Method and device for generating positively and/or negatively ionized gas analytes for gas analysis
View Patent ↗A solution is supposed to be created with a method for generating positively and/or negatively ionized gas analytes for gas analysis in an ion mobility spectrometer or in a mass spectrometer, with which method the gas analyte can be ionized without the restrictions of previous ionization methods for gas analysis in an ion mobility spectrometer or in a mass spectrometer, forming positive and/or negative ions. This is achieved in that the positive and/or negative gas ions are generated by means of a plasma, which is brought about by means of a dielectrically inhibited discharge, whereby the dielectrically inhibited discharge is produced in that a noble gas is passed in through a capillary made of a dielectric material, whereby an alternating voltage is applied by means of two electrically insulated electrodes disposed on the capillary adjacent to the exit region of the capillary, and the gas analyte is passed to the exit region outside of the capillary.
1. Method for generating at least one of positively ionized gas analytes and negatively ionized gas analytes for gas analysis in an ion mobility spectrometer or in a mass spectrometer,
wherein
the at least one of positive gas ions and negative gas ions are generated by means of a plasma, which is brought about by means of a dielectrically inhibited discharge, whereby the dielectrically inhibited discharge is produced in that a noble gas is passed in through a capillary made of a dielectric material, whereby an alternating voltage is applied by means of two electrically insulated electrodes disposed on the capillary adjacent to the exit region of the capillary, and the gas analyte is passed to the exit region outside of the capillary.
2. Method according to claim 1 , wherein
an alternating voltage in the range of 500 V to 5000 V is used.
3. Method according to claim 1 , wherein
the dielectrically inhibited discharge is operated at ambient pressure.
4. Device for generating at least one of positively ionized gas analytes and negatively ionized gas analytes for gas analysis in an ion mobility spectrometer or in a mass spectrometer, for carrying out the method according to claim 1 , wherein
a capillary ( 2 ) made of a dielectric material, for passing in a noble gas, whereby two electrically insulated electrodes ( 3 , 4 ) to which alternating voltage is applied are disposed on the capillary ( 2 ), adjacent to the exit region of the capillary ( 2 ).
5. Device according to claim 4 , wherein
the capillary ( 2 ) consists of glass.
6. Device according to claim 5 , wherein
the capillary ( 2 ) has a diameter between 50 and 500 μm.
7. Device according to claim 4 , wherein
the electrodes ( 3 , 4 ), which are spaced apart from one another in the longitudinal direction of the capillary, are disposed at a maximal distance of 1 cm.
8. Use of a device according to claim 4 in an ion mobility spectrometer, whereby the exit region of the capillary ( 2 ) extends into the ionization chamber of the ion mobility spectrometer.
9. Use of a device according to claim 4 in a mass spectrometer.