Pressure-sensitive adhesive for optical films
A pressure-sensitive adhesive contains an acrylic triblock copolymer (I) at not less than 60% by mass based on the total mass of all solids contained in the pressure-sensitive adhesive, the acrylic triblock copolymer being represented by the formula A1-B-A2 wherein: A1 and A2 are each independently an alkyl methacrylate polymer block having Tg of not less than 100° C. and B is an acryl acrylate polymer block having Tg of not more than −20° C.; the content of the polymer block B is 50 to 95% by mass; Mw is in the range of 50,000 to 300,000; and the molecular weight distribution is in the range of 1.0 to 1.5. Preferably, the acrylic triblock copolymer (I) is a combination of an acrylic triblock copolymer (Ia) having Mw of 50,000 to less than 100,000 and an acrylic triblock copolymer (Ib) having Mw of 100,000 to 300,000, in a mass ratio (Ia):(Ib) of 45:55 to 75:25.
1. A pressure-sensitive adhesive for optical films that comprises an acrylic triblock copolymer (I) at not less than 60% by mass based on the total mass of all solids contained in the pressure-sensitive adhesive, the acrylic triblock copolymer meeting requirements (E1), (E2), (E3) and (E4):
(E1) the acrylic triblock copolymer is represented by Formula (1):
A1-B-A2 (1)
wherein A1 and A2 are each independently an alkyl methacrylate polymer block having a glass transition temperature of not less than 100° C. and B is an alkyl acrylate polymer block having a glass transition temperature of not more than −20° C.;
(E2) the content of the polymer block B is 50 to 95% by mass;
(E3) the weight average molecular weight (Mw) is in the range of 50,000 to 300,000; and
(E4) the molecular weight distribution (Mw/Mn) is in the range of 1.0 to 1.5
wherein the acrylic triblock copolymer (I) is a combination comprising an acrylic triblock copolymer (Ia) and an acrylic triblock copolymer (Ib) in a mass ratio (Ia):(Ib) of 45:55 to 75:25, the acrylic triblock copolymer (Ia) meeting requirements (E1), (E2), (E3′) and (E4), the acrylic triblock copolymer (Ib) meeting requirements (E1), (E2), (E3″) and (E4):
(E3′) the weight average molecular weight (Mw) is in the range of 50,000 to less than 100,000; and
(E3″) the weight average molecular weight (Mw) is in the range of 100,000 to 300,000.
2. The pressure-sensitive adhesive for optical films according to claim 1 , wherein the weight average molecular weight (Mw) of the acrylic triblock copolymer (Ib) is in the range of 100,000 to 200,000.
3. The pressure-sensitive adhesive for optical films according to claim 1 , wherein the content of the polymer block B in the acrylic triblock copolymer (Ia) is 50 to 70% by mass and the content of the polymer block B in the acrylic triblock copolymer (Ib) is 65 to 95% by mass.
4. The pressure-sensitive adhesive for optical films according to claim 1 , wherein the acrylic triblock copolymer (Ib) is a combination comprising an acrylic triblock copolymer (Ib-1) and an acrylic triblock copolymer (Ib-2) in a mass ratio (Ib-1):(Ib-2) of 10:90 to 90:10, the acrylic triblock copolymer (Ib-1) meeting requirements (E1), (E2) and (E4) and having a weight average molecular weight (Mw) of 100,000 to less than 120,000, the acrylic triblock copolymer (Ib-2) meeting requirements (E1), (E2) and (E4) and having a weight average molecular weight (Mw) of 120,000 to 200,000.
5. The pressure-sensitive adhesive for optical films according to claim 1 , wherein the alkyl methacrylate polymer blocks A1 and A2 forming the acrylic triblock copolymer (I) have a syndiotacticity of not less than 65%.
6. The pressure-sensitive adhesive for optical films according to claim 1 , wherein the pressure-sensitive adhesive further comprises an acrylic diblock copolymer (II) at 3 to 25% by mass based on the total mass of all solids contained in the pressure-sensitive adhesive, the acrylic diblock copolymer meeting requirements (F1), (F2), (F3) and (F4):
(F1) the acrylic diblock copolymer is represented by Formula (2):
C-D (2)
wherein C is an alkyl methacrylate polymer block and D is an alkyl acrylate polymer block;
(F2) the content of the polymer block D is 50 to 95% by mass;
(F3) the weight average molecular weight (Mw) is in the range of 50,000 to 300,000; and
(F4) the molecular weight distribution (Mw/Mn) is in the range of 1.0 to 1.5.
7. The pressure-sensitive adhesive for optical films according to claim 1 , wherein when the dynamic viscoelasticity of the pressure-sensitive adhesive is measured at a frequency of 6.28 rad/s, the storage elastic modulus at 23° C. [G′ (23° C.)] is in the range of 1.0×10 5 to 8.0×10 5 Pa and the storage elastic modulus at 90° C. [G′ (90° C.)] is in the range of 7.0×10 4 to 6.0×10 5 Pa.
8. The pressure-sensitive adhesive for optical films according to claim 1 , wherein the pressure-sensitive adhesive is a pressure-sensitive adhesive solution in an organic solvent.
9. The pressure-sensitive adhesive for optical films according to claim 1 , wherein a solution of the pressure-sensitive adhesive in toluene with a solid concentration of 45% by mass has a solution viscosity of 1000 to 4000 mPa·s as measured with Brookfield viscometer at 25° C.
10. A pressure-sensitive adhesive optical film that comprises a pressure-sensitive adhesive layer formed from the pressure-sensitive adhesive of claim 1 and is produced without crosslinking.
11. An image display device comprising the pressure-sensitive adhesive optical film of claim 10 .
12. An optical film-protection pressure-sensitive adhesive film that comprises a pressure-sensitive adhesive layer formed from the pressure-sensitive adhesive of claim 1 and is produced without crosslinking.
13. An image display device comprising the optical film-protection pressure-sensitive adhesive film of claim 12 .
14. An image display device comprising the pressure-sensitive adhesive optical film of claim 10 and an optical film-protection pressure-sensitive adhesive film that comprises a pressure-sensitive adhesive layer formed from a pressure sensitive adhesive that comprises an acrylic triblock copolymer (I) at not less than 60% by mass based on the total mass of all solids contained in the pressure-sensitive adhesive.
15. The pressure-sensitive adhesive for optical films according to claim 1 , wherein said alkyl methacryalte polymer blocks A1 and A2 forming at least one of the acrylic triblock copolymer (Ia) and the acrylic triblock copolymer (Ib) has a syndiotacticity of not less than 65%.
16. The pressure-sensitive adhesive for optical films according to claim 4 , wherein said alkyl methacryalte polymer blocks A1 and A2 forming at least one of the acrylic triblock copolymer (Ib-1) and the acrylic triblock copolymer (Ib-2) has a syndiotacticity of not less than 65%.
17. The pressure-sensitive adhesive for optical films according to claim 1 , wherein polymers which are components in said pressure-sensitive adhesive do not undergo a chemical crosslinking reaction forming covalent bonds during production steps for said pressure-sensitive adhesive.