Stretch bonded laminate including an elastic member containing an adhesive composition
Elastic composite laminates are disclosed. The laminates include an elastic member bonded to at least one facing material. In accordance with the present disclosure, an adhesive composition is coextruded with an elastomeric material to form the elastic member. In this manner, the elastic member can be bonded to the facing material in a stretched state without having to apply a separate adhesive layer between the two materials. In one embodiment, the elastic member can be bonded to the facing material according to a pattern that includes bonded areas and non-bonded areas.
1. A composite material comprising:
at least one facing material;
at least one elastic member attached to the facing material, the elastic member comprising an elastomeric material combined with an adhesive composition in a sheath and core construct wherein the elastomeric material forms the core of the elastic member and the adhesive composition forms at least a partial sheath around the elastomeric material, and wherein only the adhesive composition in combination with the elastomeric material is present to bond the elastic member to the facing material; wherein
the adhesive composition comprises an atactic polymer, a crystalline polymer, and a tackifier; and
the atactic polymer is present in an amount from about 20% to about 80% by weight, the crystalline polymer is present in an amount from about 5% to about 20% by weight, the tackifier is present in an amount from about 20% to about 60% by weight,
wherein from about 10% to 80% of the surface area of the elastic member is bonded to the facing material; and
wherein the elastic member has been formed by coextruding the elastic material and the adhesive composition together.
2. A composite material as defined in claim 1 , wherein the elastic member has an outside surface and wherein at least a portion of the outside surface comprises the adhesive composition.
3. A composite material as defined in claim 1 , wherein the elastomeric material of the elastic member comprises a material selected from the group consisting of a styrenic block copolymer, a polyurethane, a polyester, a polyamide, a copolymer of ethylene and at least one vinyl monomer, or a metallocene-catalyzed polyolefin.
4. A composite material as defined in claim 1 , wherein the atactic polymer present in the adhesive composition comprises a material selected from the group consisting of a polypropylene, a polystyrene, a polybutene, a low density polyethylene, or a polyalphaolefin random copolymer and wherein the crystalline polymer present in the adhesive composition comprises a material selected from the group consisting of a polypropylene, a polystyrene, a polybutene, a high density polyethylene, or a polyalphaolefin random copolymer.
5. A composite material as defined in claim 1 , wherein the atactic polymer present in the adhesive composition comprises a material selected from the group consisting of a polypropylene, a polyethylene and copolymers thereof and wherein the crystalline polymer present within the adhesive composition comprises a material selected from the group consisting of a polypropylene, a polyethylene and copolymers thereof.
6. A composite material as defined in claim 4 , wherein the atactic polymer is less than 25% crystalline and wherein the crystalline polymer is greater than 60% crystalline.
7. A composite material as defined in claim 4 , wherein the atactic polymer is less than 20% crystalline and wherein the crystalline polymer is greater than 80% crystalline.
8. A composite material as defined in claim 1 , wherein the atactic polymer has a number average molecular weight of from about 3,000 to about 100,000 and the crystalline polymer has a number average molecular weight of from about 10,000 to about 100,000.
9. A composite material as defined in claim 1 , wherein the adhesive composition further comprises an extensible polymer, the extensible polymer comprising a material selected from the group consisting of styrene-isoprene-styrene block copolymers, styrene-butadiene-styrene block copolymers, styrene-ethylene butylene-styrene block copolymers, styrene-ethylene propylene-styrene block copolymers, single-site catalyzed polyolefins, polyisoprenes, polybutadienes, ethylene vinyl acetate copolymers, ethylene methacrylate copolymers, ethylene n-butyl acrylate copolymers, and combinations thereof.
10. A composite material as defined in claim 1 , wherein the adhesive composition has migrated to a surface of the elastic member.
11. A composite material as defined in claim 1 , wherein the adhesive composition is present within the elastic member in an amount from about 2% to about 20% by weight.
12. A composite material as defined in claim 1 , wherein the adhesive composition contained within the elastic member is bonded to the facing material according to a pattern, the adhesive composition being thermally bonded or ultrasonically bonded to the facing material.
13. A composite material as defined in claim 12 , wherein the bonding pattern comprises parallel bond lines extending in a cross-machine direction.
14. A composite material as defined in claim 1 , wherein the facing material comprises a spunbond web or a meltblown web.
15. A composite material as defined in claim 1 , wherein the elastic member is attached to the facing material in a stretched state such that the facing material gathers when the elastic member is relaxed.
16. A composite material as defined in claim 1 , wherein the elastic member comprises a plurality of filaments.
17. A composite material as defined in claim 1 , wherein the elastic member comprises a film or a non-woven web.
18. A composite material as defined in claim 1 , wherein the adhesive composition contained within the elastic member is bonded to the facing material according to a pattern, the adhesive composition being bonded to the facing material by pressure bonds.
19. A composite material as defined in claim 1 , wherein no other adhesive material is present in between or covering the elastic member.
20. A composite material as defined in claim 1 , wherein the elastic member is bonded to the facing material without any additional adhesive layer present in between the elastic member and the facing material.
