Thermoplastic vulcanizates having improved adhesion to polar substrates
Thermoplastic vulcanizate compositions having good adhesion to unheated polar substrates include an amount of functionalized polyolefin that comprises greater than 80% of the total polyolefin of the TPV. The functional group may be an anhydride. Exemplary TPVs may further include polyamide, and an elastomer, which may include one or more of conjugated diene rubber, unsaturated styrenic triblock copolymer rubber, hydrogenated styrenic triblock copolymer rubber, ethylene/alpha-olefin rubber, and ethylene/alpha-olefin/non-conjugated diene rubber. The TPVs may have hardness values of less than 85 Shore A and peel forces with respect to unheated polar substrates of greater than 15 pli. Articles comprising polar substrates and TPVs are also taught.
1. An article of manufacture comprising:
a substrate comprising a polar material, wherein the substrate comprises the surface of a tool handle or an automotive body panel; and
a thermoplastic elastomer at least partially disposed directly on the substrate, the elastomer comprising:
a rubber selected from the group consisting of conjugated diene rubber, unsaturated styrenic triblock copolymer rubber, hydrogenated styrenic triblock copolymer rubber and blends thereof; and
a plastic comprising:
one or more polyolefins, wherein the total polyolefin content of the plastic comprises greater than 80% by weight of an anhydride functionalized polyolefin and an unmodified polyolefin present up to 20 wt%; wherein the functionalized polyolefin is selected from the group consisting of polypropylene, polyethylene, poly(1-butene), poly(4-methyl-1-pentene) and blends thereof, and
a polyamide.
2. The article of claim 1 wherein the plastic comprises greater than 90% by weight of the functionalized polyolefin; and wherein the functional group in the functionalized polyolefin is maleic anhydride.
3. The article of claim 2 , wherein the plastic comprises greater than 95% by weight of the functionalized polyolefin.
4. The article of claim 1 , wherein the plastic comprises no more than 20% by weight of the polyamide.
5. The article of claim 4 , wherein the polyamide has a number average molecular weight (Mn) of about 25,000 to about 80,000.
6. The article of claim 4 , wherein the polyamide has a percent crystalline structure of less than 30%.
7. The article of claim 1 wherein the functionalized polyolefin has a melt flow rate of between 375 g/10min to 475 g/ 10 min (230° C., 2.16 kg).
8. The article of claim 1 , wherein the elastomer has a peel adhesion to the substrate at room temperature in pounds per linear inch greater than 5.
9. The article of claim 8 wherein the peel adhesion is greater than 15.
10. The article of claim 1 , wherein the rubber is styrene/ethylene-butene/styrene rubber.
11. The article of claim 10 , wherein the plastic further comprises a polyamide; and an amount of polyamide plasticizer.
12. The article of claim 11 , wherein the amount of polyamide plasticizer is from 5% to 25% by weight with respect to the total polyamide.
13. An article of manufacture comprising:
a substrate comprising a polar material; and
a thermoplastic vulcanizate at least partially disposed directly on the substrate, the thermoplastic vulcanizate comprising:
a dispersed rubber phase selected from the group consisting of ethylene/alpha-olefin rubber, ethylene/alpha-olefin/non-conjugated diene rubber and blends thereof; and
a plastic phase comprising one or more polyolefins, wherein the total polyolefin content of the plastic phase comprises greater than 80% by weight of an anhydride functionalized polyolefin and an unmodified polyolefin present up to 20 wt%; wherein the functionalized polyolefin is selected from the group consisting of polypropylene, polyethylene, poly(1-butene), poly(4-methyl-1-pentene) and blends thereof, and wherein the plastic phase further comprises a polyamide, wherein the polyamide has a percent crystalline structure of less than 30%;
wherein the polar material comprises polyamide.
14. The article of claim 13 , wherein:
the thermoplastic vulcanizate comprises:
from 20% to 80% by weight of the rubber, based on the total weight of the thermoplastic vulcanizate;
from 80% to 20% by weight of the plastic phase, based on the total weight of the thermoplastic vulcanizate.
15. The article of claim 14 , wherein the plastic phase consists essentially of the functionalized polyolefin and the polyamide.
16. The article of claim 15 , wherein the functional group in the functionalized polyolefin is maleic anhydride.
17. The article of claim 16 , wherein the rubber phase comprises EPDM rubber; and wherein the functionalized polyolefin is maleated polypropylene.
18. The article of claim 17 , wherein the thermoplastic vulcanizate has a Shore A of less than 55.
19. The article of claim 13 , wherein the rubber phase comprises maleated EP rubber.
20. The article of claim 13 further comprising less than 150 phr of processing oil selected from the group consisting of polyisobutylene oil, paraffinic oil, naphthenic oil, and blends thereof.
21. The article of claim 18 , wherein the thermoplastic vulcanizate has a peel adhesion to the substrate at room temperature in pounds per linear inch greater than 5.
22. The article of claim 1 , wherein the substrate is not pretreated, and an adhesive is absent.
23. The article of claim 13 , wherein the substrate is not pretreated, and an adhesive is absent.
24. The article of claim 1 , wherein the polar material comprises polyamide.