IP Library Granted Patent US 8,058,159
Granted Patent B2
US 8,058,159 · App. 12/198,955 · Granted Nov 15, 2011

Method of making low work function component

Assignee: General Electric Company
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Quick Facts
Patent No.
US 8,058,159
App. No.
12/198,955
Granted
Nov 15, 2011
Kind
B2
Abstract

A method for fabricating a component is disclosed. The method includes: providing a member having an effective work function of an initial value, disposing a sacrificial layer on a surface of the member, disposing a first agent within the member to obtain a predetermined concentration of the agent at said surface of the member, annealing the member, and removing the sacrificial layer to expose said surface of the member, wherein said surface has a post-process effective work function that is different from the initial value.

Claims (33)

1. A method comprising:

providing a member having an effective work function of an initial value;

disposing a sacrificial layer on a surface of the member;

disposing a first agent through the sacrificial layer and within the member to obtain a predetermined concentration of the agent at said surface of the member, wherein the first agent is disposed using an ion implantation technique;

subsequent to said disposing a first agent through the sacrificial layer, annealing the member; and

subsequent to said annealing the member, removing the sacrificial layer to expose said surface of the member, wherein said surface has a post-process effective work function that is different from the initial value.

2. The method of claim 1 , wherein said disposing a sacrificial layer includes disposing a sacrificial layer comprising a material selected from the group consisting of oxides, nitrides, carbides and polymers.

3. The method of claim 1 , wherein the sacrificial layer comprises a material selected from the group consisting of silicon dioxide, silicon carbide, silicon nitride, polysilicon, and photoresists.

4. The method of claim 1 , wherein said disposing a sacrificial layer includes disposing a sacrificial layer that has a thickness within the range from about 10 nm to about 500 nm.

5. The method of claim 1 , wherein said disposing a sacrificial layer includes disposing a sacrificial layer that has a thickness within the range from about 500 nm to about 1000 nm.

6. The method of claim 1 , wherein said disposing a sacrificial layer includes disposing a sacrificial layer that has a thickness within the range from about 1000 nm to about 5000 nm.

7. The method of claim 1 , wherein the first agent is disposed within the member so that a concentration of the first agent at said surface is about 90%.

8. The component formed by the method of claim 1 , wherein the component is a Solid State Refrigerator, a MEMS switch, a solid state power generation device, or an electron emission device.

9. The method of claim 1 , wherein a post-process effective work function is less than about 2 eV.

10. The method of claim 1 , wherein a post-process effective work function is less than the initial value.

11. The method of claim 1 , wherein said providing a member includes providing a member comprising a semiconductor, a metal, an insulator, or combinations thereof.

12. The method of claim 11 , wherein said providing a member includes providing a member comprising a semiconductor comprising a material selected from the group consisting of silicon, germanium, gallium nitride, silicon carbide, gallium arsenide, and indium nitride.

13. The method of claim 11 , wherein said providing a member includes providing a member comprising a metal comprising a material selected from the group consisting of aluminum, copper, silver, and gold.

14. The method of claim 11 , wherein said providing a member includes providing a member comprising an insulator comprising a material selected from the group consisting of glass, quartz, and sapphire.

15. The method of claim 1 , further comprising forming of dipoles within the member.

16. The method of claim 15 , wherein the said forming of dipoles is achieved via an oxygen treatment of the member, wherein the oxygen treatment results in a diffusion of oxygen into the member.

17. The method of claim 1 , wherein said providing a member includes providing an electrode.

18. The method of claim 1 , wherein said disposing a first agent within the member includes disposing a first agent comprising a material selected from the group consisting of carbon, tungsten, tungsten carbide, cesium, sodium, potassium, strontium, and rubidium.

19. The method of claim 1 , further comprising disposing a second agent at said surface.

20. The method of claim 19 , wherein the second agent is disposed via diffusion.

21. The method of claim 19 , wherein said disposing a second agent at said surface include disposing a second agent so as to combine the second agent with the first agent.

22. The method of claim 19 , wherein the annealing results in a combination of the first agent and the second agent to form another agent.

23. A method comprising:

providing a member having an effective work function of an initial value;

disposing a sacrificial layer on a surface of the member;

disposing a first agent through the sacrificial layer and within the member to obtain a predetermined concentration of the agent at said surface of the member, wherein the first agent is disposed using an ion implantation technique;

annealing the member; and

removing the sacrificial layer to expose said surface of the member, wherein said surface has a post-process effective work function that is different from the initial value and less than about 2 eV.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 13, 2016
From: GENERAL ELECTRIC COMPANY
To: HAIER US APPLIANCE SOLUTIONS, INC.
Reel/Frame 038966/0650 →
CONFIRMATORY LICENSE Recorded Oct 20, 2008
From: GE GLOBAL RESEARCH
To: ENERGY, UNITED STATES DEPARTMENT OF
Reel/Frame 021702/0567 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 27, 2008
From: ROBINSON, VANCE; WEAVER, STANTON EARL; MICHAEL, JOSEPH DARRYL
To: GENERAL ELECTRIC COMPANY
Reel/Frame 021446/0721 →
Continuity (1)
Related Publication 20100055885A1 · Mar 4, 2010