IP Library › Granted Patent US 7,923,414
Granted Patent B2
US 7,923,414 · App. 12/534,901 · Granted Apr 12, 2011

Rheology modifier comprising a tetrakis(hydroxyalkyl) phosphonium salt for polymer fluids

Assignee: Schlumberger Technology Corporation
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Quick Facts
Patent No.
US 7,923,414
App. No.
12/534,901
Granted
Apr 12, 2011
Kind
B2
Abstract

Embodiments of this invention relate to a composition and a method for tailoring the rheology of a fluid for use in the oil field services industry including forming a fluid comprising a tetrakis(hydroxyalkyl) phosphonium salt and a polymer, and exposing the fluid to a temperature of about 20° C. to about 200° C., wherein a viscosity is observed that is at least about 5 percent different than if no salt were present. Embodiments of this invention also relate to a composition and a method for tailoring the rheology of a fluid for use in the oil field services industry including forming a fluid comprising a tetrakis(hydroxyalkyl) phosphonium salt and diutan and/or guar and/or guar derivatives and/or a combination thereof, and exposing the fluid to a temperature of about 20° C. to about 163° C., wherein a viscosity is observed that is at least about 5 percent lower than if no salt were present. Embodiments of this invention also relate to a composition and a method for tailoring the rheology of a fluid for use in the oil field services industry including forming a fluid comprising a tetrakis(hydroxyalkyl) phosphonium salt and xanthan, and exposing the fluid to a temperature of about 20° C. to about 200° C., wherein a viscosity is observed that is at least about 5 percent higher than if no salt were present.

Claims (31)

1. A method for tailoring the rheology of a fluid for use in the oil field services industry, comprising:

forming a fluid comprising a tetrakis(hydroxyalkyl) phosphonium salt and a polymer, wherein the concentration of salt in the fluid is about 0.001 weight percent to about 10.00 weight percent; and

exposing the fluid to a temperature of about 20° C. to about 200° C.;

wherein a viscosity is observed that is at least about 5 percent different than if no salt were present.

2. The method of claim 1 , wherein the polymer is diutan and/or derivatives of diutan and/or combinations thereof and the observed viscosity is reduced.

3. The method of claim 2 , wherein the viscosity reduction is tailored by increasing the concentration of salt.

4. The method of claim 1 , wherein the polymer is guar and/or derivatives of guar and/or combinations thereof and the observed viscosity is reduced.

5. The method of claim 4 , wherein the viscosity reduction is tailored by increasing the concentration of salt.

6. The method of claim 1 , wherein the polymer is xanthan and/or derivatives of xanthan and/or combinations thereof and the observed viscosity is increased.

7. The method of claim 6 , wherein the viscosity increase is tailored by increasing the concentration of salt.

8. The method of claim 6 , wherein the fluid further comprises dipropylene glycol methyl ether or ethylene glycol monobutyl ether or a combination thereof.

9. The method of claim 1 , wherein the exposing the fluid to a temperature occurs for at least about 5 minutes.

10. The method of claim 1 , wherein the observed viscosity is about 20 cP to about 200 cP.

11. The method of claim 1 , wherein the tetrakis(hydroxyalkyl) phosphonium salt is tetrakis(hydroxymethyl) phosphonium sulfate, tetrakishydroxymethyl phosphonium chloride, or a combination thereof.

12. The method of claim 1 , wherein the polymer is diutan, guar, xantham, derivatives thereof, and/or combinations thereof.

13. The method of claim 1 , wherein the fluid further comprises a clay stabilizer.

14. A method for tailoring the rheology of a fluid for use in the oil field services industry, comprising:

forming a fluid comprising a tetrakis(hydroxyalkyl) phosphonium salt and diutan and/or guar and/or guar derivatives and/or a combination thereof, wherein the concentration of salt in the fluid is about 0.001 weight percent to about 10.00 weight percent; and

exposing the fluid to a temperature of about 20° C. to about 200° C.;

wherein a viscosity is observed that is at least about 5 percent lower than if no salt were present.

15. The method of claim 14 , wherein the viscosity reduction is tailored by increasing the concentration of salt.

16. The method of claim 14 , wherein the observed viscosity is about 20 cP to about 200 cP.

17. The method of claim 14 , wherein the tetrakis(hydroxyalkyl) phosphonium salt is tetrakis(hydroxymethyl) phosphonium sulfate, tetrakishydroxymethyl phosphonium chloride, or a combination thereof.

18. A method for tailoring the rheology of a fluid for use in the oil field services industry, comprising:

forming a fluid comprising a tetrakis(hydroxyalkyl) phosphonium salt and xanthan, wherein the concentration of salt in the fluid is about 0.001 eight percent to about 10.00 weight percent and

exposing the fluid to a temperature of about 20° C. to about 200° C.;

wherein a viscosity is observed that is at least about 5 percent higher than if no salt were present.

19. The method of claim 18 , wherein the observed viscosity is about 20 cP to about 200 cP.

20. The method of claim 18 , wherein the tetrakis(hydroxyalkyl) phosphonium salt is tetrakis(hydroxymethyl) phosphonium sulfate, tetrakishydroxymethyl phosphonium chloride, or a combination thereof.

21. The method of claim 18 , wherein the fluid further comprises dipropylene glycol methyl ether or ethylene glycol monobutyl ether or a combination thereof.

22. The method of claim 18 , wherein the fluid further comprises a clay stabilizer.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 26, 2009
From: LIN, LIJUN; LI, LEIMING; SAMUEL, MATHEW; ALI, SYED
To: SCHLUMBERGER TECHNOLOGY CORPORATION
Reel/Frame 023146/0366 →
Continuity (1)
Related Publication 20110034352A1 · Feb 10, 2011