynamically vulcanizing cures the rubber to an extent where not more than 10 weight percent of the rubber is extractable by cyclohexane at 23° C. and where the thermoplastic vulcanizate can be formed into an extrudate that includes less crystalline bloom than can be detected without special optical magnification after 60 days.

2. The method of claim 1 , where the organic peroxide includes 2,5-dimethyl-2,5-di(t-butylperoxy)hexane.

3. The method of claim 1 , where the dynamic vulcanization is effected with from about 3 to about 4 parts by weight triallyl isocyanurate per 100 parts by weight rubber.

4. The method of claim 1 , where the surface of the extrudate includes less bloom than can be detected by a low-powered microscope, using oblique light, after 60 days.

5. The method of claim 1 , where the surface of the extrudate includes less crystalline bloom than would otherwise an appreciable impact on the surface of the extrudate.

6. A method for preparing a thermoplastic vulcanizate, the method comprising:

forming a thermoplastic vulcanizate by dynamically vulcanizing a rubber within a blend comprising about 56 parts by weight, polypropylene, about 125 parts by weight paraffinic oil, about 42 parts by weight clay, about 3 parts by weight antioxidant, about 6.5 parts by weight peroxide curative, and about 6.6 parts by weight triallyl isocyanurate, all based on 100 parts by weight rubber, where the rubber is a copolymer of ethylene, propylene, and vinyl norbornene, the peroxide curative is 2,5-dimethyl-2,5-di(t-butylperoxy)hexane, and the antioxidant is tetrakis(methylene 3,5-ditert-buty-4-hydroxy hydrocinnamate)methane; and

forming a extrudate from the thermoplastic vulcanizate, where surface of the extrudate includes less bloom than can be detected by a low-powered microscope, using oblique light, after 60 days.

7. The method of claim 1 , where the rubber is characterized by a diene content of about 4.4 wt. %, an oil-extended Mooney viscosity ML(1+4@125° C.) of about 53, and an ethylene content of about 66 wt. %.

8. The method of claim 7 , where the triallyl isocyanurate is provided to said blend together with a carrier selected from the group consisting of silica, precipitated silica, amorphous fumed silica, fused silica, silica gel, and silicates.

9. The method of claim 8 , where the carrier has a particle size of from about 100 to about 100 nm, and where the concentration of triallyl isocyanurate on the carrier is from about 25% to about 80% by weight based on the total weight of the triallyl isocyanurate and the carrier.