Method for the determination of the CaCO

1. A method for the determination of the CaCO 3 content of a scrubbing liquid, which has been separated from a scrubbing liquid circuit of a scrubbing column, comprising the steps of:

separating a predetermined scrubbing liquid test volume from a separate, continuously available scrubbing liquid volume flow using a sampling trap, which separating further comprises the steps of:

damming up a predetermined scrubbing liquid volume inside said sampling trap by closing all stop valves in each outlet of said sampling trap; and

enclosing the predetermined scrubbing liquid volume in said sampling trap by closing a stop valve in a scrubbing liquid inlet of said sampling trap;

supplying the scrubbing liquid test volume to a measuring cell by opening a stop valve in a measuring cell outlet of said sampling trap,

dosage and supplying of a predetermined HCl volume directly to the measuring cell downstream of the sampling trap,

mixing of the supplied volumes,

awaiting the end of a predetermined reaction time,

measuring the pH value of the supplied volumes, and

determining the CaCO 3 content of the test volume based upon the change of the measured pH value.

2. The method according to claim 1 , wherein the step of determining the CaCO3 content is carried out by means of a pH probe.

3. The method according to claim 1 , in which the scrubbing liquid test volume and/or the dosed HCI volume can be modified.

4. The method according to claim 1 , further comprising regularly calibrating the measuring equipment, which is used for the measuring cell.

5. The method according to claim 4 , wherein the step of regularly calibrating the measuring equipment comprises realizing wet analytical comparison measurements.

6. The method according to claim 1 , further comprising the step of cleaning the measuring cell and the sampling trap in regular time intervals.

7. The method according to claim 1 , further comprising the steps of:

supervising the scrubbing liquid volume flow;

supervising the test volume in the measuring cell; and

supervising the dosed HCI volume;

for verifying the plausibility of the pH measurement.

8. The method according to claim 1 , further comprising the steps of:

opening a stop valve comprised in a rinse water inlet of said sampling trap;

flowing rinse water into said sampling trap through said rinse water inlet; and

opening a stop valve comprised in an outlet of said sampling trap for discharging the rinse water.

9. A method for the determination of the CaCO 3 content of a scrubbing liquid, the method comprising:

directing a liquid test volume from a scrubbing liquid volume flow into a separate measuring cell via a line of a sampling trap such that the liquid test volume in the measuring cell is fluidly separated from the scrubbing liquid volume flow, which fluidly separating the liquid test volume comprises the steps of:

damning up a predetermined scrubbing liquid volume inside said sampling trap by closing all stop valves in each outlet of said sampling trap; and

enclosing the predetermined scrubbing liquid volume in said sampling trap by closing a stop valve in a scrubbing liquid inlet of said sampling trap;

introducing and mixing a predetermined volume of HCI into the liquid test volume within the measuring cell,

awaiting the end of a predetermined reaction time, and

measuring a pH value of the liquid test volume within the measuring cell, and determining a CaCO 3 content of the liquid test volume based upon the change of the measured pH value.

10. The method according to claim 9 , further comprising:

evacuating the liquid test volume from the measuring cell following the step of measuring a pH value such that the evacuated liquid test volume remains separate from the scrubbing liquid volume flow.

11. The method according to claim 9 , in which the determination of the CaCO3 content is carried out by means of a pH probe.

12. The method according to claim 9 , in which the scrubbing liquid test volume and/or the dosed HCI volume can be modified.

13. The method according to claim 9 , further comprising calibrating equipment to be used for the step of measuring a pH value.

14. The method according to claim 13 , wherein the step of calibrating equipment comprises calibrating equipment using wet analytical comparison measurements.

15. The method according to claim 9 , further comprising:

verifying the plausibility of the pH measurement by monitoring the scrubbing liquid volume flow, the test volume in the measuring cell and the dosed HCI volume.