Condensed phase conversion and growth of nanorods and other materials instead of from vapor
View Patent ↗Compositions, systems and methods are described for condensed phase conversion and growth of nanorods and other materials. A method includes providing a condensed phase matrix material; and activating the condensed phase matrix material to produce a plurality of nanorods by condensed phase conversion and growth from the condensed phase matrix material instead of from vapor. The compositions are very strong. The compositions and methods provide advantages because they allow (1) formation rates of nanostructures necessary for reasonable production rates, and (2) the near net shaped production of component structures.
1. A method, comprising:
depositing a condensed phase matrix material comprising a plurality of particles;
activating said condensed phase matrix material after the depositing, the condensed phase matrix material not being vaporized during the activating thereof; and
forming a plurality of nanorods by condensed phase conversion and growth from the condensed phase matrix material instead of from vapor.
2. The method of claim 1 , further comprising, prior to depositing the condensed phase matrix material, condensing a gaseous phase source of the condensed phase matrix material to form the plurality of particles.
3. The method of claim 1 , wherein said condensed phase matrix material includes at least one member selected from the group consisting of carbon, silicon, silicon carbide, germanium, and gallium arsenide and said plurality of nanorods include at least one member selected from the group consisting of carbon, silicon, silicon carbide, germanium, boron nitride and gallium arsenide.
4. The method of claim 3 , wherein said condensed phase matrix material includes amorphous carbon particles with an average diameter of from approximately 1 nm to approximately 100 nm.
5. The method of claim 1 , further comprising providing a plurality of catalyst particles, wherein activating said condensed phase matrix material includes activating said plurality of catalyst particles to produce a plurality of nanorods by condensed phase conversion and growth.
6. The method of claim 1 , wherein said condensed phase matrix material is prepared by at least one technique selected from the group consisting of laser ablation, thermal spray, electric arc, plasma arc, infrared vaporization, microwave vaporization, mechanical grinding, mechanical fracture, explosive vaporization, ion sputtering, electron beam etching.
7. The method of claim 1 , wherein said condensed phase matrix material includes a plurality of solid phase templates produced by condensed phase conversion and growth, and activating said condensed phase matrix material includes reactivating said plurality of solid phase templates to grow said plurality of nanorods by condensed phase conversion and growth from said solid phase templates.
8. The method of claim 7 , wherein said plurality of solid phase templates include nanorods.
9. The method of claim 7 , wherein said plurality of solid phase templates include single wall nanotubes.
10. The method of claim 1 , wherein said condensed phase matrix material is provided in a pattern on a substrate.
11. The method of claim 10 , further comprising providing at least one catalyst particle on said pattern, wherein activating said condensed phase matrix material includes activating said at least one catalyst particle to transform said condensed phase matrix material into at least one nanorod by condensed phase conversion and growth.
12. The method of claim 1 , wherein said condensed phase matrix material is provided in a mold space.
13. The method of claim 1 , wherein said plurality of nanorods include at least one substantially cylindrical nanostructure selected from the group consisting of nanowires, multi-wall nanotubes and single-wall nanotubes.
14. The method of claim 1 , wherein said plurality of nanorods are interrelated to define a substantially random distribution of intersection angles between the plurality of nanorods.
15. The method of claim 1 , wherein said plurality of nanorods are interwoven.
16. The method of claim 1 , wherein condensed phase conversion and growth includes solid-state conversion and growth.
17. The method of claim 1 , wherein activating takes place after depositing.
18. The method of claim 1 , further comprising placing said plurality of nanorods in contact with a condensed phase feedstock material and annealing to continue growth of the plurality of nanorods.
19. A method for producing nanorods, the method comprising:
forming a mixture of particles, the mixture comprising metal catalyst particles in contact with particles of a condensed phase matrix material;
heating the mixture of particles on a substrate to a temperature insufficient to vaporize the condensed phase matrix material; and
forming a plurality of nanorods on the substrate by condensed phase conversion and growth from the particles of the condensed phase matrix material.
20. The method of claim 19 , further comprising delivering at least one of the condensed phase matrix material and the metal catalyst particles to the substrate.
21. The method of claim 20 , wherein the delivering comprises co-depositing the condensed phase matrix material and the metal catalyst particles on the substrate.
22. The method of claim 20 , wherein the delivering comprises depositing the condensed phase matrix material on the substrate and subsequently depositing the metal catalyst particles on the substrate.
23. The method of claim 20 , wherein the delivering occurs after forming the mixture of particles.
24. The method of claim 20 , wherein the delivering occurs prior to forming the mixture of particles.
25. The method of claim 19 , further comprising, prior to forming the mixture, condensing from a vapor at least one of (a) the particles of the condensed phase matrix material and (b) the metal catalyst particles.
26. The method of claim 25 , further comprising, after the condensing, aggregating at least one of (a) the particles of the condensed phase matrix material and (b) the metal catalyst particles.
27. The method of claim 19 , wherein the heating comprises sintering the condensed phase matrix material.
28. The method of claim 19 , wherein the temperature is in excess of 1000° C.
29. The method of claim 19 , wherein the plurality of nanorods grow at a rate of about 0.2 μm/s.
30. The method of claim 19 , wherein the mixture of particles includes solid phase particles.
31. The method of claim 19 , wherein the mixture of particles includes liquid phase particles.
32. The method of claim 19 , wherein the mixture of particles comprises sub-100 nm particles.
33. The method of claim 19 , wherein the nanorods comprise a non-carbon material.
34. The method of claim 19 , wherein the nanorods comprise carbon.
35. The method of claim 19 , wherein the nanorods include at least one substantially cylindrical nanostructure selected from the group consisting of nanowires, multi-wall nanotubes and single-wall nanotubes.
36. The method of claim 19 , wherein the metal catalyst particles comprise at least one element selected from the group consisting of Fe, Ni, Co, Rh, and Pd.
37. The method of claim 33 , wherein the nanorods consist essentially of the non-carbon material.
38. The method of claim 19 , wherein the nanorods formed on the substrate are epitaxial nanorods.
39. The method of claim 19 , wherein the nanorods formed on the substrate are at least partially interwoven nanorods.
40. The method of claim 19 , wherein the temperature to which the mixture is heated is a first temperature T 1 greater than or equal to T activation at which growth of the nanorods begins, and
further comprising, after heating the mixture to the first temperature T 1 , heating the mixture to a second temperature T 2 lower than the first temperature T 1 to maintain growth of the nanorods.