IP Library Granted Patent US 8,030,830
Granted Patent B2
US 8,030,830 · App. 12/272,208 · Granted Oct 4, 2011

Iridium alloy for spark plug electrodes

Assignee: FRAM Group IP LLC
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Quick Facts
Patent No.
US 8,030,830
App. No.
12/272,208
Granted
Oct 4, 2011
Kind
B2
Abstract

A spark plug comprises a shell having a substantially cylindrical threaded portion for threadable engagement in a cylinder head of an internal combustion engine, an insulator disposed coaxially in the shell, a center electrode disposed coaxially in the insulator, a side ground electrode having a first end coupled to the shell and a second end facing an end of the center electrode to define a spark discharge gap therebetween, and an electrode tip portion secured to either the side ground electrode or the center electrode proximate the spark discharge gap. The tip portion is formed from an alloy comprising from about 60 to about 70 percent by weight iridium, from about 30 to about 35 percent by weight rhodium, from 0 to about 10 percent by weight nickel, from about 3500 to about 4500 parts per million tantalum, and from about 100 to about 200 parts per million zirconium.

Claims (38)

1. A spark plug, comprising:

a shell having a substantially cylindrical threaded portion for threadable engagement in a cylinder head of an internal combustion engine;

an insulator disposed coaxially in the shell;

a center electrode disposed coaxially in the insulator;

a side ground electrode having a first end coupled to the shell and a second end facing an end of the center electrode to define a spark discharge gap therebetween; and

an electrode tip portion secured to either the side ground electrode or the center electrode proximate the spark discharge gap, the tip portion being formed from an alloy consisting essentially of from about 60 to about 70 percent by weight iridium, from about 30 to about 35 percent by weight rhodium, from 0 to about 10 percent by weight nickel, from about 3500 to about 4500 parts per million tantalum, and from about 100 to about 200 parts per million zirconium.

2. The spark plug of claim 1 , wherein the alloy comprises about 65 percent by weight iridium, about 35 percent by weight rhodium.

3. The spark plug of claim 1 , wherein the alloy consists essentially of 65 percent by weight iridium, 35 percent by weight rhodium, 4000 parts per million tantalum, and 200 parts per million zirconium.

4. The spark plug of claim 1 , wherein the alloy comprises about 60 percent by weight iridium, about 30 percent by weight rhodium, and about 10 percent by weight nickel.

5. A spark plug, comprising:

a shell having a substantially cylindrical threaded portion for threadable engagement in a cylinder head of an internal combustion engine;

an insulator disposed coaxially in the shell;

a center electrode disposed coaxially in the insulator;

a side ground electrode having a first end coupled to the shell and a second end facing an end of the center electrode to define a spark discharge gap therebetween; and

an electrode tip portion secured to either the side ground electrode or the center electrode proximate the spark discharge gap, the tip portion being formed from an alloy consists essentially of from about 60 to about 70 percent by weight iridium, from about 30 to about 35 percent by weight rhodium, from 0 to about 10 percent by weight nickel, and from about 50 to about 100 parts per million cerium.

6. The spark plug of claim 5 , wherein the alloy comprises about 70 percent by weight iridium, and about 30 percent by weight rhodium.

7. The spark plug of claim 5 , wherein the alloy comprises about 60 percent by weight iridium, about 30 percent by weight rhodium, and about 10 percent by weight nickel.

8. The spark plug of claim 5 , wherein the alloy consists essentially of 70 percent by weight iridium, 30 percent by weight rhodium, and 100 parts per million cerium.

9. The spark plug of claim 5 , wherein the alloy consists essentially of 60 percent by weight iridium, 30 percent by weight rhodium, 10 percent by weight nickel, and 100 parts per million cerium.

10. The spark plug of claim 1 , wherein the tip portion is secured to the side ground electrode.

11. The spark plug of claim 1 , wherein the tip portion is secured to the center electrode.

12. The spark plug of claim 1 , wherein the tip portion is secured to the side ground electrode and a second electrode tip portion is secured to the center electrode.

13. The spark plug of claim 1 , wherein the tip portion is secured to the side ground electrode or the center electrode by resistance welding or laser welding.

14. The spark plug of claim 12 , wherein the second tip portion is secured to the center electrode by resistance welding or laser welding.

15. The spark plug of claim 1 , wherein the end of the center electrode protrudes from the insulator.

16. A wear-resistant electrode tip portion for securing to a spark plug electrode, the tip portion consisting essentially of:

from about 60 to about 70 percent by weight iridium;

from about 30 to about 35 percent by weight rhodium;

from 0 to about 10 percent by weight nickel;

from about 3500 to about 4500 parts per million tantalum; and

from about 100 to about 200 parts per million zirconium.

17. A wear-resistant electrode tip portion for securing to a spark plug electrode, the tip portion consisting essentially of:

from about 60 to about 70 percent by weight iridium;

from about 30 to about 35 percent by weight rhodium;

from 0 to about 10 percent by weight nickel; and

from about 50 to about 100 parts per million cerium.

