Polyimide resin and liquid crystal alignment layer and polyimide film using the same
Disclosed is a polyimide resin, which is colorless and transparent and has superior properties, including mechanical properties and heat stability, and thus is usable in various fields, including semiconductor insulating films, TFT-LCD insulating films, transparent electrode films, passivation films, liquid crystal alignment layers, optical communication materials, protective films for solar cells, and flexible display substrates. Also, a liquid crystal alignment layer and a polyimide film using the polyimide resin are provided.
1. A polyimide resin, which is prepared from a polymer of aromatic dianhydride and aromatic diamine, the aromatic dianhydride comprising 4,4′-(4,4′-isopropylidenediphenoxy)bis(phthalic anhydride) (HBDA) and 4-(2,5-dioxotetrahydrofuran-3-yl)-1,2,3,4-tetrahydronaphthalene-1,2-dicarboxylic anhydride (TDA), and the aromatic diamine comprising one or a mixture of two or more selected from among diamine having a flexible group and diamine containing fluorine.
2. The polyimide resin according to claim 1 , wherein the diamine having a flexible group comprises one or a mixture of two or more selected from among oxydianiline (ODA), 1,3-bis(3-aminophenoxy)benzene (APB-133), 1,3-bis(4-aminophenoxy)benzene (APB-134), 1,4-bis(4-aminophenoxy)benzene (APB-144), bis(3-aminophenyl)sulfone (3-DDS), bis(4-aminophenyl)sulfone (4-DDS), 2,2′-bis[4(4-aminophenoxy)phenyl]hexafluoropropane (4-BDAF), 2,2′-bis[3(3-aminophenoxy)phenyl]hexafluoropropane (3-BDAF), and 2,2-bis[4-(4-aminophenoxy)phenyl]propane (6-HMDA).
3. The polyimide resin according to claim 1 , wherein the diamine containing fluorine comprises one or a mixture of two or more selected from among 2,2′-bis(trifluoromethyl)-4,4′-diaminobiphenyl (2,2′-TFDB), 3,3′-bis(trifluoromethyl)-4,4′-diaminobiphenyl (3,3′-TFDB), 2,2′-bis[4(4-aminophenoxy)phenyl]hexafluoropropane (4-BDAF), and 2,2′-bis[3(3-aminophenoxy)phenyl]hexafluoropropane (3-BDAF).
4. The polyimide resin according to claim 1 , wherein the aromatic dianhydride further comprises 2,2-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride (6-FDA).
5. The polyimide resin according to claim 1 , wherein the 4,4′-(4,4′-isopropylidenediphenoxy)bis(phthalic anhydride) (HBDA) is used in an amount of 1˜99 mol %, based on a total amount of the aromatic dianhydride.
6. The polyimide resin according to claim 1 , wherein the one or mixture of two or more selected from among diamine having a flexible group and diamine containing fluorine is used in an amount of 10˜90 mol %, based on a total amount of the diamine.
7. A liquid crystal alignment layer, comprising the polyimide resin of any one of claim 1 .
8. The liquid crystal alignment layer according to claim 7 , which has a pretilt angle of 0˜2°.
9. A polyimide film, comprising the polyimide resin of claim 1 .
10. The polyimide film according to claim 9 , which has average transmittance of 85% or more at 380˜780 nm and average transmittance of 88% or more at 551˜780 nm, according to measurement of transmittance using a UV spectrophotometer, based on a film thickness of 50˜100 μm.
11. The polyimide film according to claim 9 , which has transmittance of 88% or more at 550 nm, transmittance of 85% or more at 500 nm, and transmittance of 50% or more at 420 nm, according to measurement of transmittance using a UV spectrophotometer, based on a film thickness of 50˜100 μm.
12. The polyimide film according to claim 9 , which has a yellowing index of 15 or less based on a film thickness of 50˜100 μm.
13. The polyimide film according to claim 9 , which has a dielectric constant of 3.0 or less at 1 GHz based on a film thickness of 50˜100 μm.
14. The polyimide film according to claim 9 , which has an average coefficient of thermal expansion of 50 ppm or less at 50˜200° C. based on a film thickness of 50˜100 μm.
15. The polyimide film according to claim 9 , which has a modulus of 3.0 GPa or more based on a film thickness of 50˜100 μm.
16. The polyimide film according to claim 9 , which has a 50% cut-off wavelength of 400 nm or less, according to measurement of transmittance using a UV spectrophotometer, based on the film thickness of 50˜100 μm.