Method for manufacturing toner and toner

1. A method for manufacturing a toner, comprising:

dissolving or dispersing toner constituents comprising a resin, a colorant, a release agent, and a graft polymer comprising a polyolefin resin unit and a vinyl resin unit in a solvent, to prepare a toner constituent liquid;

supplying the toner constituent liquid to a retention part configured to retain the toner constituent liquid;

discharging the toner constituent liquid from the retention part to a granulation space through plural holes arranged on the retention part, while exciting the toner constituent liquid by a vibration means in contact with a part of the retention part, so that the discharged columnar toner constituent liquid is constricted to form liquid droplets; and

converting the liquid droplets into solid toner particles.

2. The method for manufacturing a toner according to claim 1 , wherein the solvent is an organic solvent, and the liquid droplets are converted into the solid toner particles by removing the organic solvent from the liquid droplets.

3. The method for manufacturing a toner according to claim 1 , wherein the polyolefin resin has a softening point of from 70 to 150° C.

4. The method for manufacturing a toner according to claim 1 , wherein the vinyl resin has an SP value of from 10.0 to 11.5 (cal/cm 3 ) 1/2 .

5. The method for manufacturing a toner according to claim 1 , wherein the toner constituent liquid comprises the graft polymer in an amount of from 10 to 150 parts by weight based on 100 parts by weight of the release agent.

6. The method for manufacturing a toner according to claim 1 , wherein the vinyl resin comprises at least one member selected from the group consisting of a styrene unit, an alkyl acrylate unit, an alkyl methacrylate unit, an acrylonitrile unit, and a methacrylonitrile unit.

7. The method for manufacturing a toner according to claim 1 , further comprising:

heating a mixture liquid comprising the release agent, the solvent, and the graft polymer so that the release agent is dissolved;

cooling the mixture liquid so that the release agent are precipitated out in a form of particles; and

further pulverizing the particles of the release agent.

8. The method for manufacturing a toner according to claim 1 , wherein each of the holes has an opening diameter of from 1 to 40 μm.

9. A method for manufacturing a toner, comprising:

dissolving or dispersing toner constituents comprising a resin, a colorant, a release agent, and a graft polymer comprising a polyolefin resin unit and a vinyl resin unit in a solvent, to prepare a toner constituent liquid;

supplying the toner constituent liquid to a retention part configured to retain the toner constituent liquid;

periodically discharging the toner constituent liquid from the retention part through plural holes arranged on a thin film provided on the retention part, while vibrating the thin film by a mechanical vibration means, so that liquid droplets are formed; and

converting the liquid droplets into solid toner particles,

wherein the mechanical vibration means comprises a circular vibration generating means provided surrounding the holes arranged on the thin film.

10. The method for manufacturing a toner according to claim 9 , wherein the mechanical vibration means vibrates at a frequency of not less than 20 kHz and less than 2.0 MHz.

11. The method for manufacturing a toner according to claim 9 , wherein the solvent is an organic solvent, and the liquid droplets are converted into the solid toner particles by removing the organic solvent from the liquid droplets.

12. The method for manufacturing a toner according to claim 9 , wherein the polyolefin resin has a softening point of from 70 to 150° C.

13. The method for manufacturing a toner according to claim 9 , wherein the vinyl resin has an SP value of from 10.0 to 11.5 (cal/cm 3 ) 1/2 .

14. The method for manufacturing a toner according to claim 9 , wherein the toner constituent liquid comprises the graft polymer in an amount of from 10 to 150 parts by weight based on 100 parts by weight of the release agent.

15. The method for manufacturing a toner according to claim 9 , wherein the vinyl resin comprises at least one member selected from the group consisting of a styrene unit, an alkyl acrylate unit, an alkyl methacrylate unit, an acrylonitrile unit, and a methacrylonitrile unit.

16. The method for manufacturing a toner according to claim 9 , further comprising:

heating a mixture liquid comprising the release agent, the solvent, and the graft polymer so that the release agent is dissolved;

cooling the mixture liquid so that the release agent are precipitated out in a form of particles; and

further pulverizing the particles of the release agent.

17. The method for manufacturing a toner according to claim 9 , wherein each of the holes has an opening diameter of from 1 to 40 μm.

18. A method for manufacturing a toner, comprising:

dissolving or dispersing toner constituents comprising a resin, a colorant, a release agent, and a graft polymer comprising a polyolefin resin unit and a vinyl resin unit in a solvent, to prepare a toner constituent liquid;

supplying the toner constituent liquid to a retention part configured to retain the toner constituent liquid;

periodically discharging the toner constituent liquid from the retention part through plural holes arranged on a thin film provided on the retention part, while vibrating the thin film by a mechanical vibration means, so that liquid droplets are formed; and

converting the liquid droplets into solid toner particles,

wherein the mechanical vibration means comprises a vibration means comprising a vibrating surface provided parallel to the thin film and vibrates in a vertical direction.

19. The method for manufacturing a toner according to claim 18 , wherein the mechanical vibration means vibrates at a frequency of not less than 20 kHz and less than 2.0 MHz.

20. The method for manufacturing a toner according to claim 18 , wherein the mechanical vibration means is a horn vibrator.

21. The method for manufacturing a toner according to claim 18 , wherein the solvent is an organic solvent, and the liquid droplets are converted into the solid toner particles by removing the organic solvent from the liquid droplets.

22. The method for manufacturing a toner according to claim 18 , wherein the polyolefin resin has a softening point of from 70 to 150° C.

23. The method for manufacturing a toner according to claim 18 , wherein the vinyl resin has an SP value of from 10.0 to 11.5 (cal/cm 3 ) 1/2 .

24. The method for manufacturing a toner according to claim 18 , wherein the toner constituent liquid comprises the graft polymer in an amount of from 10 to 150 parts by weight based on 100 parts by weight of the release agent.

25. The method for manufacturing a toner according to claim 18 , wherein the vinyl resin comprises at least one member selected from the group consisting of a styrene unit, an alkyl acrylate unit, an alkyl methacrylate unit, an acrylonitrile unit, and a methacrylonitrile unit.

26. The method for manufacturing a toner according to claim 18 , further comprising:

heating a mixture liquid comprising the release agent, the solvent, and the graft polymer so that the release agent is dissolved;

cooling the mixture liquid so that the release agent are precipitated out in a form of particles; and

further pulverizing the particles of the release agent.

27. The method for manufacturing a toner according to claim 18 , wherein each of the holes has an opening diameter of from 1 to 40 μm.