18. The tip portion of claim 16 , wherein the tip portion is rivet-shaped.

19. The tip portion of claim 16 , wherein the tip portion is substantially spherical.

Assignments (22)
RELEASE OF SECURITY INTEREST Recorded Jul 2, 2026
From: WILMINGTON SAVINGS FUND SOCIETY, FSB
To: JEFFERIES FINANCE LLC
Reel/Frame 075891/0705 →
SECURITY INTEREST Recorded Jun 12, 2026
From: PGI NORTHSTAR LLC
To: FIRST HORIZON BANK
Reel/Frame 075410/0391 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 4, 2026
From: FIRST BRANDS GROUP HOLDINGS, LLC; FIRST BRANDS GROUP INTERMEDIATE, LLC; FIRST BRANDS GROUP, LLC; CHAMPION LABORATORIES, INC.; FRAM GROUP IP LLC; PYLON MANUFACTURING CORP.; HEATHERTON HOLDINGS, LLC; TRICO PRODUCTS CORPORATION; STRONGARM, LLC
To: PGI NORTHSTAR LLC
Reel/Frame 075584/0001 →
LIEN Recorded Dec 8, 2025
From: JEFFERIES FINANCE LLC
To: WILMINGTON SAVINGS FUND SOCIETY, FSB
Reel/Frame 073892/0154 →
FIRST LIEN INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Jun 18, 2025
From: AIRTEX INDUSTRIES, LLC; AIRTEX PRODUCTS, LP; APC INTERMEDIATE HOLDINGS, LLC; APC PARENT, LLC; ASC INDUSTRIES, INC.; AUTOLITE OPERATIONS LLC; AVM EXPORT, INC.; BPI ACQUISITION COMPANY, LLC; BPI EC, LLC; BPI HOLDINGS INTERNATIONAL, LLC; BRAKE PARTS INC CHINA LLC; BRAKE PARTS INC INDIA LLC; BRAKE PARTS INC LLC; CARDONE INDUSTRIES, INC.; CARRAND COMPANIES, INC.; CARTER CARBURETOR HOLDINGS, LLC; CARTER CARBURETOR, LLC; CARTER FUEL EXPORT, INC.; CARTER FUEL SYSTEMS, LLC; CHAMPION LABORATORIES, INC.; CWD HOLDING, LLC; CWD INTERMEDIATE HOLDINGS I, LLC; CWD INTERMEDIATE HOLDINGS II, LLC; CWD, LLC; DALTON CORPORATION; DALTON CORPORATION, KENDALLVILLE; MANUFACTURING FACILITY DALTON CORPORATION, ASHLAND; MANUFACTURING FACILITY DALTON CORPORATION, STRYKER MACHINING FACILITY CO.; DALTON CORPORATION, WARSAW MANUFACTURING FACILITY; EAGLE CASTING, LLC; EAGLE MACHINING, LLC; FIRST BRANDS GROUP INTERMEDIATE, LLC; FIRST BRANDS GROUP, LLC; FRAM GROUP IP LLC; FRAM GROUP OPERATIONS LLC; FRAMAUTO HOLDINGS, LLC; FUEL FILTER TECHNOLOGIES, INC.; GLOBAL REMAN VENTURES, LLC; HEATHERTON HOLDINGS, LLC; HOPKINS ACQUISITION, INC.; HOPKINS MANUFACTURING CORPORATION; HORIZON EURO FINANCE LLC; HORIZON GLOBAL AMERICAS INC.; HORIZON GLOBAL COMPANY LLC; HORIZON GLOBAL CORPORATION; HORIZON INTERNATIONAL HOLDINGS LLC; IBI INTERNATIONAL HOLDING COMPANY, INC.; INTERNATIONAL BRAKE INDUSTRIES, INC.; JASPER ACQUISITION CORP.; JASPER RUBBER PRODUCTS, INC.; KTRI HOLDINGS, INC.; KTRI OFFSHORE HOLDINGS, LLC; LONGMAN ENTERPRISES, INC.; PHNX ACQUISITION CORP.; PREMIER MARKETING GROUP, LLC; PYLON MANUFACTURING CORP.; PYLON SOUTH BEND, INC.; QUALIS AUTOMOTIVE, L.L.C.; QUALIS ENTERPRISES, LLC; QUALITOR ACQUISITION INC.; QUALITOR AUTOMOTIVE, LLC; QUALITOR SUBSIDIARY H, INC.; QUALITOR SUBSIDIARY S, INC.; QUALITOR, INC.; REMAN MANAGEMENT INTERNATIONAL LLC; SDC TX, LLC; SMART CHOICE, LLC; SPECIALTY PUMPS GROUP, INC.; STRONGARM, LLC; TAE BRAKES, LLC; TAE CHINA HOLDINGS, INC.; TMD INTERNATIONAL HOLDINGS LLC; TMD MEXICO LLC; TOLEDO MOLDING & DIE, LLC; TRANSPORTATION AFTERMARKET ENTERPRISE, LLC; TRICO HOLDING CORPORATION; TRICO PRODUCTS CORPORATION; TRICO TECHNOLOGIES CORPORATION; TRIDONEX USA LLC; UCI ACQUISITION HOLDINGS (NO. 4) LLC; UCI INTERNATIONAL HOLDINGS PARENT, INC.; UCI INTERNATIONAL HOLDINGS, INC.; UCI INTERNATIONAL, LLC; UCI PENNSYLVANIA, INC.; UCI-AIRTEX HOLDINGS, INC.; UNITED COMPONENTS, LLC; UNIVERSAL AUTO FILTER LLC; VIPER ACQUISITION I, INC.; VIPER ACQUISITION, INC.; WALBRO LLC; WALBRO MIDCO LLC; WEM US CO.
