Manufacturing nanocomposites
Techniques for preparing PNCs are provided. In one embodiment, a polymer extruding device may include a barrel configured to accommodate a composite material, a shaft rotatably disposed in the barrel, and a motor coupled to the shaft and configured to rotate the shaft, thereby moving the composite material. The polymer extruding device may further include a die including one or more injectors configured to inject nano particles into the die to cause shear stress to be exerted to the composite material, thereby forming a layer of the nano particles on a surface of the composite material.
1. An apparatus comprising:
a barrel configured to accommodate an extrudable raw material;
a shaft rotatably disposed in the barrel;
a motor coupled to the shaft and configured to rotate the shaft to force the raw material through the barrel;
a heater configured to melt at least a portion of the raw material passing through the barrel;
a die coupled to the barrel and including one or more first injectors configured to inject nano-particles into the die, thereby forming at least one layer of the nano-particles over the molten raw material; and
a supply of nanoparticles operably coupled to the one or more first injectors.
2. The apparatus of claim 1 , further comprising a hopper disposed at and in communication with one end of the barrel, and configured to feed the composite material into the barrel.
3. The apparatus of claim 1 , further comprising a base over which the barrel is disposed.
4. The apparatus of claim 1 , wherein the one or more first injectors are configured to be disposed in a proximal zone of the die.
5. The apparatus of claim 4 , wherein the one or more first injectors are further configured to be disposed according to at least one of factors including a viscosity of the composite material, a linear flow rate of the composite material, a volumetric flow rate of the composite material, a temperature profile in the die, a pressure distribution in the die, an amount of nano particles to be coated on the composite material, and a fluid dynamic and kinetic properties of the nano particles.
6. The apparatus of claim 1 , wherein the die includes a second injector configured to inject an additional substance between an inner wall of the die and the nano particles in the die.
7. The apparatus of claim 6 , wherein the additional substance includes a coupling substance or a die-releasing agent.
8. The apparatus of claim 1 , wherein the heater is configured to heat the barrel to a predetermined temperature above 200° C.
9. The apparatus of claim 8 , wherein the heater is configured to gradually increase the temperature of the barrel from a proximal zone of the barrel to a distal zone of the barrel.
10. The apparatus of claim 1 , wherein the motor is configured to rotate the shaft at a rotation rate greater than 100 rpm.
11. The apparatus of claim 1 , wherein the one or more first injectors are configured to inject the nanoparticles into the die to align the nanoparticles in a flow direction of the composite materials.
12. The apparatus of claim 1 , wherein the die is configured to have a lumen of which radius decreases from a proximal zone of the die to a distal zone of the die.
13. The apparatus of claim 1 , further comprising a supply of a thermoplastic polymer operably coupled to the barrel.
14. The apparatus of claim 1 , wherein the nanoparticles in the supply of nanoparticles have an aspect ratio greater than 10.
15. The apparatus of claim 1 , wherein the nanoparticles in the supply of nanoparticles comprise at least one of carbon nanotubes or carbon nanowires.
16. The apparatus of claim 12 , wherein at least a portion of the inner surface of the lumen in the distal zone is concave inward.
17. An apparatus comprising:
a barrel configured to accommodate an extrudable raw material;
a shaft rotatably disposed in the barrel;
a motor coupled to the shaft and configured to rotate the shaft to force the raw material through the barrel;
a heater configured to melt at least a portion of the raw material passing through the barrel;
a die coupled to the barrel, wherein the die comprises a lumen having radius that decreases from a proximal zone of the die to a distal zone of the die, and wherein at least a portion of the inner surface of the lumen in the distal zone is concave inward;
a first injector configured to inject nanoparticles into the distal zone of the die, thereby forming a layer of the nanoparticles over the raw material; and
a supply of nanoparticles operably coupled to the first injector.
18. The apparatus of claim 17 , wherein the first injector is generally flush with the inner surface of the lumen.
19. The apparatus of claim 17 , wherein the nanoparticles in the supply of nanoparticles have an aspect ratio greater than 10.
20. The apparatus of claim 17 , further comprising a supply of a thermoplastic polymer operably coupled to the barrel.
21. The apparatus of claim 17 , wherein the nanoparticles comprise at least one of carbon nanotubes or carbon nanowires.