Continuous-fiber-reinforced amorphous ceramic composition
View Patent ↗The application discloses and claims an oxidation resistant, continuous-fiber-reinforced ceramic composition, durable at temperatures above 1000° C., and capable of taking on any arbitrary near net shape formed without machining and tooling. The composition of the invention comprises a fine grained ceramic matrix which in turn comprises a mixture of a ZrB 2 phase and a SiC phase with the matrix being reinforced with SiC or C or an oxide fiber, resulting in a fine grained ZrB 2 —SiC matrix with domain sizes ≦0.5 μm. The ZrB 2 phase of the invention is capable of forming small microcrystalline domains ≦0.5 μm upon heat treatment. The composition the invention also comprises a fiber reinforced composite with a high degree of filling and densification of its preform resulting in a composition containing a low level of porosity and high fiber volume fraction.
1. An oxidation resistant, continuous-fiber-reinforced ceramic composition, the composition being durable at temperatures above 1000° C., the composition being capable of taking on any arbitrary near net shape as formed without machining and tooling, the composition comprising;
a. a fine grained ceramic matrix, the matrix comprising a mixture of a MB x phase, wherein M is selected from the group consisting of Zr and Hf, and x ranges from 1 to 4 and a SiC phase, the matrix being reinforced with a material selected from the group consisting of SiC fiber, C fiber and oxide fiber, the matrix comprising domain sizes ≦0.5 μm, the matrix being formed by mixing a liquid precursor of MB x wherein M is selected from the group consisting of Zr and Hf wherein the ratio of Boron to M in the precursor capable of ranging from about 1:1 to 4:1 with polymeric precursors of SiC and pyrolyzing the resulting mixture; and
b. a fiber-reinforced composite with a high degree of filling and densification of its preform resulting in a composition containing a low level of porosity and high fiber volume fraction.
2. The oxidation resistant, continuous fiber-reinforced ceramic composition of claim 1 , wherein the weight ratio of the SiC phase to the MB x phase ranges from about 100 to about 0.1.
3. The oxidation resistant, continuous fiber-reinforced ceramic composition of claim 1 wherein the composition is not limited by geometries available from high pressure dies.
4. The oxidation resistant, continuous fiber-reinforced ceramic composition of claim 1 wherein fiber architectures can be varied at will from simple 2-dimensional lay-ups to complex 3-dimensional woven preforms.
5. The oxidation resistant, continuous fiber-reinforced ceramic composition of claim 1 wherein the domain size of the ceramic phases is small compared to the fiber diameter.
6. The oxidation resistant, continuous fiber-reinforced ceramic composition of claim 1 , wherein the ratio of boron to zirconium is 1.4:1.
7. The oxidation resistant, continuous fiber-reinforced ceramic composition of claim 1 , wherein the liquid precursor of MB x is derived from reaction of an amine with M(BH 4 ) 4 .