To: GLAS USA LLC
Reel/Frame 071674/0688 →
CORRECTIVE ASSIGNMENT TO CORRECT THE THE PATENT APPLICATION NUMBERS PREVIOUSLY RECORDED AT REEL: 053377 FRAME: 0596. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Dec 19, 2022
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH
To: JEFFERIES FINANCE LLC
Reel/Frame 062584/0429 →
ASSIGNMENT OF SECURITY INTEREST Recorded Jul 31, 2020
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH
To: JEFFERIES FINANCE LLC
Reel/Frame 053377/0596 →
RELEASE OF INTELLECTUAL PROPERTY SECURITY INTEREST Recorded May 25, 2020
From: ACQUIOM AGENCY SERVICES LLC
To: ASC INDUSTRIES, INC.; CARTER FUEL SYSTEMS, LLC; FRAM GROUP IP LLC; STRONGARM, LLC; TRICO PRODUCTS CORPORATION; TRICO GROUP, LLC; TRICO GROUP HOLDINGS, LLC
Reel/Frame 053313/0812 →
SECURITY INTEREST Recorded Apr 23, 2020
From: FRAM GROUP IP LLC
To: ACQUIOM AGENCY SERVICES LLC
Reel/Frame 052481/0586 →
ABL INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Mar 1, 2019
From: FRAM GROUP IP LLC
To: BANK OF AMERICA, N.A., AS COLLATERAL AGENT
Reel/Frame 048479/0639 →
SECOND LIEN INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Feb 27, 2019
From: ASC INDUSTRIES, INC.; CARTER FUEL SYSTEMS, LLC; FRAM GROUP IP LLC; HEATHERTON HOLDINGS, LLC; STRONGARM, LLC; TRICO PRODUCTS CORPORATION
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
Reel/Frame 048887/0495 →
RELEASE OF ABL PATENT SECURITY INTEREST Recorded Feb 27, 2019
From: BMO HARRIS BANK N.A., AS COLLATERAL AGENT
To: FRAM GROUP IP LLC
Reel/Frame 048455/0808 →
RELEASE OF TERM LOAN PATENT SECURITY INTEREST Recorded Feb 27, 2019
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
To: FRAM GROUP IP LLC
Reel/Frame 048455/0869 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 16, 2017
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS RESIGNING COLLATERAL AGENT
To: BMO HARRIS BANK, N.A., AS SUCCESSOR COLLATERAL AGENT
Reel/Frame 041739/0040 →
SECURITY INTEREST Recorded Dec 27, 2016
From: FRAM GROUP IP LLC
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
Reel/Frame 041190/0001 →
SECURITY INTEREST Recorded Dec 27, 2016
From: FRAM GROUP IP LLC
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
Reel/Frame 041190/0278 →
RELEASE OF SECURITY INTEREST Recorded Dec 27, 2016
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
To: FRAM GROUP IP LLC
Reel/Frame 041189/0938 →
RELEASE OF SECURITY INTEREST Recorded Dec 27, 2016
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS COLLATERAL AGENT
To: FRAM GROUP IP LLC
Reel/Frame 041189/0782 →
SECURITY AGREEMENT Recorded Aug 12, 2011
From: FRAM GROUP IP LLC; PRESTONE PRODUCTS CORPORATION
To: CREDIT SUISSE AG, AS SECOND LIEN COLLATERAL AGENT
Reel/Frame 026740/0089 →
SECURITY AGREEMENT Recorded Aug 11, 2011
From: FRAM GROUP IP LLC; PRESTONE PRODUCTS CORPORATION
To: CREDIT SUISSE AG, AS FIRST LIEN COLLATERAL AGENT
Reel/Frame 026732/0670 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 29, 2011
From: HONEYWELL INTERNATIONAL INC.
To: FRAM GROUP IP LLC
Reel/Frame 026671/0907 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 17, 2008
From: PASSMAN, ERIC P.; BOEHLER, JEFFREY T.; LEONE, EDGAR A.
To: HONEYWELL INTERNATIONAL INC.
Reel/Frame 021844/0532 →
Continuity (2)
Provisional Application 60988262 · Nov 15, 2007
Related Publication 20090127996A1 · May 21, 2009