Coated insert
The present invention relates to cutting tool insert for metal machining on which at least on the functioning parts of the surface thereof a thin, adherent, hard and wear resistant coating is applied. The coating comprises a metal oxide/oxide composite layer consisting of two components with a grain size of from about 1 to about 100 nm. The oxide layer is under a compressive stress.
1. A cutting tool insert comprising a body of cemented carbide, cermet, ceramics, cubic boron nitride or high speed steel on which at least on the functioning parts of the surface thereof a thin, adherent, hard and wear resistant coating is applied wherein said coating comprises at least one PVD layer of an metal oxide/oxide composite where the metal atoms are selected from Ti, Nb, V, Mo, Zr, Cr, Al, Hf, Ta, Y or Si and where said oxide layer has a total thickness of between from about 0.2 to about 20 μm and is composed of two components, component A and component B, with different composition and different structure, which components are a single phase oxide of one metal element or a solid solution of two or more metal oxides, wherein said component A contains tetragonal or cubic zirconia and said component B contains crystalline or amorphous alumina, and wherein the volume contents of component A and B are from about 40 to about 95% and from about 5 to about 60% respectively.
2. A cutting tool insert according of claim 1 wherein the body has as a first, inner single or multilayer of metal carbides, nitrides or carbonitrides with a thickness between from about 0.2 and to about 20 μm where the metal atoms are chosen from one or more of Ti, Nb, V, Mo, Zr, Cr, Al, Hf, Ta, Y or Si.
3. A cutting tool insert of claim 1 wherein the body has as an outer single or multilayer coating of metal carbides, nitrides or carbonitrides with a thickness between from about 0.2 and to about 5 μm where the metal atoms are chosen from one or more of Ti, Nb, V, Mo, Zr, Cr, Al, Hf, Ta, Y or Si.
4. A cutting tool insert of claim 1 wherein said component A has an average grain size of from about 1 to about 100 nm.
5. A cutting tool insert of claim 4 wherein said component A has an average grain size of from about 1 to about 70 nm.
6. A cutting tool insert of claim 5 wherein said component A has an average grain size of from about 1 to about 20 nm.
7. The cutting tool insert of claim 4 , wherein said component B surrounds said component A, and said component B has a mean linear intercept of from about 0.5 to about 200 nm.
8. A cutting tool insert of claim 1 wherein said component B has a mean linear intercept of from about 0.5 to about 200 nm.
9. A cutting tool insert of claim 8 wherein said component B has a mean linear intercept of from about 0.5 to about 50 nm.
10. A cutting tool insert of claim 9 wherein said component B has a mean linear intercept of about 0.5 nm.
11. A cutting tool insert of claim 1 wherein said component B consists essentially of crystalline alumina of the alpha (α)-and/or the gamma (γ)-phase.
12. A cutting tool insert of claim 1 wherein the oxygen:metal atomic ratio in the oxide layer is from about 85% to about 99% of the stoichiometric oxygen:metal atomic ratio.
13. A cutting tool insert of claim 1 wherein the oxygen:metal atomic ratio is from about 90 to 97% of the stoichiometric oxygen:metal atomic ratio.
14. A cutting tool insert of claim 1 wherein said body is a cemented carbide or a cermet.
15. The cutting tool insert of claim 1 , wherein the oxide layer includes stress being compressive in the range of from about 200 to about 5000 MPa.
16. The cutting tool insert of claim 1 , wherein said component A is in the form of nanosized grains or columns and said component B surrounds said component A.
17. A cutting tool insert comprising a body of cemented carbide, cermet, ceramics, cubic boron nitride or high speed steel on which at least on the functioning parts of the surface thereof a thin, adherent, hard and wear resistant coating is applied wherein said coating comprises at least one PVD layer of an metal oxide/oxide composite where the metal atoms are selected from Ti, Nb, V, Mo, Zr, Cr, Al, Hf, Ta, Y or Si and where said oxide layer has a total thickness of between from about 0.2 to about 20 μm and is composed of two components, component A and component B, with different composition and different structure, which components are a single phase oxide of one metal element or a solid solution of two or more metal oxides, wherein said component A contains tetragonal or cubic zirconia and said component B contains crystalline or amorphous alumina, wherein when component A contains tetragonal zirconia then said component B contains crystalline alumina and when component A contains cubic zirconia the said component B contains amorphous alumina, and wherein the volume contents of component A and B are from about 40 to about 95% and from about 5 to about 60% respectively.