Organic electroluminescence device using a copolymer and a phosphorescent compound
An organic electroluminescence device including one layer or two or more layers of organic layer sandwiched between an anode and a cathode. At least one of the organic layers includes a phosphorescent compound and a polymer. The polymer has a structural unit derived from a monomer represented by formula (1) as defined herein, and a structural unit derived from a monomer having heterocycle(s) containing two or more heteroatoms.
1. An organic electroluminescence device comprising one layer or two or more layers of organic layer sandwiched between an anode and a cathode wherein:
at least one of the organic layers comprises a phosphorescent compound and a polymer;
wherein the phosphorescent compound is an iridium complex, and
the polymer consists essentially of a structural unit derived from a monomer represented by the following formula (1) and a structural unit derived from a monomer having heterocycle(s) containing two or more heteroatoms:
wherein in formula (1), R 1 -R 27 each represents independently a hydrogen atom, a halogen atom, a cyano group, an amino group, an alkyl group having 1 to 10 carbon atoms or an alkoxy group having 1 to 10 carbon atoms; within each of the groups R 1 -R 4 , R 5 -R 9 , R 10 -R 14 and R 15 -R 19 , two groups bonding to adjacent carbon atoms in a benzene ring may bond to each other forming a fused ring; X 1 represents a single bond, an oxygen atom (—O—), a sulfur atom (—S—), —SO—, —SO 2 —, —NR— (R represents a hydrogen atom, an alkyl group having 1 to 4 carbon atoms or a phenyl group), —CO— or a divalent organic group having 1 to 20 carbon atoms (the organic group may be substituted with an atom or a group selected from the group consisting of an oxygen atom (—O—), a sulfur atom (—S—), —SO—, —SO 2 —, —NR— (R represents a hydrogen atom, an alkyl group having 1 to 4 carbon atoms or a phenyl group) and —CO—); Y 1 represents a polymerizable functional group; and p represents 0 or 1; and
wherein the monomer having heterocycle(s) is selected from the group consisting of monomers represented by the following formulae (2) to (5):
wherein in formulae (2) to (5), each of R 28 -R 71 has the same definition as R 1 in the formula (1); within each of the groups R 28 -R 31 , R 32 -R 36 , R 37 -R 40 , R 42 -R 44 , R 45 -R 49 , R 50 -R 54 , R 58 -R 62 , R 63 -R 66 and R 67 -R 71 , two groups bonding to adjacent carbon atoms in a benzene ring may bond to each other forming a fused ring; X 2 -X 5 each has the same definition as X 1 in the formula (1); and Y 2 -Y 5 each has the same definition as Y 1 in the formula (1), and in the formula (5), Ar represents a phenyl group or a naphthyl group.
2. An image display device comprising the organic EL device of claim 1 .
3. An area light source comprising the organic EL device of claim 1 .