IP Library Granted Patent US 7,910,787
Granted Patent B2
US 7,910,787 · App. 11/526,824 · Granted Mar 22, 2011

Method and system for methanol production

Assignee: Gas Technologies LLC
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Quick Facts
Patent No.
US 7,910,787
App. No.
11/526,824
Granted
Mar 22, 2011
Kind
B2
Abstract

An apparatus and method of producing methanol includes reacting a heated hydrocarbon-containing gas and an oxygen-containing gas in a reactor; to provide a product stream comprising methanol; and transferring heat from the product stream to the hydrocarbon-containing gas to heat the hydrocarbon containing gas. After removing methanol and CO 2 from the product stream, unprocessed hydrocarbons are mixed with the hydrocarbon containing gas for reprocessing through the reactor. Reactor byproducts are injected into the ground to increase the output of a hydrocarbon producing well.

Claims (23)

1. A method of transferring hydrocarbon gas containing stream from an off-shore platform comprising:

a) converting a portion of methane containing gas from the hydrocarbon gas containing stream into methanol, CO 2 , H 2 O, ethanol and formaldehyde, the hydrocarbon gas containing stream moving through a pipeline;

b) separating the methanol from reaction products;

c) injecting the methanol formed in step a) into the methane containing gas stream to reduce the formation of hydrates within the pipeline; and

d) separating the CO 2 from the reaction products.

2. The method according to claim 1 further comprising injecting the CO 2 at a predetermined distance from a well into the ground to increase the output of the well.

3. The method according to claim 1 wherein converting a methane containing gas is controlling the amount of CO 2 , H 2 O, and formaldehyde produced in a partial oxidation reactor.

4. The method according to claim 1 wherein converting a methane containing gas includes partially oxidizing the methane using a plurality of reactors to increase per-pass conversion of the methane to methanol and further oxidize the formaldehyde into CO 2 , and H 2 O.

5. The method according to claim 1 wherein converting methane gas to methanol includes providing an oxygen containing gas; providing a first methane containing gas, reacting the oxygen containing gas with the methane containing gas to form a reaction product stream, and directly mixing a coolant with the reaction product stream to adjust the proportion of CO 2 and H 2 O to formaldehyde.

6. The method according to claim 5 wherein directly mixing a gas includes directly mixing a second methane containing gas stream into the reaction product stream.

7. The method according to claim 6 wherein the first and second methane containing gas streams are taken from a well.

8. A method of transporting a methane containing hydrocarbon stream from an off-shore hydrocarbon producing well comprising:

converting methane from a first portion of the methane containing hydrocarbon stream into methanol and reaction products within a first predetermined distance from the well;

separating the methanol from the reaction products; and

injecting the methanol from the first portion into a second portion of the methane containing hydrocarbon stream.

9. The method according to claim 8 further comprising separating CO 2 from the reaction products.

10. The method according to claim 9 further comprising injecting the CO 2 at a second predetermined distance from the off-shore hydrocarbon producing well.

11. The method according to claim 8 wherein the reaction products comprise H 2 O, ethanol and formaldehyde.

12. The method according to claim 11 further comprising separating H 2 O from the reaction stream and injecting at least one of CO 2 and H 2 O into the ground at a third predetermined distance from the off-shore hydrocarbon producing well.

13. The method according to claim 9 further comprising injecting the CO 2 into a well casing of the off-shore hydrocarbon producing well.

14. The method according to claim 8 wherein converting the methanol from a methane containing hydrocarbon stream includes providing an oxygen containing gas; providing a first methane containing gas, reacting the oxygen containing gas with the methane containing gas to form a reaction product stream, and directly mixing a coolant with the reaction product stream in a reactor to adjust the degree of oxidation of formaldehyde, thereby increasing the proportion of CO 2 and H 2 O to formaldehyde.

15. The method according to claim 14 wherein directly mixing a coolant includes directly mixing a second methane containing gas stream into the reaction product stream.

16. The method according to claim 15 wherein the first and second methane containing gas streams are taken from the off-shore hydrocarbon producing well.

Assignments (4)
CORRECTIVE ASSIGNMENT TO CORRECT THE U.S. PATENT NO. 7,910,878 TO U.S. PATENT NO. 7,910,787 (TYPOGRAPHICAL ERROR ON APPENDIX B) PREVIOUSLY RECORDED ON REEL 71374 FRAME 823. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Jul 11, 2025
From: GAS TECHNOLOGIES LLC
To: GASTECHNO CORP.
Reel/Frame 071908/0419 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 10, 2025
From: GAS TECHNOLOGIES LLC
To: GASTECHNO CORP.
Reel/Frame 071374/0823 →
SECURITY AGREEMENT Recorded Apr 12, 2012
From: GAS TECHNOLOGIES LLC
To: PAWLAK, NATHAN; PAWLAK, PAUL; PAWLAK, BETH
Reel/Frame 028034/0741 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 25, 2006
From: PAWLAK, NATHAN A.; BREIDENSTEIN, WALTER; CARR, ROBERT W.
To: GAS TECHNOLOGIES LLC
Reel/Frame 018346/0351 →
Continuity (5)
Continuation In Part 11446371 · Jun 2, 2006
Continuation In Part 11432692 · May 11, 2006
Continuation In Part 11351532 · Feb 10, 2006
Continuation In Part 11319093 · Dec 27, 2005
Related Publication 20070100005A1 · May 3, 2007