Aqueous alkyd resin emulsion for fixing water-soluble dyes
The invention provides aqueous resin emulsion containing a resin obtained by reaction of a composition containing at least: at least one polyhydric alcohol having at least two hydroxyl groups, at least one polyetherpolyol having a molecular weight of 400 to 8000 g/mol, at least one monobasic carboxylic acid, and at least one polybasic carboxylic acid having at least two carboxyl groups or its anhydride, to form a resin and the resin emulsion is modified by providing basic groups. The invention further relates to a process for preparing a resin, to a resin as obtained by the process and to a coating film obtained from the resin emulsion.
1. An aqueous alkyd resin emulsion containing a resin obtained by reaction of a composition comprising:
10 to 35 wt. % of at least one polyhydric alcohol having at least two hydroxyl groups which has a molecular weight of at least 60 g/mol,
3 to 15 wt. % of at least one polyetherpolyol having a molecular weight of 400 to 8000 g/mol,
10 to 60 wt. % of at least one monobasic carboxylic acid, and
10 to 40 wt. % of at least one polybasic carboxylic acid having at least two carboxyl groups or its anhydride,
wherein the resin obtained by the reaction further comprises at least one nitrogen-containing basic group which is provided by a molecule which has at least one nitrogen-containing basic group or a molecule which has at least one protected nitrogen-containing basic group, and which has a molecular weight of at least 100 g/mol, wherein the nitrogen-containing basic group is attached to the resin by a covalent bond.
2. The aqueous alkyd resin emulsion according to claim 1 wherein the molecule which provides the nitrogen-containing basic group(s) has a molecular weight of at least 200 g/mol.
3. The aqueous alkyd resin emulsion according to claim 1 wherein the composition further comprises an oil or fatty acid component.
4. The aqueous alkyd resin emulsion according to claim 1 wherein the emulsion has a pH of less than 7.5.
5. The aqueous alkyd resin emulsion according to claim 1 wherein the basic group(s) are selected from primary, secondary, tertiary amino group(s) and mixtures thereof.
6. The aqueous alkyd resin emulsion according to claim 1 wherein the resin has an acid number in the range of 5-30 mg KOH/g resin.
7. The aqueous alkyd resin emulsion according to claim 1 wherein the resin has nitrogen-containing basic group(s) and the resin emulsion has a nitrogen content of 0.4% to 27% by weight based on the solids content.
8. The aqueous alkyd resin emulsion according to claim 1 wherein the resin emulsion has a solids content of 25% to 75% by weight.
9. A process for preparing an alkyd resin which comprises preparing a composition comprising at least the following components:
10 to 35 wt. % of at least one polyhydric alcohol having at least two hydroxyl groups which has a molecular weight of at least 60 g/mol,
3 to 15 wt. % of at least one polyetherpolyol having a molecular weight of 400 to 8000 g/mol,
10 to 60 wt. % of at least monobasic carboxylic acid, and
10 to 40 wt. % of at least one polybasic carboxylic acid having at least two carboxyl groups or its anhydride,
wherein the weight percentages are based on the resin; converting the composition to a resin, and modifying the resin by introduction of nitrogen-containing basic group(s), wherein the resin is modified by adding to the composition a molecule comprising at least one nitrogen-containing basic group or at least one protected nitrogen-containing group, and also at least one reactive group capable of reacting with a group of a component of the composition to form a covalent bond, wherein the molecule has a molecular weight of at least 100 g/mol, and, if the nitrogen-containing group is protected, deprotecting the nitrogen-containing group; wherein the alkyd resin comprises at least one nitrogen-containing basic group.
10. The process according to claim 9 wherein the molecule is selected from the group consisting of amino acids, diamines, oligomers of diamines having 1 to 5 repeat units, sulfonamides, sulfanilamide, high molecular weight polyamines and mixtures thereof.
11. A process for preparing an alkyd resin which comprises reacting a composition comprising at least the following components:
10 to 35 wt. % of at least one polyhydric alcohol having at least two hydroxyl groups which has a molecular weight of at least 60 g/mol,
3 to 15 wt. % of at least one polyetherpolyol having a molecular weight of 400 to 8000 g/mol,
10 to 60 wt. % of at least monobasic carboxylic acid, and
10 to 40 wt. % of at least one polybasic carboxylic acid having at least two carboxylic groups or its anhydride,
wherein the weight percentages are based on the resin; with a molecule comprising at least one nitrogen-containing basic group, or at least one protected nitrogen-containing basic group, and at least one reactive group capable of reacting with a group of a component of the composition to form a covalent bond, wherein the molecule has a molecular weight of at least 100 g/mol, and if the nitrogen-containing group is protected, deprotecting the nitrogen containing group; wherein the reaction provides an alkyd resin which comprises at least one nitrogen-containing basic group.
12. The process according to claim 9 wherein the molecule is a diisocyanate and wherein the reaction of the resin with the diisocyanate is carried out at a pH of less than 4.
13. The process according to claim 9 wherein the resin is precrosslinked with a diisocyanate at a pH of 7.0 to 7.5.
14. A coating film obtained by preparing a resin by the process of claim 9 and evaporating the aqueous solvent.
15. A coating film obtained by preparing a resin by the process of claim 11 and evaporating the aqueous solvent.
16. A resin obtained by the process according to claim 11 .
17. An aqueous alkyd resin emulsion containing a resin obtained by reaction of a composition comprising:
10 to 35 wt % of at least one polyhydric alcohol having at least two hydroxyl groups which has a molecular weight of at least 60 g/mol,
3 to 15 wt. % of at least one polyetherpolyol having a molecular weight of 400 to 8000 g/mol,
10 to 60 wt. % of at least monobasic carboxylic acid, and
10 to 40 wt. % of at least one polybasic carboxylic acid having at least two carboxylic groups or its anhydride,
wherein the emulsion further contains a molecule separate from the resin which molecule has at least two nitrogen-containing basic groups and which has a molecular weight of at least 100 g/mol.
18. The aqueous alkyd resin emulsion according to claim 17 wherein the molecule which contains the at least two nitrogen-containing basic groups has a molecular weight of at least 200 g/mol.
19. The aqueous alkyd resin emulsion according to claim 17 wherein the composition further comprises an oil or fatty acid component.
20. The aqueous alkyd resin emulsion according to claim 17 wherein the emulsion has a pH of less than 7.5.
21. The aqueous alkyd resin emulsion according to claim 17 wherein the basic groups are selected from primary, secondary, tertiary amino groups and mixtures thereof.
22. The aqueous alkyd resin emulsion according to claim 17 wherein the resin has an acid number in the range of 5-30 mg KOH/g resin.
23. A resin obtained by reaction of a composition comprising
10 to 35 wt. % of at least one polyhydric alcohol having at least two hydroxyl groups which has a molecular weight of at least 60 g/mol,
3 to 15 wt. % of at least one polyetherpolyol having a molecular weight of 400 to 8000 g/mol,
10 to 60 wt. % of at least monobasic carboxylic acid, and
10 to 40 wt. % of at least one polybasic carboxylic acid having at least two carboxylic groups or its anhydride,
wherein the weight percentages are based on the composition;
wherein the resin obtained by the reaction further comprises at least one nitrogen-containing basic group which is provided by a molecule which has at least one nitrogen-containing basic group or a molecule which has at least one protected nitrogen-containing basic group, and which has a molecular weight of at least 100 g/mol, wherein the nitrogen-containing basic group is attached to the resin by a covalent bond.