21. A composite material comprising:
a facing material;
elastic filaments extending generally in the same direction, the elastic filaments comprising an elastomeric material combined with an adhesive composition in a sheath and core construct wherein the elastomeric material forms the core of the elastic member and the adhesive composition forms at least a partial sheath around the elastomeric material, the adhesive composition being bonded to the facing material for attaching the elastic filaments to the facing material, the elastic filaments being attached to the facing material in a stretched state such that the facing material gathers when the elastic filaments are relaxed, and wherein the adhesive composition contained within the elastic filaments is bonded to the facing material according to a pattern so as to form bonded areas and non-bonded areas along the length of the filaments; wherein the adhesive composition comprises an atactic polymer, a crystalline polymer, an extensible polymer, and a tackifier, the atactic polymer comprising a material selected from the group consisting of a polyethylene, a polypropylene, or a polyalphaolefin random copolymer, the atactic polymer being present in the adhesive composition in an amount of from about 20% to about 80% by weight, the crystalline polymer comprising a material selected from the group consisting of a polypropylene or a polyethylene, the crystalline polymer being present in the adhesive composition in an amount from about 5% to about 20% by weight, the adhesive composition comprising from about 2% to about 20% by weight of the elastic filaments;
wherein from about 10% to 80% of the surface area of the elastic filaments is bonded to the facing material; and
wherein the elastic filaments have been formed by coextruding extruding the elastic material and the adhesive composition together.
22. A composite material as defined in claim 21 , wherein the atactic polymer is less than 20% crystalline and wherein the crystalline polymer is greater than 80% crystalline.
23. A composite material as defined in claim 21 , wherein the extensible polymer comprises a material selected from the group consisting of styrene-isoprene-styrene block copolymers, styrene-butadiene-styrene block copolymers, styrene-ethylene butylene-styrene block copolymers, styrene-ethylene propylene-styrene block copolymers, single-site catalyzed polyolefins, polyisoprenes, polybutadienes, ethylene vinyl acetate copolymers, ethylene methacrylate copolymers, ethylene n-butyl acrylate copolymers, and combinations thereof.
24. A composite material as defined in claim 21 , wherein the adhesive composition contained within the elastic filaments is thermally bonded or ultrasonically bonded to the facing material.
25. A composite material as defined in claim 21 , wherein the bonding pattern comprises parallel bond lines that are perpendicular to a filament axis.
26. A composite material as defined in claim 21 , wherein no other adhesive layer is present in between or covering the elastic filaments and the facing material.
27. A composite material as defined in claim 21 , wherein the composite material comprises a second facing material, the elastic filaments being positioned in between the first facing material and the second facing material.
28. An elastic member comprising an elastomeric material combined with an adhesive composition in a sheath and core construct wherein the elastomeric material forms the core of the elastic member and the adhesive composition forms at least a partial sheath around the elastomeric material wherein the elastomeric material and the adhesive composition have been coextruded together, the adhesive composition having migrated to a surface of the elastic member after being coextruded with the elastomeric material, the elastic member comprising a material selected from the group consisting of a fiber, a filament, a film, or a nonwoven web;
wherein the adhesive composition comprises an atactic polymer, a crystalline polymer, and a tackifier; and
wherein the atactic polymer comprises a material selected from the group consisting of a polyethylene, a polypropylene, or a polyalphaolefin random copolymer, the atactic polymer being present in the adhesive composition in an amount from about 20% to about 80% by weight, the crystalline polymer comprising a material selected from the group consisting of a polypropylene or a polyethylene, the crystalline polymer being present in the adhesive composition in an amount from about 5% to about 20% by weight, the tackifier being present in the adhesive composition in an amount from about 20% to about 60% by weight; and
wherein from about 10% to 80% of the surface area of the elastic member is bonded to a facing material.
29. An elastic member as defined in claim 28 , wherein the adhesive composition further comprises an extensible polymer.
30. A composite material as defined in claim 1 , wherein the adhesive composition forms a complete sheath around the elastomeric material.
31. A composite material as defined in claim 21 , wherein the adhesive composition forms a complete sheath around the elastomeric material.
32. An elastic member as defined in claim 28 , wherein the adhesive composition forms a complete sheath around the elastomeric material.
33. A composite material as defined in claim 1 wherein from about 20% to 60% of the surface area of the elastic member is bonded to the facing material.
34. A composite material as defined in claim 1 wherein from about 35% to 45% of the surface area of the elastic member is bonded to the facing material.
35. A composite material as defined in claim 21 wherein from about 20% to 60% of the surface area of the elastic filament is bonded to the facing material.
36. A composite material as defined in claim 21 wherein from about 35% to 45% of the surface area of the elastic filament is bonded to the facing material.
37. An elastic member as defined in claim 28 wherein from about 20% to 60% of the surface area of the elastic member is bonded to the facing material.
38. An elastic member as defined in claim 28 wherein from about 35% to 45% of the surface area of the elastic member is bonded to the facing material.