Process for the formulation of potassium chloride from a carnallite source
A process for formulating high purity potassium chloride from a carnallite source. The process takes advantage of solubility differences and saturation levels in a multiple salt system generated upon dissolution of carnallite. In the system, the sodium chloride is kept in solution and the magnesium chloride present in the system is controlled to be in a concentration range of between 12% and 25% by weight. This avoids co-precipitation of sodium chloride with the potassium chloride during crystallization and therefore prevents the sodium chloride from contaminating the potassium chloride. The result is high grade potassium chloride.
1. A method of formulating potassium chloride from a source of carnallite, comprising:
providing a source of carnallite;
dissolving said source of carnallite to result in a solution at least containing sodium chloride, potassium chloride, and magnesium chloride;
removing undissolved said sodium chloride;
maintaining, absent addition of magnesium chloride, undersaturation of the magnesium chloride concentration existing in the solution in a range between 12% and 25% by weight throughout said method to prevent co-precipitation of any sodium chloride with potassium chloride; and
crystallizing potassium chloride from said solution with a sodium chloride of not greater than 2% by weight, whereby said potassium chloride has a high purity.
2. The method as set forth in claim 1 , wherein said crystallizing of said potassium chloride is performed in a plurality of crystallizers.
3. The method as set forth in claim 2 , wherein said crystallizers are sequential.
4. The method as set forth in claim 1 , further including the step of adding make-up water to said solution to prevent precipitation of sodium chloride during said crystallizing of said potassium chloride.
5. The method as set forth in claim 1 , wherein said source of carnallite is a subterranean source.
6. The method as set forth in claim 1 , further including the step of adding flocculant to dissolved carnallite to flocculate insoluble compounds present therein.
7. The method as set forth in claim 6 , wherein said insoluble compounds are stored.
8. The method as set forth in claim 1 , wherein removed sodium chloride from said solution is deep well injected.
9. The method as set forth in claim 1 , wherein said magnesium chloride is crystallized.
10. The method as set forth in claim 1 , further including the step treating said potassium chloride with an anti-caking agent.