IP Library › Granted Patent US 8,134,145
Granted Patent B2
US 8,134,145 · App. 11/654,585 · Granted Mar 13, 2012

Organic electronic device

Assignee: Samsung Electronics Co., Ltd.
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Quick Facts
Patent No.
US 8,134,145
App. No.
11/654,585
Granted
Mar 13, 2012
Kind
B2
Abstract

Disclosed is an organic electronic device, in which a semiconductor layer and source/drain electrodes may be formed from materials of the same type, suitable for a room-temperature wet process, and thus have surface properties similar to each other, thereby decreasing contact resistance between the semiconductor layer and the source/drain electrodes. The materials for formation of the semiconductor layer and source/drain electrodes may be organic semiconductor type materials obtained by adding carbon-based nanoparticles to organic semiconductor materials in predetermined or given amounts. As such, the conductivity of a semiconductor or conductor may vary depending on the amount of carbon-based nanoparticles.

Claims (29)

1. An organic electronic device, comprising a substrate, a gate electrode, a gate insulating layer, a semiconductor layer, and source/drain electrodes,

wherein the semiconductor layer and the source/drain electrodes include organic semiconductor type materials having different concentrations of carbon-based nanoparticles and organic semiconductor materials,

wherein the carbon-based nanoparticles and the organic semiconductor materials are the same in the semiconductor layer and the source/drain electrodes, and

wherein the organic semiconductor materials include at least one selected from the group consisting of anthracene, tetracene, pentacene, oligothiophene, polythiophene, merocyanine, copper phthalocyanine, perylene, polyaniline, polyacetylene, polypyrrole, polyphenylene, rubrene, coronene, anthradithiophene, polyfluorene, polyphenylenevinylene, and polythienylthiazole.

2. The device as set forth in claim 1 , wherein the semiconductor layer is formed of a first organic semiconductor type material obtained by adding the carbon-based nanoparticles to the organic semiconductor material in an amount of about 0.001˜0.6 wt % based on an amount of the organic semiconductor material, and the source/drain electrodes are formed of a second organic semiconductor type material obtained by adding the carbon-based nanoparticles to the organic semiconductor material in an amount of about 1.0˜10 wt % based on an amount of the organic semiconductor material.

3. The device as set forth in claim 1 , wherein the organic semiconductor materials include at least one selected from the group consisting of low-molecular-weight or oligomer organic semiconductor materials and polymer organic semiconductor materials.

4. The device as set forth in claim 1 , wherein the carbon-based nanoparticles include at least one selected from the group consisting of carbon nanotubes, fullerene, graphite, and carbon black.

5. The device as set forth in claim 1 , wherein the carbon-based nanoparticles are carbon nanotubes, the carbon nanotubes being selected from the group consisting of single-walled carbon nanotubes, double-walled carbon nanotubes, multi-walled carbon nanotubes, and rope carbon nanotubes.

6. The device as set forth in claim 1 , wherein the carbon-based nanoparticles have a particle size from about ones to tens of nm.

7. The device as set forth in claim 1 , wherein the substrate is selected from the group consisting of a silicon substrate, a glass substrate, and a plastic substrate.

8. The device as set forth in claim 1 , wherein the gate electrode includes at least one material selected from the group consisting of metals or alloys thereof, metal oxides, and conductive polymers.

9. The device as set forth in claim 1 , wherein the gate insulating layer includes a ferroelectric insulator, an inorganic insulator, an organic insulator, or a composition including an aqueous polymer solution, having a UV curing agent added thereto, and a fluorine-based aqueous compound.

10. The device as set forth in claim 1 , further comprising:

at least one selected from the group consisting of a data line and a bank.

11. The device as set forth in claim 10 , further comprising the data line, wherein the data line includes at least one selected from the group consisting of metals or alloys thereof, and metal oxides.

12. The device as set forth in claim 10 , further comprising the bank, wherein the bank includes at least one selected from the group consisting of banks for a semiconductor layer and banks for source/drain electrodes.

13. The device as set forth in claim 1 , wherein the organic electronic device is selected from the group consisting of a thin film transistor, a field emission device, a solar cell, and polymer memory.

14. A method of fabricating an organic electronic device, comprising:

providing a substrate; and

forming a gate electrode, a gate insulating layer, a semiconductor layer, and source/drain electrodes on the substrate,

wherein the semiconductor layer and the source/drain electrodes are formed using organic semiconductor type materials obtained by adding different concentrations of carbon-based nanoparticles to organic semiconductor materials,

wherein the carbon-based nanoparticles and the organic semiconductor materials are the same in the semiconductor layer and the source/drain electrodes, and

wherein the organic semiconductor materials include at least one selected from the group consisting of anthracene, tetracene, pentacene, oligothiophene, polythiophene, merocyanine, copper phthalocyanine, perylene, polyaniline, polyacetylene, polypyrrole, polyphenylene, rubrene, coronene, anthradithiophene, polyfluorene, polyphenylenevinylene, and polythienylthiazole.

15. The method as set forth in claim 14 , wherein the method of forming the semiconductor layer and the source/drain electrodes further comprises:

dissolving and dispersing the organic semiconductor type material in an organic solvent to make a mixture; and

applying the mixture to the semiconductor layer and the source/drain electrodes.

16. The method as set forth in claim 15 , wherein the organic solvent includes at least one selected from the group consisting of alcohols, glycols, glycol ethers, glycol ether acetates, terpineols, trimethyl pentanediol monoisobutyrate (TEXANOL), dichloroethene (DCE), chlorobenzene, N-methyl-2-pyrrolidone (NMP) and mixtures thereof.

17. The method as set forth in claim 15 , wherein dissolving and dispersing the organic semiconductor type material is conducted at about 30˜60° C. for about 0.5˜5 hours.

18. The method as set forth in claim 15 , wherein applying the mixture is conducted through a coating process selected from the group consisting of printing, spin coating, solution casting, screen printing, dip coating, ink jetting, and drop casting.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 23, 2007
From: LEE, SANG YOON; HAHN, JUNG SEOK; HAN, KOOK MIN; KOO, BON WON; MOON, HYUN SIK
To: SAMSUNG ELECTRONICS CO., LTD.
Reel/Frame 019092/0054 →
Priority Claims (1)
KR 10-2006-0049947 · Jun 2, 2006 · national
Continuity (1)
Related Publication 20070278481A1 · Dec 6, 2007